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沥青质大分子的结构及其测定方法综述 被引量:2
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作者 张志荣 陶国亮 +2 位作者 Lloyd R SNOWDON John K VOLKMAN 陈彦鄂 《石油实验地质》 CAS CSCD 北大核心 2023年第5期963-972,共10页
沥青质是石油或岩石可溶有机质的重要组分之一,通常具有复杂的大分子结构和较高的分子量。沥青质中包裹(或键合)的生物标志物被认为具有重要的油气地球化学研究价值,而对沥青质大分子的实际分子量和分子结构的研究在油藏勘探开发、地球... 沥青质是石油或岩石可溶有机质的重要组分之一,通常具有复杂的大分子结构和较高的分子量。沥青质中包裹(或键合)的生物标志物被认为具有重要的油气地球化学研究价值,而对沥青质大分子的实际分子量和分子结构的研究在油藏勘探开发、地球化学实验以及油品存储、运输和炼化生产等方面也具有潜在价值。对文献中报道的沥青质结构、分子量及相关的实验测定方法等开展综述,试图为沥青质的分子结构、分子量以及物理化学性质提供更加全面的认识,从而为沥青质地球化学研究在常规、非常规油藏勘探、开发研究中的应用提供基础资料。针对沥青质分子的结构及分子量方面存在的不同观点开展成果综述并结合实验测定技术的现状探讨了存在争议的主要原因,指出相关研究的下一步发展方向。目前对沥青质大分子结构的认识主要是基于两种完全不同的模型,即“孤岛”模型和“群岛”模型。前者认为沥青质具有单个芳核,表征的分子量相对较低;而后者则认为沥青质具有多个芳核,表征的分子量高。上述两种沥青质分子结构的模型均有各自的实验测定结果得以支持,其中“孤岛”模型的证据主要来自荧光光谱及激光气化/离子化质谱(L2MS)分析以及基于不同离子化方式的高分辨质谱(FT-ICR-MS)分析技术;“群岛”模型的证据主要来自气相渗透测量法、体积排阻色谱法和化学降解法等。 展开更多
关键词 沥青质 大分子结构 群岛模型 孤岛模型 分子量 极性
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Temperature Variations in Sidi Bel Abbes during the Last Three Decades
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作者 Sara Lebid Youcef Amar +3 位作者 Macho Anani Benyounes Djahed KadaMouedden Christian Mathieu 《Journal of Environmental Science and Engineering(B)》 2012年第5期690-694,共5页
The Mediterranean climate of the Sidi Bel Abbes city in northwestern Algeria has not been the subject of many investigations except some sporadic syntheses reports. However, climate change studying its most important ... The Mediterranean climate of the Sidi Bel Abbes city in northwestern Algeria has not been the subject of many investigations except some sporadic syntheses reports. However, climate change studying its most important parameters has not, at our knowledge, been the subject of a rigorous study. For this purpose this work intends to gather several temperatures ranging between 1980 and 2006 and find a mathematical model that tells us climate changes following changes in temperature during this time interval. Consequently and undesirably, the results confirm firmly the global greenhouse effect affecting our planet, but what seems rather puzzling is the fact that this warming trend has accelerated over time resulting in a changing climate toward warmer periods, for that reason a likely shift in the region of a semi-arid to tropical or arid regime overall, depending mainly on the evolution of the Azores anticyclone. 展开更多
关键词 CLIMATE temperature heat quantity global warming greenhouse effect.
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Probabilistic Seismic Hazard Assessment for Bridgetown-Barbados, Employing Subduction Interface Characteristic Earthquakes
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作者 Walter Salazar Lyndon Brown Garth Mannette 《Journal of Civil Engineering and Architecture》 2013年第11期1405-1422,共18页
A new probabilistic seismic hazard analysis was performed for the city of Bridgetown, Barbados, West Indies. Hazard computations have been performed using the standard Cornell-McGuire approach based on the definition ... A new probabilistic seismic hazard analysis was performed for the city of Bridgetown, Barbados, West Indies. Hazard computations have been performed using the standard Cornell-McGuire approach based on the definition of appropriate seismogenic sources and expected maximum magnitudes, the authors take into consideration the possibility of large subduction interface earthquakes of magnitude 8.0-9.0 beneath the Barbados accretionary prism via application of a characteristic model and slip rates. The analysis has been conducted using a standard logic-tree approach. Uniform hazard spectra have been calculated for the 5% of critical damping and the horizontal component of ground motion for rock site conditions setting 5 return periods (95, 475, 975, 2,475 and 4,975 years) and spectral accelerations for 34 structural periods ranging from 0 to 3 s. The disaggregation results suggest that the magnitude-distance pair that dominates the hazard yields M 7.4 and 8.6 and a distance of 42.5 km in the Interface Subduction Zone beneath Barbados for the 475 and 975 years RP (return period), respectively. An event with an M 8.0 at a distance of 107.5 km in the Intraplate Subduction Zone is the second scenario that dominates the hazard for both 475 and 975 years RP. 展开更多
关键词 TECTONICS seismogenic sources characteristic earthquakes recurrence interval disaggregation.
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