The microstructure and corrosion resistance of different boric/sulfuric acid anodic（BSAA） films on 7050 aluminum alloy were studied by atomic force microscopy（AFM）,electrochemical impedance spectroscopy（EIS） and...The microstructure and corrosion resistance of different boric/sulfuric acid anodic（BSAA） films on 7050 aluminum alloy were studied by atomic force microscopy（AFM）,electrochemical impedance spectroscopy（EIS） and scanning Kelvin probe（SKP）.The results show that boric acid does not change the structure of barrier layer of anodic film,but will significantly affect the structure of porous layer,consequently affect the corrosion resistance of anodic film.As the content of boric acid in electrolyte increases from 0 to 8 g/L,the resistance of porous layer（Rp） of BSAA film increases,the capacitance of porous layer（CPEp） decreases,the surface potential moves positively,the pore size lessens,and the corrosion resistance improves.However,the Rp,CPEp and surface potential will change towards opposite direction when the content of boric acid is over 8 g/L.展开更多
The use of a constrained groove pressing(CGP) method to plastically deform AA6063 aluminum alloy led to the improved surface properties. It was found that hardness magnitude is dramatically improved and its uniformity...The use of a constrained groove pressing(CGP) method to plastically deform AA6063 aluminum alloy led to the improved surface properties. It was found that hardness magnitude is dramatically improved and its uniformity is considerably decreased after the first pass, while subsequent passes result in better hardness behavior for the processed material. Also, the elongated grains formed in the first pass of the CGP are gradually converted to the equiaxed counterparts by adding pass numbers. Eventually, higher corrosion resistance of the sample by imposing the CGP process is related to the quick formation of passivation film and the change in the morphology of the second phase and precipitates which hinder their electrochemical reactions and decrease the potential localized attack sites.展开更多
Friction stir welding (FSW) with water cooling and air cooling was used to weld 2219-T62 aluminum alloy joints with a thickness of 20 mm. The effect of cooling conditions on the corrosion resistance of joints in 3.5% ...Friction stir welding (FSW) with water cooling and air cooling was used to weld 2219-T62 aluminum alloy joints with a thickness of 20 mm. The effect of cooling conditions on the corrosion resistance of joints in 3.5% NaCl solution was investigated using the open circuit potential (OCP), the potentiodynamic polarization, and the corrosion morphology after immersing for different time. And the precipitates distribution was characterized by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The results reveal that the weld nugget zone (WNZ) owning positive potential, lower corrosion current density and fine and uniform precipitates, is much more difficult to corrode than the heat affected zone (HAZ) and the base metal (BM). Compared with air-cooled joint, the water-cooled joint has better corrosion resistance. In addition, the results of microstructure observation show that the potential, distribution and size of second phase particles determine the corrosion resistance of FSW AA2219 alloy joints in chlorine-contained solution.展开更多
The Al-3.40Mg-1.08Sc alloy plates were manufactured by selective laser melting(SLM) at platform temperatures of 35 ℃ and 200 ℃, respectively, and the corrosion performance of them was studied along height direction....The Al-3.40Mg-1.08Sc alloy plates were manufactured by selective laser melting(SLM) at platform temperatures of 35 ℃ and 200 ℃, respectively, and the corrosion performance of them was studied along height direction. The results show that the corrosion resistance of the alloy plate built at platform temperature of 35 ℃ along height direction is basically the same due to a uniform microstructure;While the corrosion resistance of the alloy plate built at platform temperature of 200 ℃ along height direction is different. The evolution of microstructure and the distribution of secondary phases are investigated, and the results show that the Cu-rich phases in alloy play a key role on corrosion performance. At higher platform temperature, the cooling rate is relative slow and a certain degree of in situ ageing leads to the significantly different distribution of Cu-rich phases along grain boundary. Specimens built at the platform temperature of 200 ℃ are inclined to locate at the crossed grain boundary, rather than continuous segregation of Cu-rich phases along grain boundary that is built at platform temperature of 35 ℃. Therefore, the corrosion resistance of Al-3.40Mg-1.08Sc alloy plate manufactured at platform temperature of 200 ℃ is higher, and presents a gradually decreasing trend along height direction.展开更多
文摘The microstructure and corrosion resistance of different boric/sulfuric acid anodic（BSAA） films on 7050 aluminum alloy were studied by atomic force microscopy（AFM）,electrochemical impedance spectroscopy（EIS） and scanning Kelvin probe（SKP）.The results show that boric acid does not change the structure of barrier layer of anodic film,but will significantly affect the structure of porous layer,consequently affect the corrosion resistance of anodic film.As the content of boric acid in electrolyte increases from 0 to 8 g/L,the resistance of porous layer（Rp） of BSAA film increases,the capacitance of porous layer（CPEp） decreases,the surface potential moves positively,the pore size lessens,and the corrosion resistance improves.However,the Rp,CPEp and surface potential will change towards opposite direction when the content of boric acid is over 8 g/L.
基金funded by“Quality Engineering Project of Anhui Province of China in 2016”entitled mold design and manufacturing experimental training center(2016sxzx050)。
文摘The use of a constrained groove pressing(CGP) method to plastically deform AA6063 aluminum alloy led to the improved surface properties. It was found that hardness magnitude is dramatically improved and its uniformity is considerably decreased after the first pass, while subsequent passes result in better hardness behavior for the processed material. Also, the elongated grains formed in the first pass of the CGP are gradually converted to the equiaxed counterparts by adding pass numbers. Eventually, higher corrosion resistance of the sample by imposing the CGP process is related to the quick formation of passivation film and the change in the morphology of the second phase and precipitates which hinder their electrochemical reactions and decrease the potential localized attack sites.
基金Project (51405392) supported by the National Natural Science Foundation of ChinaProject (2019T120954) supported by the China Postdoctoral Science Foundation+1 种基金Project (3102019MS0404) supported by Fundamental Research Funds for the Central Universities, ChinaProject (2018BSHQYXMZZ31) supported by the Postdoctoral Science Foundation of Shaanxi Province, China。
文摘Friction stir welding (FSW) with water cooling and air cooling was used to weld 2219-T62 aluminum alloy joints with a thickness of 20 mm. The effect of cooling conditions on the corrosion resistance of joints in 3.5% NaCl solution was investigated using the open circuit potential (OCP), the potentiodynamic polarization, and the corrosion morphology after immersing for different time. And the precipitates distribution was characterized by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The results reveal that the weld nugget zone (WNZ) owning positive potential, lower corrosion current density and fine and uniform precipitates, is much more difficult to corrode than the heat affected zone (HAZ) and the base metal (BM). Compared with air-cooled joint, the water-cooled joint has better corrosion resistance. In addition, the results of microstructure observation show that the potential, distribution and size of second phase particles determine the corrosion resistance of FSW AA2219 alloy joints in chlorine-contained solution.
基金Project(51901207) supported by the National Natural Science Foundation of ChinaProject(2018M632796) supported by the China Postdoctoral Science FoundationProjects(19A430024, 21A430037) supported by the Plan of Henan Key Scientific Research Project of Universities,China。
文摘The Al-3.40Mg-1.08Sc alloy plates were manufactured by selective laser melting(SLM) at platform temperatures of 35 ℃ and 200 ℃, respectively, and the corrosion performance of them was studied along height direction. The results show that the corrosion resistance of the alloy plate built at platform temperature of 35 ℃ along height direction is basically the same due to a uniform microstructure;While the corrosion resistance of the alloy plate built at platform temperature of 200 ℃ along height direction is different. The evolution of microstructure and the distribution of secondary phases are investigated, and the results show that the Cu-rich phases in alloy play a key role on corrosion performance. At higher platform temperature, the cooling rate is relative slow and a certain degree of in situ ageing leads to the significantly different distribution of Cu-rich phases along grain boundary. Specimens built at the platform temperature of 200 ℃ are inclined to locate at the crossed grain boundary, rather than continuous segregation of Cu-rich phases along grain boundary that is built at platform temperature of 35 ℃. Therefore, the corrosion resistance of Al-3.40Mg-1.08Sc alloy plate manufactured at platform temperature of 200 ℃ is higher, and presents a gradually decreasing trend along height direction.
