A new nickel coordination compound [Ni(L2-)(2,2′-bipy)(H2O)]·2H2O (H2L=phenyliminodiacetic acid) was obtained by self-assembly of phenyliminodiacetic acid, 2,2′-bipy, and NiCl2·6H2O in the mixed solvent of...A new nickel coordination compound [Ni(L2-)(2,2′-bipy)(H2O)]·2H2O (H2L=phenyliminodiacetic acid) was obtained by self-assembly of phenyliminodiacetic acid, 2,2′-bipy, and NiCl2·6H2O in the mixed solvent of water and ethanol (V∶V=1∶1). The complex was characterized by elemental analysis, IR spectra, and X-ray crystallography analysis. The crystal is monoclinic, space group P21 / c with a=0.867 4(2) nm, b=0.907 3(1) nm, c=2.643 5(5) nm, β=91.01(1)°, V=2.080 2(4) nm3, Z=4, F(000)=992, Dc=1.520 Mg·m-3, R1=0.027 0 and wR2=0.067 5. In the complex, nickel atom is coordinated with a distorted octahedral geometry and extensive hydrogen bonds link the complexes into a 2D network structure. CCDC: 244926.展开更多
The novel benzo-18-crown-6(B18-C-6)complex;{[Na(Bl8-C-6)]_(6)[Pt(SCN)_(6)]}[Pt(SCN)_(6)](SCN)_(2)(1)was synthesized and characterized by elemental analysis,IR spectrum and x-ray diffraction analysis.Thr crystal struct...The novel benzo-18-crown-6(B18-C-6)complex;{[Na(Bl8-C-6)]_(6)[Pt(SCN)_(6)]}[Pt(SCN)_(6)](SCN)_(2)(1)was synthesized and characterized by elemental analysis,IR spectrum and x-ray diffraction analysis.Thr crystal structure belongs to rhomobohedral,space group R-3 with cell dimesions:a=6=1.9933(3),c=2.9760(6)nm,α=β=90,γ=120°,V=10.240(3)nm^(3),Z=3,A,aclcd=1.564 g/cm^(3),F(000)=4908.1 is composed of one{[Na(B18-C-6)]_(6)[Pt(SCN)_(6)]}4+complex cation,one[Pt(SCN)_(6)]^(2-)complex anion and two SCN~anions.{[Na(B18-C-6)]_(6)[Pt(SCN)_(6)3}4+complex cation shows a three-dimensional network structure bridged by Na-O interactions between adjacent[Na(B18-C-6)]+units.The function of[Pt(SCN)_(6)]^(2-)complex anion and two SCN'anions are balancing charge in crystal.展开更多
The title complex [CdLCl2] 1 (C10H15CdCl2N3, Mr = 360.55) has been synthesized by the reaction of CdCl22.5H2O with the tridentate Schiff base L, N,N-dimethyl-N-pyridin-2-yl- methylene-1,2-diaminoethane, which is deriv...The title complex [CdLCl2] 1 (C10H15CdCl2N3, Mr = 360.55) has been synthesized by the reaction of CdCl22.5H2O with the tridentate Schiff base L, N,N-dimethyl-N-pyridin-2-yl- methylene-1,2-diaminoethane, which is derived from the condensation reaction of pyridine-2- carboxaldehyde and N,N-dimethylethylenediamine. It crystallizes in the monoclinic system, space group C2/c with a = 25.054(13), b = 7.532(4), c = 16.119(8) ? b = 116.238(8)? V = 2728(2) ?, Z = 8, Dc = 1.756 g/cm3, m(MoKa) = 1.970 mm-1, F(000) = 1424, R = 0.0297 and wR = 0.0625. Crystal analyses reveal that the cadmium atom is coordinated by two chlorine atoms and three N atoms from the tridentate ligand in a distorted tetragonal pyramidal environment. Each complex molecule is connected with four surrounding ones to form 2D network by hydrogen bonds along the bc plane. The chlorine atoms act as acceptors and the carbon atoms of the tridentate Schiff base as donors with the CH…Cl distances in the range of 3.518～3.752 ?展开更多
文摘A new nickel coordination compound [Ni(L2-)(2,2′-bipy)(H2O)]·2H2O (H2L=phenyliminodiacetic acid) was obtained by self-assembly of phenyliminodiacetic acid, 2,2′-bipy, and NiCl2·6H2O in the mixed solvent of water and ethanol (V∶V=1∶1). The complex was characterized by elemental analysis, IR spectra, and X-ray crystallography analysis. The crystal is monoclinic, space group P21 / c with a=0.867 4(2) nm, b=0.907 3(1) nm, c=2.643 5(5) nm, β=91.01(1)°, V=2.080 2(4) nm3, Z=4, F(000)=992, Dc=1.520 Mg·m-3, R1=0.027 0 and wR2=0.067 5. In the complex, nickel atom is coordinated with a distorted octahedral geometry and extensive hydrogen bonds link the complexes into a 2D network structure. CCDC: 244926.
文摘The novel benzo-18-crown-6(B18-C-6)complex;{[Na(Bl8-C-6)]_(6)[Pt(SCN)_(6)]}[Pt(SCN)_(6)](SCN)_(2)(1)was synthesized and characterized by elemental analysis,IR spectrum and x-ray diffraction analysis.Thr crystal structure belongs to rhomobohedral,space group R-3 with cell dimesions:a=6=1.9933(3),c=2.9760(6)nm,α=β=90,γ=120°,V=10.240(3)nm^(3),Z=3,A,aclcd=1.564 g/cm^(3),F(000)=4908.1 is composed of one{[Na(B18-C-6)]_(6)[Pt(SCN)_(6)]}4+complex cation,one[Pt(SCN)_(6)]^(2-)complex anion and two SCN~anions.{[Na(B18-C-6)]_(6)[Pt(SCN)_(6)3}4+complex cation shows a three-dimensional network structure bridged by Na-O interactions between adjacent[Na(B18-C-6)]+units.The function of[Pt(SCN)_(6)]^(2-)complex anion and two SCN'anions are balancing charge in crystal.
基金Supported by the National Natural Science Foundation of China (No. 20171026) and Natural Science Foundation of Tianjin (No. 013605811)
文摘The title complex [CdLCl2] 1 (C10H15CdCl2N3, Mr = 360.55) has been synthesized by the reaction of CdCl22.5H2O with the tridentate Schiff base L, N,N-dimethyl-N-pyridin-2-yl- methylene-1,2-diaminoethane, which is derived from the condensation reaction of pyridine-2- carboxaldehyde and N,N-dimethylethylenediamine. It crystallizes in the monoclinic system, space group C2/c with a = 25.054(13), b = 7.532(4), c = 16.119(8) ? b = 116.238(8)? V = 2728(2) ?, Z = 8, Dc = 1.756 g/cm3, m(MoKa) = 1.970 mm-1, F(000) = 1424, R = 0.0297 and wR = 0.0625. Crystal analyses reveal that the cadmium atom is coordinated by two chlorine atoms and three N atoms from the tridentate ligand in a distorted tetragonal pyramidal environment. Each complex molecule is connected with four surrounding ones to form 2D network by hydrogen bonds along the bc plane. The chlorine atoms act as acceptors and the carbon atoms of the tridentate Schiff base as donors with the CH…Cl distances in the range of 3.518～3.752 ?
