A series of wear and flame resistant polyamide 6(PA6)composites were prepared using glass fiber(GF)and talc(T)as reinforcer,polytetrafluoroethylene(PTFE)and graphite(Gr)as solid lubricants,red phosphorus(RP)and zinc b...A series of wear and flame resistant polyamide 6(PA6)composites were prepared using glass fiber(GF)and talc(T)as reinforcer,polytetrafluoroethylene(PTFE)and graphite(Gr)as solid lubricants,red phosphorus(RP)and zinc borate(ZB)as flame retardant.The tribological property,mechanical property,flame retardant property and the flame retardant mechanism were investigated.The tests show that the formula of the wear resistant PA6 composite(WRPA 6)is PA6/GF/T/PTFE/Gr in the ratio of 100/15/5/10/5 by mass.Because this composite exhibits the lowest friction coefficient(0.1429)and no wear mass loss,the introduction of RP and ZB can increase the flame resistance of WRPA6,and the synergistic effect of RP and ZB is obtained.Detailedly,the composite with 4 parts of ZB and 12 parts of RP shows the best flame retardant property,achieving the highest limiting oxygen index(LOI)(30.2 vol%)and a UL94 V-0 rating,and the flame retardant mechanisms may be gas phase along with condense phase mechanism.展开更多
As resource scarcity, extreme climate change, and pollution levels increase, economic growth must rely on more environmentally friendly and efficient production processes, Fuel cells are an ideal alternative to intern...As resource scarcity, extreme climate change, and pollution levels increase, economic growth must rely on more environmentally friendly and efficient production processes, Fuel cells are an ideal alternative to internal combustion （IC） engines and boilers on the path to greener industries because of their high effi- ciency and environmentally friendly operation, However, as a new energy technology, significant market penetration of fuel cells has not yet been achieved, In this paper, we perform a techno-economic and environmental analysis of fuel cell systems using life cycle and value chain activities, First, we investigate the procedure of fuel cell development and identify what activities should he undertaken according to fuel cell life cycle activities, value chain activities, and end-user acceptance criteria, Next, we present a unified learning of the institutional barriers in fuel cell commercialization, The primary end-user accep- tance criteria are function, cost, and reliability; a fuel cell should outperform these criteria compared with its competitors, such as IC engines and batteries, to achieve a competitive advantage, The repair and maintenance costs of fuel cells （due to low reliability） can lead to a substantial cost increase and decrease in availability, which are the major factors for end-user acceptance, The fuel cell industry must face the challenge of how to overcome this reliability barrier, This paper provides a deeper insight into our work over the years on the main barriers to fuel cell commercialization, and discusses the potential pivotal role of fuel cells in a future low-carbon green economy, It also identifies the needs and points out some direc- tions for this future low-carbon economy, Green energy, supplied with fuel cells, is truly the business mode of the future, Striving for a more sustainable development of economic growth by adopting green public investments and implementing policy initiatives encourages environmentally responsible indus- trial investments.展开更多
Interest in thorium stems mainly from the fact that it is expected to have a substantial increase in uranium prices. So, advanced fuel cycles which increase the reserves of nuclear materials are interesting, particula...Interest in thorium stems mainly from the fact that it is expected to have a substantial increase in uranium prices. So, advanced fuel cycles which increase the reserves of nuclear materials are interesting, particularly, the use of thorium is to produce the fissile isotope ^233U. Thorium is three to five times more abundant than uranium in the earth＇s crust. Additionally, thoria produces less radiotoxicity than the UO2, because it produces fewer amounts of actinides. ThO2 has higher corrosion resistance, besides being chemically stable, and the burning of Pu in a reactor based in thorium also decreases the inventories of Pu from the current fuel cycles. There are some ongoing projects in the world, taking into consideration the proposed goals for Generation IV reactors, namely： sustainability, economics, safety and reliability, proliferation resistance and physical protection. Some developments on the use of thorium in reactors are underway, with the support of the IAEA （International Atomic Energy Agency） and some govern like molten salt reactor. In this paper, we discuss the future importance of thorium, particularly for Brazil, which has large mineral reserves of this strategic element, the characteristics of the molten salt reactor and the experience of the IPEN （Instituto de Pesquisas Energ6ticas e Nucleares） in the purification of thorium compounds.展开更多
基金Project(149929)supported by the Postdoctoral Fund of Central South University,ChinaProject(16C0292)supported by the Hunan Education Department,ChinaProject(2016TP1022)supported by the Hunan Provincial Key Lab of Dark Tea and Jin-hua,China
文摘A series of wear and flame resistant polyamide 6(PA6)composites were prepared using glass fiber(GF)and talc(T)as reinforcer,polytetrafluoroethylene(PTFE)and graphite(Gr)as solid lubricants,red phosphorus(RP)and zinc borate(ZB)as flame retardant.The tribological property,mechanical property,flame retardant property and the flame retardant mechanism were investigated.The tests show that the formula of the wear resistant PA6 composite(WRPA 6)is PA6/GF/T/PTFE/Gr in the ratio of 100/15/5/10/5 by mass.Because this composite exhibits the lowest friction coefficient(0.1429)and no wear mass loss,the introduction of RP and ZB can increase the flame resistance of WRPA6,and the synergistic effect of RP and ZB is obtained.Detailedly,the composite with 4 parts of ZB and 12 parts of RP shows the best flame retardant property,achieving the highest limiting oxygen index(LOI)(30.2 vol%)and a UL94 V-0 rating,and the flame retardant mechanisms may be gas phase along with condense phase mechanism.
基金the Ministry of Economic Development and Trade of Government of Alberta for the Campus Alberta Innovation Program (CAIP) Research Chair (RCP-12-001BCAIP)
文摘As resource scarcity, extreme climate change, and pollution levels increase, economic growth must rely on more environmentally friendly and efficient production processes, Fuel cells are an ideal alternative to internal combustion （IC） engines and boilers on the path to greener industries because of their high effi- ciency and environmentally friendly operation, However, as a new energy technology, significant market penetration of fuel cells has not yet been achieved, In this paper, we perform a techno-economic and environmental analysis of fuel cell systems using life cycle and value chain activities, First, we investigate the procedure of fuel cell development and identify what activities should he undertaken according to fuel cell life cycle activities, value chain activities, and end-user acceptance criteria, Next, we present a unified learning of the institutional barriers in fuel cell commercialization, The primary end-user accep- tance criteria are function, cost, and reliability; a fuel cell should outperform these criteria compared with its competitors, such as IC engines and batteries, to achieve a competitive advantage, The repair and maintenance costs of fuel cells （due to low reliability） can lead to a substantial cost increase and decrease in availability, which are the major factors for end-user acceptance, The fuel cell industry must face the challenge of how to overcome this reliability barrier, This paper provides a deeper insight into our work over the years on the main barriers to fuel cell commercialization, and discusses the potential pivotal role of fuel cells in a future low-carbon green economy, It also identifies the needs and points out some direc- tions for this future low-carbon economy, Green energy, supplied with fuel cells, is truly the business mode of the future, Striving for a more sustainable development of economic growth by adopting green public investments and implementing policy initiatives encourages environmentally responsible indus- trial investments.
文摘Interest in thorium stems mainly from the fact that it is expected to have a substantial increase in uranium prices. So, advanced fuel cycles which increase the reserves of nuclear materials are interesting, particularly, the use of thorium is to produce the fissile isotope ^233U. Thorium is three to five times more abundant than uranium in the earth＇s crust. Additionally, thoria produces less radiotoxicity than the UO2, because it produces fewer amounts of actinides. ThO2 has higher corrosion resistance, besides being chemically stable, and the burning of Pu in a reactor based in thorium also decreases the inventories of Pu from the current fuel cycles. There are some ongoing projects in the world, taking into consideration the proposed goals for Generation IV reactors, namely： sustainability, economics, safety and reliability, proliferation resistance and physical protection. Some developments on the use of thorium in reactors are underway, with the support of the IAEA （International Atomic Energy Agency） and some govern like molten salt reactor. In this paper, we discuss the future importance of thorium, particularly for Brazil, which has large mineral reserves of this strategic element, the characteristics of the molten salt reactor and the experience of the IPEN （Instituto de Pesquisas Energ6ticas e Nucleares） in the purification of thorium compounds.
