The isotherm,mechanism and kinetics of carbon tetrachloride(CT) adsorption by polyacrylonitrile-based activated carbon fiber(PAN-ACF) were investigated in batch reactors and a continuous flow reactor,and the regenerat...The isotherm,mechanism and kinetics of carbon tetrachloride(CT) adsorption by polyacrylonitrile-based activated carbon fiber(PAN-ACF) were investigated in batch reactors and a continuous flow reactor,and the regeneration of PAN-ACF was also studied.Freundlich and Dubinin-Radushkevich(D-R) adsorption equations can well describe the adsorption isotherm.CT is mainly adsorbed on the exterior surface of PAN-ACF with low boundary layer effect and rate-controlling step of intra-particle diffusion.The adsorption dynamics in the batch reactor well fits with the pseudo-first-order model,and the breakthrough curves in the continuous flow reactor can be well described by the Yoon-Nelson model.The ACF can be recycled through thermal regeneration,whereas the adsorption capacity decreases from 7.87 to 4.98 mg/g after the fourth regeneration.78%-94%of CT can be removed from the wastewater of a fluorine chemical plant on a pilot scale,which confirms the efficacy of ACF under industrial conditions.The results indicate that PAN-ACF is applicable to CT removal from wastewater.展开更多
In this paper, the authors present a new control strategy for continuous backbone (continuum) "trunk and tentacle" robots. Control of this emerging new class of robots has proved difficult due to the inherent comp...In this paper, the authors present a new control strategy for continuous backbone (continuum) "trunk and tentacle" robots. Control of this emerging new class of robots has proved difficult due to the inherent complexity of their dynamics. Using a recently established full dynamic model, the authors introduce a new nonlinear model-based control strategy for continuum robots. The approach is applicable to continuum robots which can extend/contract as well as bend throughout their structure. Results are illustrated using the mathematical model of a three-section, six-degree of freedom planar continuum robot.展开更多
Multiple fractured horizontal well(MFHW) is widely applied in the development of shale gas. To investigate the gas flow characteristics in shale, based on a new dual mechanism triple continuum model, an analytical sol...Multiple fractured horizontal well(MFHW) is widely applied in the development of shale gas. To investigate the gas flow characteristics in shale, based on a new dual mechanism triple continuum model, an analytical solution for MFHW surrounded by stimulated reservoir volume(SRV) was presented. Pressure and pressure derivative curves were used to identify the characteristics of flow regimes in shale. Blasingame type curves were established to evaluate the effects of sensitive parameters on rate decline curves, which indicates that the whole flow regimes could be divided into transient flow, feeding flow, and pseudo steady state flow. In feeding flow regime, the production of gas well is gradually fed by adsorbed gases in sub matrix, and free gases in matrix. The proportion of different gas sources to well production is determined by such parameters as storability ratios of triple continuum, transmissibility coefficients controlled by dual flow mechanism and fracture conductivity.展开更多
A 9-story concrete-filled steel tubular frame model is used to analyze the response of joints due to sudden column loss. Three different models are developed and compared to study the efficiency and feasibility of sim...A 9-story concrete-filled steel tubular frame model is used to analyze the response of joints due to sudden column loss. Three different models are developed and compared to study the efficiency and feasibility of simulation, which include substructure model, beam element model and solid element model. The comparison results show that the substructure model has a satisfying capability, calculation efficiency and accuracy to predict the concerned joints as well as the overall framework. Based on the substructure model and a kind of semi-rigid connection for concretefilled square hollow section steel column proposed in this paper, the nonlinear dynamic analyses are conducted by the alternate path method. It is found that the removal of the ground inner column brings high-level joint moments and comparatively low-level axial tension forces. The initial stiffness and transmitted ultimate moment of the semi-rigid connection are the main factors that influence the frame behavior, and their lower limit should be guaranteed to resist collapse. Reduced ultimate moment results in drastic displacement and axial force development, which may bring progressive collapse. The higher initial stiffness ensures that the structure has a stronger capacity to resist progressive collapse.展开更多
Reinforced concrete(RC) load bearing wall is widely used in high-rise and mid-rise buildings. Due to the number of walls in plan and reduction in lateral force portion, this system is not only stronger against earthqu...Reinforced concrete(RC) load bearing wall is widely used in high-rise and mid-rise buildings. Due to the number of walls in plan and reduction in lateral force portion, this system is not only stronger against earthquakes, but also more economical. The effect of progressive collapse caused by removal of load bearing elements, in various positions in plan and stories of the RC load bearing wall system was evaluated by nonlinear dynamic and static analyses. For this purpose, three-dimensional model of 10-story structure was selected. The analysis results indicated stability, strength and stiffness of the RC load-bearing wall system against progressive collapse. It was observed that the most critical condition for removal of load bearing walls was the instantaneous removal of the surrounding walls located at the corners of the building where the sections of the load bearing elements were changed. In this case, the maximum vertical displacement was limited to 6.3 mm and the structure failed after applying the load of 10 times the axial load bored by removed elements. Comparison between the results of the nonlinear dynamic and static analyses demonstrated that the "load factor" parameter was a reasonable criterion to evaluate the progressive collapse potential of the structure.展开更多
By employing the inequality of [8] and a positive continuous function g(t), t[t0, +∞), oscillation criteria for the second-order half-linear impulsive differential equ-ations with damping are established. Our res...By employing the inequality of [8] and a positive continuous function g(t), t[t0, +∞), oscillation criteria for the second-order half-linear impulsive differential equ-ations with damping are established. Our results generalize and improve some known ones.展开更多
This paper is intended to be a first step towards the continuous dependence of dynamical contact problems on the initial data as well as the uniqueness of a solution. Moreover,it provides the basis for a proof of the ...This paper is intended to be a first step towards the continuous dependence of dynamical contact problems on the initial data as well as the uniqueness of a solution. Moreover,it provides the basis for a proof of the convergence of popular time integration schemes as the Newmark method.We study a frictionless dynamical contact problem between both linearly elastic and viscoelastic bodies which is formulated via the Signorini contact conditions.For viscoelastic materials fulfilling the Kelvin-Voigt constitutive law,we find a characterization of the class of problems which satisfy a perturbation result in a non-trivial mix of norms in function space.This characterization is given in the form of a stability condition on the contact stresses at the contact boundaries.Furthermore,we present perturbation results for two well-established approximations of the classical Signorini condition:The Signorini condition formulated in velocities and the model of normal compliance,both satisfying even a sharper version of our stability condition.展开更多
The direct hydroxylation of benzene to phenol catalyzed by activated carbon-supported Fe (Fe/AC) in acetonitrile using H2O2 as the oxidant was studied in a continuous flow reactor. Results showed that the continuous...The direct hydroxylation of benzene to phenol catalyzed by activated carbon-supported Fe (Fe/AC) in acetonitrile using H2O2 as the oxidant was studied in a continuous flow reactor. Results showed that the continuous operation could obtain high phenol yield of 28.1%, coupled with the turnover frequency of 3 h^-1, and high selectivity of 98% under mild condition. The catalyst was characterized by N2 adsorption/desorption, Boehm titration, X-ray photoelectron spectra, and Fourier transform infrared spectroscopy. It was observed that iron may interact with the carboxyl group forming iron-carboxylate like species, which act as the active phase. The apparent activation energy obtained by fitting an Arrhenius model to the experimental data was 13.4 kJ/mol. The reaction order was calculated to be about i, 0.2 for benzene and 0.7 for H202.展开更多
In this paper,we prove approximations of multifractional Brownian motions with moving-average representations and of those with harmonizable representations in the space of continuous functions on [0,1]. These approxi...In this paper,we prove approximations of multifractional Brownian motions with moving-average representations and of those with harmonizable representations in the space of continuous functions on [0,1]. These approximations are constructed by Poisson processes.展开更多
This work presents the nonlinear dynamical system of continuous fermentation from glycerol to 1,3-propanediol. The impulsive control scheme of continuous culture is intro- duced. By employing impulsive control, Lyapu...This work presents the nonlinear dynamical system of continuous fermentation from glycerol to 1,3-propanediol. The impulsive control scheme of continuous culture is intro- duced. By employing impulsive control, Lyapunov's method and comparison technique, sufficient conditions are established for the asymptotical stability and synchronization of the dynamical system of continuous fermentation. The upper bound of the impulse interval is also estimated. An example will illustrate the effectiveness of the results in Sec. 4.展开更多
基金Project(2004C33068) supported by the Science and Technology Programs of Zhejiang Province,ChinaProject(20100933B17) supported by the Social Development and Science Research Program of Hangzhou,China
文摘The isotherm,mechanism and kinetics of carbon tetrachloride(CT) adsorption by polyacrylonitrile-based activated carbon fiber(PAN-ACF) were investigated in batch reactors and a continuous flow reactor,and the regeneration of PAN-ACF was also studied.Freundlich and Dubinin-Radushkevich(D-R) adsorption equations can well describe the adsorption isotherm.CT is mainly adsorbed on the exterior surface of PAN-ACF with low boundary layer effect and rate-controlling step of intra-particle diffusion.The adsorption dynamics in the batch reactor well fits with the pseudo-first-order model,and the breakthrough curves in the continuous flow reactor can be well described by the Yoon-Nelson model.The ACF can be recycled through thermal regeneration,whereas the adsorption capacity decreases from 7.87 to 4.98 mg/g after the fourth regeneration.78%-94%of CT can be removed from the wastewater of a fluorine chemical plant on a pilot scale,which confirms the efficacy of ACF under industrial conditions.The results indicate that PAN-ACF is applicable to CT removal from wastewater.
文摘In this paper, the authors present a new control strategy for continuous backbone (continuum) "trunk and tentacle" robots. Control of this emerging new class of robots has proved difficult due to the inherent complexity of their dynamics. Using a recently established full dynamic model, the authors introduce a new nonlinear model-based control strategy for continuum robots. The approach is applicable to continuum robots which can extend/contract as well as bend throughout their structure. Results are illustrated using the mathematical model of a three-section, six-degree of freedom planar continuum robot.
基金Project(2011ZX05015)supported by Important National Science and Technology Specific Projects of the "Twelfth Five-years" Plan Period,China
文摘Multiple fractured horizontal well(MFHW) is widely applied in the development of shale gas. To investigate the gas flow characteristics in shale, based on a new dual mechanism triple continuum model, an analytical solution for MFHW surrounded by stimulated reservoir volume(SRV) was presented. Pressure and pressure derivative curves were used to identify the characteristics of flow regimes in shale. Blasingame type curves were established to evaluate the effects of sensitive parameters on rate decline curves, which indicates that the whole flow regimes could be divided into transient flow, feeding flow, and pseudo steady state flow. In feeding flow regime, the production of gas well is gradually fed by adsorbed gases in sub matrix, and free gases in matrix. The proportion of different gas sources to well production is determined by such parameters as storability ratios of triple continuum, transmissibility coefficients controlled by dual flow mechanism and fracture conductivity.
基金Supported by National Natural Science Foundation of China (No.50878066)Natural Science Foundation of Heilongjiang Province (No.ZJG0701)Heilongjiang Postdoctoral Science Foundation
文摘A 9-story concrete-filled steel tubular frame model is used to analyze the response of joints due to sudden column loss. Three different models are developed and compared to study the efficiency and feasibility of simulation, which include substructure model, beam element model and solid element model. The comparison results show that the substructure model has a satisfying capability, calculation efficiency and accuracy to predict the concerned joints as well as the overall framework. Based on the substructure model and a kind of semi-rigid connection for concretefilled square hollow section steel column proposed in this paper, the nonlinear dynamic analyses are conducted by the alternate path method. It is found that the removal of the ground inner column brings high-level joint moments and comparatively low-level axial tension forces. The initial stiffness and transmitted ultimate moment of the semi-rigid connection are the main factors that influence the frame behavior, and their lower limit should be guaranteed to resist collapse. Reduced ultimate moment results in drastic displacement and axial force development, which may bring progressive collapse. The higher initial stiffness ensures that the structure has a stronger capacity to resist progressive collapse.
文摘Reinforced concrete(RC) load bearing wall is widely used in high-rise and mid-rise buildings. Due to the number of walls in plan and reduction in lateral force portion, this system is not only stronger against earthquakes, but also more economical. The effect of progressive collapse caused by removal of load bearing elements, in various positions in plan and stories of the RC load bearing wall system was evaluated by nonlinear dynamic and static analyses. For this purpose, three-dimensional model of 10-story structure was selected. The analysis results indicated stability, strength and stiffness of the RC load-bearing wall system against progressive collapse. It was observed that the most critical condition for removal of load bearing walls was the instantaneous removal of the surrounding walls located at the corners of the building where the sections of the load bearing elements were changed. In this case, the maximum vertical displacement was limited to 6.3 mm and the structure failed after applying the load of 10 times the axial load bored by removed elements. Comparison between the results of the nonlinear dynamic and static analyses demonstrated that the "load factor" parameter was a reasonable criterion to evaluate the progressive collapse potential of the structure.
基金Foundation item: Supported by the Natural Science Foundation of Guangdong Province(011471)
文摘By employing the inequality of [8] and a positive continuous function g(t), t[t0, +∞), oscillation criteria for the second-order half-linear impulsive differential equ-ations with damping are established. Our results generalize and improve some known ones.
基金supported by the DFG Research Center MATHEON,"Mathematicsfor key technologies:Modelling,simulation,and optimization of real-world processes",Berlin
文摘This paper is intended to be a first step towards the continuous dependence of dynamical contact problems on the initial data as well as the uniqueness of a solution. Moreover,it provides the basis for a proof of the convergence of popular time integration schemes as the Newmark method.We study a frictionless dynamical contact problem between both linearly elastic and viscoelastic bodies which is formulated via the Signorini contact conditions.For viscoelastic materials fulfilling the Kelvin-Voigt constitutive law,we find a characterization of the class of problems which satisfy a perturbation result in a non-trivial mix of norms in function space.This characterization is given in the form of a stability condition on the contact stresses at the contact boundaries.Furthermore,we present perturbation results for two well-established approximations of the classical Signorini condition:The Signorini condition formulated in velocities and the model of normal compliance,both satisfying even a sharper version of our stability condition.
文摘The direct hydroxylation of benzene to phenol catalyzed by activated carbon-supported Fe (Fe/AC) in acetonitrile using H2O2 as the oxidant was studied in a continuous flow reactor. Results showed that the continuous operation could obtain high phenol yield of 28.1%, coupled with the turnover frequency of 3 h^-1, and high selectivity of 98% under mild condition. The catalyst was characterized by N2 adsorption/desorption, Boehm titration, X-ray photoelectron spectra, and Fourier transform infrared spectroscopy. It was observed that iron may interact with the carboxyl group forming iron-carboxylate like species, which act as the active phase. The apparent activation energy obtained by fitting an Arrhenius model to the experimental data was 13.4 kJ/mol. The reaction order was calculated to be about i, 0.2 for benzene and 0.7 for H202.
基金supported by National Natural Science Foundation of China (Grant No. 10901054)
文摘In this paper,we prove approximations of multifractional Brownian motions with moving-average representations and of those with harmonizable representations in the space of continuous functions on [0,1]. These approximations are constructed by Poisson processes.
文摘This work presents the nonlinear dynamical system of continuous fermentation from glycerol to 1,3-propanediol. The impulsive control scheme of continuous culture is intro- duced. By employing impulsive control, Lyapunov's method and comparison technique, sufficient conditions are established for the asymptotical stability and synchronization of the dynamical system of continuous fermentation. The upper bound of the impulse interval is also estimated. An example will illustrate the effectiveness of the results in Sec. 4.