An efficient synthesis of carbon nanofibers by pyrolysis of as-prepared polypyrrole nanowires was reported. Under the subsequent KOH activation, a significant morphology variation was detected and the obtained sample ...An efficient synthesis of carbon nanofibers by pyrolysis of as-prepared polypyrrole nanowires was reported. Under the subsequent KOH activation, a significant morphology variation was detected and the obtained sample took on a ribbon-like structure. The morphology and structure of the carbon nanofibers and carbon nanoribbons were characterized. When the as-prepared one-dimensional carbon nanostructures were used as anode materials in lithium ion batteries, both of them exhibited superior cyclical stability and good rate properties. After 50 cycles, the reversible capacity of carbon nanofibers electrode maintained 530 mA·h/g. Concerning carbon nanoribbons, the reversible capacity is always larger than 850 mA·h/g and the reversible capacity retention after 23 cycles is 86%.展开更多
This article draws attention to the subject of art in Levinas's thinking through consideration of his philosophical language, which is aided by images, metaphors, and idioms of art. The primary image that will accomp...This article draws attention to the subject of art in Levinas's thinking through consideration of his philosophical language, which is aided by images, metaphors, and idioms of art. The primary image that will accompany our discussion throughout this article is the image of art as shadow, which Levinas incorporates into the title of the essay which he devotes to the subject of art: "Reality and Its Shadow". Thinking about art from the perspective of Levinas means thinking about image and essence, about which is visible before us and which we cannot see, and about the different ways in which art can express itself. Levinas's theory of interpretation is grounded in and guided by the field of ethics and addresses the ethical aspects of interpretation. Levinas approaches the discourse of interpretation not out of na'ivet6 but rather based on a deep understanding of the field of hermeneutics, with all its shortcomings and challenges. Thinking of hermeneutics from an ethical perspective is no mere addition to the discussion but the very crux of the matter. An attempt to understand interpretation as an act of exposing the truth encounters serious philosophical and logical difficulties, whether we are seeking to discover the intention of the artist, the intent of a specific work of art, or a hidden form within the work itself. The engagement with Levinas's theory of hermeneutics, however, raises a different question which is the focus of this article: Can Levinas's theory of interpretation be applied to the realm of artistic creation, and if so, how? This question is sharpened by the difficulties that Levinas himself poses to his readers by designating art as the "shadow" of reality and drawing attention to the egoistic dimension of the artistic act.展开更多
The development of well-defined TiO2 nanoarchitectures is a versatile strategy to achieve high-efficiency photocatalytic performance.In this study,mesoporous TiO2 nanofibers consisting of oriented nanocrystals were fa...The development of well-defined TiO2 nanoarchitectures is a versatile strategy to achieve high-efficiency photocatalytic performance.In this study,mesoporous TiO2 nanofibers consisting of oriented nanocrystals were fabricated by a facile vapothermal-assisted topochemical transformation of preformed H-titanate nanobelts.The vapothermal temperature is crucial in tuning the microstructures and photocatalytic redox properties of the resulting mesoporous TiO2 nanofibers.The microstructures were characterized with XRD,TEM,XPS and nitrogen adsorption-desorption isotherms,etc.The photocatalytic activities were evaluated by photocatalytic oxidation of organic pollutant(Rhodamine B as an example)as well as photocatalytic reduction of water to generate hydrogen(H2).The nanofibers vapothermally treated at 150°C showed the highest photocatalytic activity in both oxidation and reduction reactions,2 times higher than that of P25.The oriented alignment and suitable mesoporosity in the resulting nanofiber architecture were crucial for enhancing photocatalytic performances.The oriented alignment of anisotropic anatase nanocrystals shall facilitate faster vectorial charge transportation along the nanofibers architecture.And,the suitable mesoporosity and high surface area would also effectively enhance the mass exchange during photocatalytic reactions.We also demonstrate that efficient energy-recovering photocatalytic water treatments could be accomplished by a cascading oxic-anoxic process where the dye is degraded in the oxic phase and hydrogen is generated in the successive anoxic phase.This study showcases a novel and facile method to fabricate mesoporous TiO2 nanofibers with high photocatalytic activity for both clean energy production and environmental purification.展开更多
Cellulose nanocrystals (CNCs) of rod-like shape were prepared from degreased cotton using sulfuric acid hydrolysis. The obtained CNC suspension was neutralized using a sodium hydroxide solution to remove the...Cellulose nanocrystals (CNCs) of rod-like shape were prepared from degreased cotton using sulfuric acid hydrolysis. The obtained CNC suspension was neutralized using a sodium hydroxide solution to remove the residual sulfuric acid and improve the thermal stability of the CNC particles. Then, poly(ethylene oxide) (PEO) was employed to modify the nanocrystals through entanglement and physical adsorption. The goal was to further improve the thermal stability and weaken the hydrophilicity of CNCs. Original and modifed CNCs were dosed into a polylactic acid (PLA) matrix to prepare nanocomposites using a hot compression process. Results of the thermogravimetric analysis showed that the initial thermal decomposition temperature of the modifed CNCs showed a 120℃ improvement compared to the original CNCs. That is, the thermal stability of the modified CNCs improved because of their shielding and wrapping by a PEO layer on their surface. Results from scanning electron microscopy and ultraviolet-visible spectrophotometry showed that the compatibility of the modifed CNCs with organic PLA improved, which was attributed to the compatibility of the PEO chains adsorbed on the surface of the CNCs. Finally, the results of tensile tests indicated a significant improvement in terms of breaking strength and elongation at the break point.展开更多
An adaptive method of residual life estimation for deteriorated products with two performance characteristics (PCs) was proposed, which was sharply different from existing work that only utilized one-dimensional degra...An adaptive method of residual life estimation for deteriorated products with two performance characteristics (PCs) was proposed, which was sharply different from existing work that only utilized one-dimensional degradation data. Once new degradation information was available, the residual life of the product being monitored could be estimated in an adaptive manner. Here, it was assumed that the degradation of each PC over time was governed by a Wiener degradation process and the dependency between them was characterized by the Frank copula function. A bivariate Wiener process model with measurement errors was used to model the degradation measurements. A two-stage method and the Markov chain Monte Carlo (MCMC) method were combined to estimate the unknown parameters in sequence. Results from a numerical example about fatigue cracks show that the proposed method is valid as the relative error is small.展开更多
Shallow gas is composed of all kinds of shallow buried natural gas resources( < 1500 m) with relatively small reserve for each gas resource. It has some advantages such as shallow burial depth,good physical propert...Shallow gas is composed of all kinds of shallow buried natural gas resources( < 1500 m) with relatively small reserve for each gas resource. It has some advantages such as shallow burial depth,good physical properties and the huge accumulations. Based on the Wigner-Vill distribution,a general spectral decomposition method is applied in the shallow gas detection. Cone-shaped kernel function filtering method is used to suppress cross-terms of the Wigner-Ville distribution,which is tested on field seismic data. Because of shallow gas reservoir has a characteristic that low frequency energy is stronger and high frequency energy is weaker,it indicates the presence of shallow gas successfully.展开更多
The authors consider here some Oldroyd models of non-Newtonian flows consisting of a strong coupling between incompressible Navier-Stokes equations and some transport equations. It is proved that there exist global we...The authors consider here some Oldroyd models of non-Newtonian flows consisting of a strong coupling between incompressible Navier-Stokes equations and some transport equations. It is proved that there exist global weak solutions for general initial conditions. The existence proof relies upon showing the propagation in time of the compactness of solutions.展开更多
Developing highly efficient,cost-effective,and stable electrocatalysts for hydrogen evolution reaction(HER)is of considerable importance but remains challenging.Herein,we report the fabrication of a robust Ru-based el...Developing highly efficient,cost-effective,and stable electrocatalysts for hydrogen evolution reaction(HER)is of considerable importance but remains challenging.Herein,we report the fabrication of a robust Ru-based electrocatalyst,which comprises heterostructured Ru-Ru_(2)P nanoparticles that are embedded in the N,P-codoped carbon nanofibers(CNFs),through a synthetic strategy involving electrospinning and temperature-controlled pyrolysis treatment.The as-prepared Ru-Ru_(2)P catalyst(Ru-Ru_(2)P@CNFs)shows excellent HER catalytic activities with low overpotentials of 11 and 14 mV in acidic and alkaline media,respectively,to achieve a current density of 10 mA cm^(−2),which are superior to the individual components of pure Ru and Ru_(2)P catalysts.Density functional theory calculations demonstrate the existence of electronic coupling effect between Ru and Ru_(2)P at the heterointerfaces,leading to a well-modulated electronic structure with optimized hydrogen adsorption strength and enhanced electrical conductivity for efficient HER electrocatalysis.In addition,the overall synthetic strategy can be generalized for the synthesis of a series of transitional metal phosphide-based nanofibers,thereby holding a remarkable capacity for various potential applications.展开更多
基金National Natural Science Foundation of China(30870657,30970775,81101106,61108081)Chinese National Programs for High Technology Research and Development(2009AA02Z413)+2 种基金Tianjin Municipal Government of China(09JCZDJC18200,10JCZDJC17300)Tianjin Natural Science Foundation of China(12JCQNJC09400)Ph.D.Programs Foundation of Ministry of Education of China(20100032120064 and 20110032120069)
基金Projects (51204209,51274240) supported by the National Natural Science Foundation of China
文摘An efficient synthesis of carbon nanofibers by pyrolysis of as-prepared polypyrrole nanowires was reported. Under the subsequent KOH activation, a significant morphology variation was detected and the obtained sample took on a ribbon-like structure. The morphology and structure of the carbon nanofibers and carbon nanoribbons were characterized. When the as-prepared one-dimensional carbon nanostructures were used as anode materials in lithium ion batteries, both of them exhibited superior cyclical stability and good rate properties. After 50 cycles, the reversible capacity of carbon nanofibers electrode maintained 530 mA·h/g. Concerning carbon nanoribbons, the reversible capacity is always larger than 850 mA·h/g and the reversible capacity retention after 23 cycles is 86%.
文摘This article draws attention to the subject of art in Levinas's thinking through consideration of his philosophical language, which is aided by images, metaphors, and idioms of art. The primary image that will accompany our discussion throughout this article is the image of art as shadow, which Levinas incorporates into the title of the essay which he devotes to the subject of art: "Reality and Its Shadow". Thinking about art from the perspective of Levinas means thinking about image and essence, about which is visible before us and which we cannot see, and about the different ways in which art can express itself. Levinas's theory of interpretation is grounded in and guided by the field of ethics and addresses the ethical aspects of interpretation. Levinas approaches the discourse of interpretation not out of na'ivet6 but rather based on a deep understanding of the field of hermeneutics, with all its shortcomings and challenges. Thinking of hermeneutics from an ethical perspective is no mere addition to the discussion but the very crux of the matter. An attempt to understand interpretation as an act of exposing the truth encounters serious philosophical and logical difficulties, whether we are seeking to discover the intention of the artist, the intent of a specific work of art, or a hidden form within the work itself. The engagement with Levinas's theory of hermeneutics, however, raises a different question which is the focus of this article: Can Levinas's theory of interpretation be applied to the realm of artistic creation, and if so, how? This question is sharpened by the difficulties that Levinas himself poses to his readers by designating art as the "shadow" of reality and drawing attention to the egoistic dimension of the artistic act.
基金supported by the National Natural Science Foundation of China(21707173,51872341,51572209)the Science and Technology Program of Guangzhou(201707010095)+2 种基金the Start-up Funds for High-Level Talents of Sun Yat-sen University(38000-31131103)the Fundamental Research Funds for the Central Universities(19lgzd29)the China Postdoctoral Science Foundation(2017M622869)~~
文摘The development of well-defined TiO2 nanoarchitectures is a versatile strategy to achieve high-efficiency photocatalytic performance.In this study,mesoporous TiO2 nanofibers consisting of oriented nanocrystals were fabricated by a facile vapothermal-assisted topochemical transformation of preformed H-titanate nanobelts.The vapothermal temperature is crucial in tuning the microstructures and photocatalytic redox properties of the resulting mesoporous TiO2 nanofibers.The microstructures were characterized with XRD,TEM,XPS and nitrogen adsorption-desorption isotherms,etc.The photocatalytic activities were evaluated by photocatalytic oxidation of organic pollutant(Rhodamine B as an example)as well as photocatalytic reduction of water to generate hydrogen(H2).The nanofibers vapothermally treated at 150°C showed the highest photocatalytic activity in both oxidation and reduction reactions,2 times higher than that of P25.The oriented alignment and suitable mesoporosity in the resulting nanofiber architecture were crucial for enhancing photocatalytic performances.The oriented alignment of anisotropic anatase nanocrystals shall facilitate faster vectorial charge transportation along the nanofibers architecture.And,the suitable mesoporosity and high surface area would also effectively enhance the mass exchange during photocatalytic reactions.We also demonstrate that efficient energy-recovering photocatalytic water treatments could be accomplished by a cascading oxic-anoxic process where the dye is degraded in the oxic phase and hydrogen is generated in the successive anoxic phase.This study showcases a novel and facile method to fabricate mesoporous TiO2 nanofibers with high photocatalytic activity for both clean energy production and environmental purification.
基金the National Natural Science Foundation of China (grant Nos. 31570578 and 31270632)the Fundamental Research Funds for the Central Universities (grant No. JUSRP51622A)the State Key Laboratory of Pulp and Paper Engineering (grant No. 201809)
文摘Cellulose nanocrystals (CNCs) of rod-like shape were prepared from degreased cotton using sulfuric acid hydrolysis. The obtained CNC suspension was neutralized using a sodium hydroxide solution to remove the residual sulfuric acid and improve the thermal stability of the CNC particles. Then, poly(ethylene oxide) (PEO) was employed to modify the nanocrystals through entanglement and physical adsorption. The goal was to further improve the thermal stability and weaken the hydrophilicity of CNCs. Original and modifed CNCs were dosed into a polylactic acid (PLA) matrix to prepare nanocomposites using a hot compression process. Results of the thermogravimetric analysis showed that the initial thermal decomposition temperature of the modifed CNCs showed a 120℃ improvement compared to the original CNCs. That is, the thermal stability of the modified CNCs improved because of their shielding and wrapping by a PEO layer on their surface. Results from scanning electron microscopy and ultraviolet-visible spectrophotometry showed that the compatibility of the modifed CNCs with organic PLA improved, which was attributed to the compatibility of the PEO chains adsorbed on the surface of the CNCs. Finally, the results of tensile tests indicated a significant improvement in terms of breaking strength and elongation at the break point.
基金Project(60904002)supported by the National Natural Science Foundation of China
文摘An adaptive method of residual life estimation for deteriorated products with two performance characteristics (PCs) was proposed, which was sharply different from existing work that only utilized one-dimensional degradation data. Once new degradation information was available, the residual life of the product being monitored could be estimated in an adaptive manner. Here, it was assumed that the degradation of each PC over time was governed by a Wiener degradation process and the dependency between them was characterized by the Frank copula function. A bivariate Wiener process model with measurement errors was used to model the degradation measurements. A two-stage method and the Markov chain Monte Carlo (MCMC) method were combined to estimate the unknown parameters in sequence. Results from a numerical example about fatigue cracks show that the proposed method is valid as the relative error is small.
文摘Shallow gas is composed of all kinds of shallow buried natural gas resources( < 1500 m) with relatively small reserve for each gas resource. It has some advantages such as shallow burial depth,good physical properties and the huge accumulations. Based on the Wigner-Vill distribution,a general spectral decomposition method is applied in the shallow gas detection. Cone-shaped kernel function filtering method is used to suppress cross-terms of the Wigner-Ville distribution,which is tested on field seismic data. Because of shallow gas reservoir has a characteristic that low frequency energy is stronger and high frequency energy is weaker,it indicates the presence of shallow gas successfully.
文摘The authors consider here some Oldroyd models of non-Newtonian flows consisting of a strong coupling between incompressible Navier-Stokes equations and some transport equations. It is proved that there exist global weak solutions for general initial conditions. The existence proof relies upon showing the propagation in time of the compactness of solutions.
基金financially supported by the Natural Science Foundation of Zhejiang Province (LQ20B030001 and LY20E020002)China Postdoctoral Science Foundation (2021M702305)。
文摘Developing highly efficient,cost-effective,and stable electrocatalysts for hydrogen evolution reaction(HER)is of considerable importance but remains challenging.Herein,we report the fabrication of a robust Ru-based electrocatalyst,which comprises heterostructured Ru-Ru_(2)P nanoparticles that are embedded in the N,P-codoped carbon nanofibers(CNFs),through a synthetic strategy involving electrospinning and temperature-controlled pyrolysis treatment.The as-prepared Ru-Ru_(2)P catalyst(Ru-Ru_(2)P@CNFs)shows excellent HER catalytic activities with low overpotentials of 11 and 14 mV in acidic and alkaline media,respectively,to achieve a current density of 10 mA cm^(−2),which are superior to the individual components of pure Ru and Ru_(2)P catalysts.Density functional theory calculations demonstrate the existence of electronic coupling effect between Ru and Ru_(2)P at the heterointerfaces,leading to a well-modulated electronic structure with optimized hydrogen adsorption strength and enhanced electrical conductivity for efficient HER electrocatalysis.In addition,the overall synthetic strategy can be generalized for the synthesis of a series of transitional metal phosphide-based nanofibers,thereby holding a remarkable capacity for various potential applications.