The recovery of indium from waste indium tin oxide （ITO） target has great significance for the economy and environment.Based on our previous study on the optimization of acid leaching technique,the present study foc...The recovery of indium from waste indium tin oxide （ITO） target has great significance for the economy and environment.Based on our previous study on the optimization of acid leaching technique,the present study focuses on tin removal via zinc substitution and indium recovery from a tin-free leach solution.The results show that when the amount of added zinc powder and reaction time increase,the tin removal effect can be improved.The optimal conditions obtained are as follows：additional content of zinc powder from 20 g/L to 25 g/L,reaction temperature of 60 ℃,and reaction time from 3 h to 4 h.Under this condition,the tin removal rate exceeds 98%,and the tin content in the tin removal solution is lower than 0.05 g/L.After tin removal,the substitution time could be reduced from 3-5 d to 1-2 d by neutralizing the residual acid by using alkaline residue and maintaining the pH value less than 2.The indium recovery rate is also improved when this condition is used.The indium content in the tin residue is reduced to lower than 0.1% and the acid-insoluble β-SnO2 could be obtained via the strong nitric acid leaching of the indium-containing tin residue.Indium could be recovered from ITO with a high purity of 99.995% via electrorefining.展开更多
The exchange bias is of technological significance in magnetic recording and spintronic devices.Pursuing a large bias field is a long-term goal for the research field of magnetic shape memory alloys.In this work,a lar...The exchange bias is of technological significance in magnetic recording and spintronic devices.Pursuing a large bias field is a long-term goal for the research field of magnetic shape memory alloys.In this work,a large bias field of 0.53 T is achieved in the Ni50Mn34In16-xFex(x=1,3,5)system by tuning the magnetic ground state(determined by the composition x)and the magnetic-field history(determined by the magnetic field HFCduring field cooling and the maximum field HMaxduring isothermal magnetization).The maximum volume fraction of the interfaces between the ferromagnetic clusters and antiferromagnetic matrix and the strong interfacial interaction are achieved by tuning the magnetic ground state and the magnetic-field history,which results in strong magnetic unidirectional anisotropy and the large exchange bias.Moreover,two guidelines were proposed to obtain the large bias field.Firstly,the composition with a magnetic ground state consisting of the dilute spin glass and the strong antiferromagnetic matrix is preferred to obtain a large bias field;secondly,tuning the magnetic-field history by enhancing HFCand reducing HMaxis beneficial to achieving large exchange bias.Our work provides an effective way for designing magnetically inhomogeneous compounds with large exchange bias.展开更多
基金Project(2012BAE06B01)supported by the National High Technology Research and Development Program of China
文摘The recovery of indium from waste indium tin oxide （ITO） target has great significance for the economy and environment.Based on our previous study on the optimization of acid leaching technique,the present study focuses on tin removal via zinc substitution and indium recovery from a tin-free leach solution.The results show that when the amount of added zinc powder and reaction time increase,the tin removal effect can be improved.The optimal conditions obtained are as follows：additional content of zinc powder from 20 g/L to 25 g/L,reaction temperature of 60 ℃,and reaction time from 3 h to 4 h.Under this condition,the tin removal rate exceeds 98%,and the tin content in the tin removal solution is lower than 0.05 g/L.After tin removal,the substitution time could be reduced from 3-5 d to 1-2 d by neutralizing the residual acid by using alkaline residue and maintaining the pH value less than 2.The indium recovery rate is also improved when this condition is used.The indium content in the tin residue is reduced to lower than 0.1% and the acid-insoluble β-SnO2 could be obtained via the strong nitric acid leaching of the indium-containing tin residue.Indium could be recovered from ITO with a high purity of 99.995% via electrorefining.
基金supported by the National Natural Science Foundation of China(51471127,51431007 and 51371134)the Program for Young Scientific New-star in Shaanxi Province of China(2014KJXX-35)+2 种基金the Innovation Capability Support Program of Shaanxi(2018PT-28 and 2017KTPT-04)Shenzhen Science and Technology Project(JCYJ20180507182246321)the Fundamental Research Funds for Central Universities of China。
文摘The exchange bias is of technological significance in magnetic recording and spintronic devices.Pursuing a large bias field is a long-term goal for the research field of magnetic shape memory alloys.In this work,a large bias field of 0.53 T is achieved in the Ni50Mn34In16-xFex(x=1,3,5)system by tuning the magnetic ground state(determined by the composition x)and the magnetic-field history(determined by the magnetic field HFCduring field cooling and the maximum field HMaxduring isothermal magnetization).The maximum volume fraction of the interfaces between the ferromagnetic clusters and antiferromagnetic matrix and the strong interfacial interaction are achieved by tuning the magnetic ground state and the magnetic-field history,which results in strong magnetic unidirectional anisotropy and the large exchange bias.Moreover,two guidelines were proposed to obtain the large bias field.Firstly,the composition with a magnetic ground state consisting of the dilute spin glass and the strong antiferromagnetic matrix is preferred to obtain a large bias field;secondly,tuning the magnetic-field history by enhancing HFCand reducing HMaxis beneficial to achieving large exchange bias.Our work provides an effective way for designing magnetically inhomogeneous compounds with large exchange bias.
