The catalytic performance of two oxides coated anodes (OCSs) meshes and one OCA plate was investigated in a zinc electrowinning electrolyte at 38 ℃. Their electrochemical behaviors were compared with that of a conv...The catalytic performance of two oxides coated anodes (OCSs) meshes and one OCA plate was investigated in a zinc electrowinning electrolyte at 38 ℃. Their electrochemical behaviors were compared with that of a conventional Pb-0.7%Ag alloy anode. Electrochemical measurements such as cyclic voltammetric, galvanostatic, potentiodynamic, open-circuit potential (OCP) and in situ electrochemical noise measurements were considered. After 2 h of OCP test, the linear polarization shows that the corrosion current density of the Ti/(IrO2-Ta2O5) mesh electrode is the lowest (3.37μA/cm^2) among the three OCAs and shows excellent performance. Additionally, after 24 h of galvanostatic polarization at 50 mA/cm^2and 38 ℃, the Ti/MnO2mesh anode has the highest potential (1.799 V), followed by the Ti/(IrO2-Ta2O5) plate (1.775 V) and Ti/(IrO2-Ta2O5) mesh (1.705 V) anodes. After 24 h of galvanostatic polarization followed by 16 h of decay, the linear polarization method confirms the sequence obtained after 2 h of OCP test, and the Ti/(IrO2-Ta2O5) mesh attains the lowest corrosion current density. The Ti/(IrO2-Ta2O5) mesh anode also shows better performance after 24 h of galvanostatic polarization with the overpotential lower than that of the conventional Pb-Ag anode by about 245 mV.展开更多
The trusted network connection is a hot spot in trusted computing field and the trust measurement and access control technology are used to deal with network security threats in trusted network.But the trusted network...The trusted network connection is a hot spot in trusted computing field and the trust measurement and access control technology are used to deal with network security threats in trusted network.But the trusted network connection lacks fine-grained states and real-time measurement support for the client and the authentication mechanism is difficult to apply in the trusted network connection,it is easy to cause the loss of identity privacy.In order to solve the abovedescribed problems,this paper presents a trust measurement scheme suitable for clients in the trusted network,the scheme integrates the following attributes such as authentication mechanism,state measurement,and real-time state measurement and so on,and based on the authentication mechanism and the initial state measurement,the scheme uses the realtime state measurement as the core method to complete the trust measurement for the client.This scheme presented in this paper supports both static and dynamic measurements.Overall,the characteristics of this scheme such as fine granularity,dynamic,real-time state measurement make it possible to make more fine-grained security policy and therefore it overcomes inadequacies existing in the current trusted network connection.展开更多
基金Project(RDCPJ 428402)supported by the Natural Sciences and Engineering Research Council of Canada
文摘The catalytic performance of two oxides coated anodes (OCSs) meshes and one OCA plate was investigated in a zinc electrowinning electrolyte at 38 ℃. Their electrochemical behaviors were compared with that of a conventional Pb-0.7%Ag alloy anode. Electrochemical measurements such as cyclic voltammetric, galvanostatic, potentiodynamic, open-circuit potential (OCP) and in situ electrochemical noise measurements were considered. After 2 h of OCP test, the linear polarization shows that the corrosion current density of the Ti/(IrO2-Ta2O5) mesh electrode is the lowest (3.37μA/cm^2) among the three OCAs and shows excellent performance. Additionally, after 24 h of galvanostatic polarization at 50 mA/cm^2and 38 ℃, the Ti/MnO2mesh anode has the highest potential (1.799 V), followed by the Ti/(IrO2-Ta2O5) plate (1.775 V) and Ti/(IrO2-Ta2O5) mesh (1.705 V) anodes. After 24 h of galvanostatic polarization followed by 16 h of decay, the linear polarization method confirms the sequence obtained after 2 h of OCP test, and the Ti/(IrO2-Ta2O5) mesh attains the lowest corrosion current density. The Ti/(IrO2-Ta2O5) mesh anode also shows better performance after 24 h of galvanostatic polarization with the overpotential lower than that of the conventional Pb-Ag anode by about 245 mV.
基金ACKNOWLEDGMENT This work was supported by the National Basic Research Program of China (973 Project) (NO.2007CB311100), the National Science Foundation for Young Scholars of China (Grant No.61001091), Beijing Nature Science Foundation(No. 4122012), "next-generation broadband wireless mobile communication network" National Science and Technology major Special issue funding(No. 2012ZX03002003), Funding Program for Academic Human Resources Development in Institutions of Higher Learning Under the Jurisdiction of Beijing Municipality of China and the key technology research and validation issue for the emergency treatment telemedicine public service platform which integrates the military and civilian and bases on the broadband wireless networks(No.2013ZX03006001-005), the issue belongs to Major national science and technology projects.
文摘The trusted network connection is a hot spot in trusted computing field and the trust measurement and access control technology are used to deal with network security threats in trusted network.But the trusted network connection lacks fine-grained states and real-time measurement support for the client and the authentication mechanism is difficult to apply in the trusted network connection,it is easy to cause the loss of identity privacy.In order to solve the abovedescribed problems,this paper presents a trust measurement scheme suitable for clients in the trusted network,the scheme integrates the following attributes such as authentication mechanism,state measurement,and real-time state measurement and so on,and based on the authentication mechanism and the initial state measurement,the scheme uses the realtime state measurement as the core method to complete the trust measurement for the client.This scheme presented in this paper supports both static and dynamic measurements.Overall,the characteristics of this scheme such as fine granularity,dynamic,real-time state measurement make it possible to make more fine-grained security policy and therefore it overcomes inadequacies existing in the current trusted network connection.