以氧化铟锡(indium tin oxide,ITO)为代表的透明导电氧化物(transparent conducting oxide,TCO)在当前光电器件中的重要性日益增长.通过在TCO中引入金属网格构成复合电极,可以在保持良好透明性的前提下有效提升电学性能,同时降低对铟的...以氧化铟锡(indium tin oxide,ITO)为代表的透明导电氧化物(transparent conducting oxide,TCO)在当前光电器件中的重要性日益增长.通过在TCO中引入金属网格构成复合电极,可以在保持良好透明性的前提下有效提升电学性能,同时降低对铟的需求量,并为可穿戴设备所需的柔性电极提供可能方案.对此类电极的电学性能分析,如复合电极方阻随金属网格结构参数的变化,可为电极设计与制备提供基本的出发点,但相关理论尚十分缺乏.本文针对典型的方孔方格型金属网格-TCO复合电极,分别展开基于瑞利模型和基于有限元仿真的电学性能分析.结果表明,孔型近似导致的金属通道显著畸变是复合电极的电学计算中瑞利模型在中高开口率下失效的主要原因.据此,我们采用格型修正,通过提升瑞利模型中的原胞外边界对称性来改善金属通道的畸变.与电极仿真的对比表明,修正后瑞利模型的适用范围明显扩大,其结果可与实验数据很好地拟合,为此类复合透明电极的电学数据分析与结构设计提供了简洁高效的理论工具.展开更多
A kind of photoelectrode was innovated by anodising titanium mesh in H 2SO 4 solution and photo reduced in HAuCl 4 solution and named Ti/Au TiO 2 mesh electrode. The structural and surface morphology of the Ti/Au TiO ...A kind of photoelectrode was innovated by anodising titanium mesh in H 2SO 4 solution and photo reduced in HAuCl 4 solution and named Ti/Au TiO 2 mesh electrode. The structural and surface morphology of the Ti/Au TiO 2 mesh was examined by X ray diffraction, laser Raman spectra, scanning electronic microscopy(SEM) and X ray photoelectron spectroscopy respectively. The results indicate that its crystal structure, morphology and the size of pore are affected greatly by gold deposition. XPS measurement shows that the valence band of Ti/TiO 2 has two peaks: a wide one at 4.97 eV and a narrow one at 6.61 eV, which correspond mainly to π(nonbonding) and σ (bonding) O 2p orbitals. The emission intensity of O 2p orbitals becomes stronger and the width of the valence band increases with the increase of Au content. And the emission of nonbonding shifts toward lower binding energy and that of bonding O 2p orbitals shifts toward higher binding energy. The photoelectrocatalytic(PEC) oxidation of humic acid(HA) was investigated in terms of TOC. The PEC oxidation efficiency of Ti/Au TiO 2 mesh with optimal content of gold is higher than that of Ti/TiO 2 mesh. It is suggested that the recombination of electrons and holes is hindered owing to gold deposition. The investigation shows that PEC oxidation is a convenient way to mineralize organic matter for water treatment.展开更多
文摘以氧化铟锡(indium tin oxide,ITO)为代表的透明导电氧化物(transparent conducting oxide,TCO)在当前光电器件中的重要性日益增长.通过在TCO中引入金属网格构成复合电极,可以在保持良好透明性的前提下有效提升电学性能,同时降低对铟的需求量,并为可穿戴设备所需的柔性电极提供可能方案.对此类电极的电学性能分析,如复合电极方阻随金属网格结构参数的变化,可为电极设计与制备提供基本的出发点,但相关理论尚十分缺乏.本文针对典型的方孔方格型金属网格-TCO复合电极,分别展开基于瑞利模型和基于有限元仿真的电学性能分析.结果表明,孔型近似导致的金属通道显著畸变是复合电极的电学计算中瑞利模型在中高开口率下失效的主要原因.据此,我们采用格型修正,通过提升瑞利模型中的原胞外边界对称性来改善金属通道的畸变.与电极仿真的对比表明,修正后瑞利模型的适用范围明显扩大,其结果可与实验数据很好地拟合,为此类复合透明电极的电学数据分析与结构设计提供了简洁高效的理论工具.
文摘A kind of photoelectrode was innovated by anodising titanium mesh in H 2SO 4 solution and photo reduced in HAuCl 4 solution and named Ti/Au TiO 2 mesh electrode. The structural and surface morphology of the Ti/Au TiO 2 mesh was examined by X ray diffraction, laser Raman spectra, scanning electronic microscopy(SEM) and X ray photoelectron spectroscopy respectively. The results indicate that its crystal structure, morphology and the size of pore are affected greatly by gold deposition. XPS measurement shows that the valence band of Ti/TiO 2 has two peaks: a wide one at 4.97 eV and a narrow one at 6.61 eV, which correspond mainly to π(nonbonding) and σ (bonding) O 2p orbitals. The emission intensity of O 2p orbitals becomes stronger and the width of the valence band increases with the increase of Au content. And the emission of nonbonding shifts toward lower binding energy and that of bonding O 2p orbitals shifts toward higher binding energy. The photoelectrocatalytic(PEC) oxidation of humic acid(HA) was investigated in terms of TOC. The PEC oxidation efficiency of Ti/Au TiO 2 mesh with optimal content of gold is higher than that of Ti/TiO 2 mesh. It is suggested that the recombination of electrons and holes is hindered owing to gold deposition. The investigation shows that PEC oxidation is a convenient way to mineralize organic matter for water treatment.
