A La-modified Al2O3 catalyst was prepared with deposition-precipitation method. The effect of calcination temperature on the reactivity for vapor phase hydrofluorination of acetylene to vinyl fluoride. The catalysts c...A La-modified Al2O3 catalyst was prepared with deposition-precipitation method. The effect of calcination temperature on the reactivity for vapor phase hydrofluorination of acetylene to vinyl fluoride. The catalysts calcined at different temperatures were characterized using NH3-TPD, pyridine-FTIR, X-ray diffraction, and Raman techniques. It was found that the calcination process could not only change the structure of these catalysts but also modify the amount of surface acidity on the catalysts. The catalyst calcined at 400 ℃ exhibited the highest conversion of acetylene （94.6%） and highest selectivity to vinyl fluoride （83.4%） and lower coke deposition selectivity （0.72%）. The highest activity was related to the largest amount of surface acidity on the catalyst, and the coke deposition was also related to the total amount of surface acidic sites.展开更多
Currently, most of MT （magnetotelluric） data are still collected on sparse survey lines and interpreted using 2D inversion methods because of the field work cost, the work area environment, and so on. However, there...Currently, most of MT （magnetotelluric） data are still collected on sparse survey lines and interpreted using 2D inversion methods because of the field work cost, the work area environment, and so on. However, there are some 2D interpretation limitations of the MT data from 3D geoelectrical structures which always leads to wrong geological interpretations. In this paper, we used the 3D inversion method to interpret the MT sparse lines data. In model testing, the sparse lines data are the MT full information data generated from a test model and processed using the 3D conjugate gradients inversion code. The inversion results show that this inversion method is reasonable and effective. Meanwhile, we prove that for inversion results with different element parameters, the results by joint inversion of both the impedance tensor data and the tipper data are more accurate and closer to the test model.展开更多
基金ACKNOWLEDGMENT This work was supported by the National Natural Science Foundation of China （No.20873125）,
文摘A La-modified Al2O3 catalyst was prepared with deposition-precipitation method. The effect of calcination temperature on the reactivity for vapor phase hydrofluorination of acetylene to vinyl fluoride. The catalysts calcined at different temperatures were characterized using NH3-TPD, pyridine-FTIR, X-ray diffraction, and Raman techniques. It was found that the calcination process could not only change the structure of these catalysts but also modify the amount of surface acidity on the catalysts. The catalyst calcined at 400 ℃ exhibited the highest conversion of acetylene （94.6%） and highest selectivity to vinyl fluoride （83.4%） and lower coke deposition selectivity （0.72%）. The highest activity was related to the largest amount of surface acidity on the catalyst, and the coke deposition was also related to the total amount of surface acidic sites.
基金supported by the National Hi-Tech Research and Development Program of China (863 Program) (No. 2007AA09Z310)National Natural Science Foundation of China (No. 40677037, 40774029, 41004028)+1 种基金Fundamental Research Funds for the Central Universities (No. 2010ZY53) Program for New Century Excellent Talents in University (NCET)
文摘Currently, most of MT （magnetotelluric） data are still collected on sparse survey lines and interpreted using 2D inversion methods because of the field work cost, the work area environment, and so on. However, there are some 2D interpretation limitations of the MT data from 3D geoelectrical structures which always leads to wrong geological interpretations. In this paper, we used the 3D inversion method to interpret the MT sparse lines data. In model testing, the sparse lines data are the MT full information data generated from a test model and processed using the 3D conjugate gradients inversion code. The inversion results show that this inversion method is reasonable and effective. Meanwhile, we prove that for inversion results with different element parameters, the results by joint inversion of both the impedance tensor data and the tipper data are more accurate and closer to the test model.
