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Solvent Selection for Extractive Distillation by the Universal Quasichemical Functional Group Activity Coefficient(UNIFAC) Group Contribution Method 被引量:7
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作者 崔现宝 翟亚锐 +2 位作者 杨志才 冯天扬 张缨 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2004年第6期862-868,共7页
A method to select solvent for extractive distillation is proposed by UNIFAC group contribution. Solventselectivity can be divided into two parts: the partial combinatorial solvent selectivity and the partial residual... A method to select solvent for extractive distillation is proposed by UNIFAC group contribution. Solventselectivity can be divided into two parts: the partial combinatorial solvent selectivity and the partial residual solventselectivity. The properties of partial combinatorial and residual solvent selectivity are demonstrated. In most cases,the partial residual solvent selectivity is predominant. The candidate groups of solvent can be selected by groupinteraction parameter using UNIFAC group interaction parameter table as a guide. 展开更多
关键词 官能团 萃取精馏 溶剂选择 UNIFAC 群体交互参数
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