CaCO3 was chosen as main raw material and Solid State method was used to prepare the sample. The precursor was directly sintered at 1100 ℃ with reducing atmosphere for 3 h to obtain new green CaO:Tb^3+, Li^+ Phosp...CaCO3 was chosen as main raw material and Solid State method was used to prepare the sample. The precursor was directly sintered at 1100 ℃ with reducing atmosphere for 3 h to obtain new green CaO:Tb^3+, Li^+ Phosphors. The effects of the content of the doping ions Tb^3+ on the luminescent properties have been studied. The structure, morphology and luminescent properties of the phosphors were characterized by XRD, SEM, UV and PL-PLE spectra respectively. The results showed that the CaO:Tb^3+, Li^+ was a single face-centered cubic crystals, the phosphor particle distributed uniformly. The phosphor has a strong absorptive capacity excited by 282 nm ultraviolet ray, and could emit the strong green light with the wavelength of 543 nm (^5D4→^7F5). The CaO:Tb^3+, Li^+ is a new type of green fluorescent material.展开更多
文摘CaCO3 was chosen as main raw material and Solid State method was used to prepare the sample. The precursor was directly sintered at 1100 ℃ with reducing atmosphere for 3 h to obtain new green CaO:Tb^3+, Li^+ Phosphors. The effects of the content of the doping ions Tb^3+ on the luminescent properties have been studied. The structure, morphology and luminescent properties of the phosphors were characterized by XRD, SEM, UV and PL-PLE spectra respectively. The results showed that the CaO:Tb^3+, Li^+ was a single face-centered cubic crystals, the phosphor particle distributed uniformly. The phosphor has a strong absorptive capacity excited by 282 nm ultraviolet ray, and could emit the strong green light with the wavelength of 543 nm (^5D4→^7F5). The CaO:Tb^3+, Li^+ is a new type of green fluorescent material.