Substance flow analysis was applied to analyzing the lead emissions in 2010. It turns out that in 2010, for every 1 kg of lead consumed, 0.48 kg lead is lost into the environment. The emissions in 2010 were estimated ...Substance flow analysis was applied to analyzing the lead emissions in 2010. It turns out that in 2010, for every 1 kg of lead consumed, 0.48 kg lead is lost into the environment. The emissions in 2010 were estimated to be 1.89×10^6 t, which were mainly from use （39.20%） and waste management＆recycling （33.13%）. The accumulative lead in 1960-2010 from the anthropogenic flow was estimated and the results show that the total accumulative lead in this period amounted to 19.54×10^6 t, which was equivalent to 14.26 kg and 2.04 g/m^2 at the present population and territory.展开更多
In this paper we discuss neural network-based matrix effect correction in energy dispersive X-ray fluorescence (EDXRF) analysis,with detailed algorithm to classify the samples.The method can correct the matrix effect ...In this paper we discuss neural network-based matrix effect correction in energy dispersive X-ray fluorescence (EDXRF) analysis,with detailed algorithm to classify the samples.The method can correct the matrix effect effectively through classifying the samples automatically,and influence of X-ray absorption and enhancement by major elements of the samples is reduced.Experiments for the complex matrix effect correction in EDXRF analysis of samples in Pangang showed improved accuracy of the elemental analysis result.展开更多
This study examines oblique wave motion over multiple submerged porous bars in front of a vertical wall. Based on linear potential theory, an analytical solution for the present problem is developed using matched eige...This study examines oblique wave motion over multiple submerged porous bars in front of a vertical wall. Based on linear potential theory, an analytical solution for the present problem is developed using matched eigenfunction expansions. A complex dispersion relation is adopted to describe the wave elevation and energy dissipation over submerged porous bars. In the analytical solution, no limitations on the bar number, bar size, and spacing between adjacent bars are set. The convergence of the analytical solution is satisfactory, and the correctness of the analytical solution is confirmed by an independently developed multi-domain BEM （boundary element method） solution. Numerical examples are presented to examine the reflection and transmission coefficients of porous bars, CR and Cv, respectively, for engineering applications. The calculation results show that when the sum of widths for all the porous bars is fixed, increasing the bar number can significantly improve the sheltering function of the bars. Increasing the bar height can cause more wave energy dissipation and lower CR and Cr. The spacing between adjacent bars and the spacing between the last bar and the vertical wall are the key parameters affecting CR and Ct. The proposed analytical method may be used to analyze the hydrodynamic performance of submerged porous bars in preliminary engineering designs.展开更多
A theoretical and numerical study has been performed on an air film dumper attached to a plate structure. Combined with the analysis by Fox and Whittorg a damping model of the air fiim damper has been developed. A com...A theoretical and numerical study has been performed on an air film dumper attached to a plate structure. Combined with the analysis by Fox and Whittorg a damping model of the air fiim damper has been developed. A complex stiffness was introduced to represent the air pressure in the damper cavity. The stain energy and dissipated energy were integrated from the real part and imaginary part of the complex stiffness to determine the stiffness and damping. The response of the plate with the air film damper was considered by treating the air film as multiple discrete damping-stiffness elements using ANSYS.展开更多
Umbrella-shaped assembly of cylindrical fins is optimized by adopting analytical method and taking dimensionless mean thermal resistance (MTR) as performance index. The optimal construct of umbrella-shaped assembly is...Umbrella-shaped assembly of cylindrical fins is optimized by adopting analytical method and taking dimensionless mean thermal resistance (MTR) as performance index. The optimal construct of umbrella-shaped assembly is obtained. The results show that the heat conductance performance of the assembly becomes ever worse with ever greater number of elemental cylindrical fins,the umbrella-shaped assembly reduces to cylindrical fin in some values of design parameters,and the diameters’ dependence on design parameters is weak for the optimized assembly. An equivalent thermal resistance defined based on entransy dissipation rate (EDR) reflects an average heat transfer effect of the assembly. The constructal design corresponding to the minimum EDR (or MTR) should be adopted for designing an assembly of fins in engineering at the limit safe condition.展开更多
A model of non-uniform height rectangular fin, in which the variation of base's thickness and width are taken into account, is established in this paper. The dimensionless maximum thermal resistance(DMTR) and the ...A model of non-uniform height rectangular fin, in which the variation of base's thickness and width are taken into account, is established in this paper. The dimensionless maximum thermal resistance(DMTR) and the dimensionless equivalent thermal resistance(DETR) defined based on the entransy dissipation rate(EDR) are taken as performance evaluation indexes. According to constructal theory, the variations of the two indexes with the geometric parameters of the fin are analyzed by using a finite-volume computational fluid dynamics code, the effects of the fin-material fraction on the two indexes are analyzed. It is found that the two indexes decrease monotonically as the ratio between the front height and the back height of the fin increases subjected to the non-uniform height rectangular fin. When the model is reduced to the uniform height fin, the two indexes increase first and then decrease with increase in the ratio between the height of the fin and the fin space. The fin-material fraction has no effect on the change rule of the two indexes with the ratio between the height of the fin and the fin space. The sensitivity of the DETR to the geometric parameters of the fin is higher than that of the DMTR to the geometric parameters. The results obtained herein can provide some theoretical support for the thermal design of rectangular fins.展开更多
The thermodynamic systems and dynamic model suitable for determining the nonlinear chemical fingerprints of samples were analyzed.The results indicated that the damp nonlinear chemical reactions in close systems away ...The thermodynamic systems and dynamic model suitable for determining the nonlinear chemical fingerprints of samples were analyzed.The results indicated that the damp nonlinear chemical reactions in close systems away from the equilibrium and open systems without the complementarity of the dissipation substances have important significance for the throng characterization and whole content analysis of chemical components in samples.Various factors influencing on nonlinear chemical fingerprint,such as reactant species and their concentrations,electrode types,temperature,stir rate,the sort,dosage and granularity of the sample,etc.were amply researched by a nonlinear chemistry reaction,namely,damp B-Z oscillation which used acetone and glucose as the main dissipative substances.In addition,the quantitative information on the whole of chemical components in samples and the traits and applications of the fingerprint were investigated.The method and its important conditions for determining nonlinear chemistry fingerprint used in distinguishing and evaluating complex samples were successfully put forward.展开更多
Layered double hydroxides （LDHs） are effective molecular carriers in cytological research, gene therapy, and transgenic applications. Herein, we investigated the internalization behavior of the LDH-DNA biocon- jugat...Layered double hydroxides （LDHs） are effective molecular carriers in cytological research, gene therapy, and transgenic applications. Herein, we investigated the internalization behavior of the LDH-DNA biocon- jugates via a microscopic approach and analyzed the internalization pathway by dissipative particle dynamics （DPD） simulations. We experimentally found that LDH can efficiently carry DNA into the nucleus of cell in BY-2 suspension cells. Furthermore, atomic force microscopy and X-ray diffraction anal- ysis demonstrated that the LDH-DNA bioconjugates mainly exist as a DNA-LDH-DNA sandwich complex, while the LDH-DNA-LDH sandwich complex and DNA-LDH complex cannot be excluded. The DPD simu- lations further indicated that only the DNA-LDH-DNA sandwich structure could penetrate the plasma membrane （PM）, while PM is impermeable to the LDH-DNA-LDH sandwich complex and the DNA-LDH complex. This work provides novel perspective for understanding the membrane penetration mechanism of LDH nano-sheets and new insights into the design of novel molecular delivery systems.展开更多
基金Project (41171361) supported by the National Natural Science Foundation of China
文摘Substance flow analysis was applied to analyzing the lead emissions in 2010. It turns out that in 2010, for every 1 kg of lead consumed, 0.48 kg lead is lost into the environment. The emissions in 2010 were estimated to be 1.89×10^6 t, which were mainly from use （39.20%） and waste management＆recycling （33.13%）. The accumulative lead in 1960-2010 from the anthropogenic flow was estimated and the results show that the total accumulative lead in this period amounted to 19.54×10^6 t, which was equivalent to 14.26 kg and 2.04 g/m^2 at the present population and territory.
基金supported by the National Natural Science Foundation of China (No.40574059)the Ministry of Education (No.NCET-04-0904)
文摘In this paper we discuss neural network-based matrix effect correction in energy dispersive X-ray fluorescence (EDXRF) analysis,with detailed algorithm to classify the samples.The method can correct the matrix effect effectively through classifying the samples automatically,and influence of X-ray absorption and enhancement by major elements of the samples is reduced.Experiments for the complex matrix effect correction in EDXRF analysis of samples in Pangang showed improved accuracy of the elemental analysis result.
基金supported by the National Natural Science Foundation of China(Nos.51490675,51322903 and 51279224.)
文摘This study examines oblique wave motion over multiple submerged porous bars in front of a vertical wall. Based on linear potential theory, an analytical solution for the present problem is developed using matched eigenfunction expansions. A complex dispersion relation is adopted to describe the wave elevation and energy dissipation over submerged porous bars. In the analytical solution, no limitations on the bar number, bar size, and spacing between adjacent bars are set. The convergence of the analytical solution is satisfactory, and the correctness of the analytical solution is confirmed by an independently developed multi-domain BEM （boundary element method） solution. Numerical examples are presented to examine the reflection and transmission coefficients of porous bars, CR and Cv, respectively, for engineering applications. The calculation results show that when the sum of widths for all the porous bars is fixed, increasing the bar number can significantly improve the sheltering function of the bars. Increasing the bar height can cause more wave energy dissipation and lower CR and Cr. The spacing between adjacent bars and the spacing between the last bar and the vertical wall are the key parameters affecting CR and Ct. The proposed analytical method may be used to analyze the hydrodynamic performance of submerged porous bars in preliminary engineering designs.
文摘A theoretical and numerical study has been performed on an air film dumper attached to a plate structure. Combined with the analysis by Fox and Whittorg a damping model of the air fiim damper has been developed. A complex stiffness was introduced to represent the air pressure in the damper cavity. The stain energy and dissipated energy were integrated from the real part and imaginary part of the complex stiffness to determine the stiffness and damping. The response of the plate with the air film damper was considered by treating the air film as multiple discrete damping-stiffness elements using ANSYS.
基金supported by the National Natural Science Foundation of China (Grant No.10905093)the Program for New Century Excellent Talents in University of China (Grant No.NCET-04-1006)the Foundation for the Author of National Excellent Doctoral Dissertation of China (Grant No.200136)
文摘Umbrella-shaped assembly of cylindrical fins is optimized by adopting analytical method and taking dimensionless mean thermal resistance (MTR) as performance index. The optimal construct of umbrella-shaped assembly is obtained. The results show that the heat conductance performance of the assembly becomes ever worse with ever greater number of elemental cylindrical fins,the umbrella-shaped assembly reduces to cylindrical fin in some values of design parameters,and the diameters’ dependence on design parameters is weak for the optimized assembly. An equivalent thermal resistance defined based on entransy dissipation rate (EDR) reflects an average heat transfer effect of the assembly. The constructal design corresponding to the minimum EDR (or MTR) should be adopted for designing an assembly of fins in engineering at the limit safe condition.
基金supported by the National Natural Science Foundation of China (Grant Nos. 51579244, 51506220 and 51356001)
文摘A model of non-uniform height rectangular fin, in which the variation of base's thickness and width are taken into account, is established in this paper. The dimensionless maximum thermal resistance(DMTR) and the dimensionless equivalent thermal resistance(DETR) defined based on the entransy dissipation rate(EDR) are taken as performance evaluation indexes. According to constructal theory, the variations of the two indexes with the geometric parameters of the fin are analyzed by using a finite-volume computational fluid dynamics code, the effects of the fin-material fraction on the two indexes are analyzed. It is found that the two indexes decrease monotonically as the ratio between the front height and the back height of the fin increases subjected to the non-uniform height rectangular fin. When the model is reduced to the uniform height fin, the two indexes increase first and then decrease with increase in the ratio between the height of the fin and the fin space. The fin-material fraction has no effect on the change rule of the two indexes with the ratio between the height of the fin and the fin space. The sensitivity of the DETR to the geometric parameters of the fin is higher than that of the DMTR to the geometric parameters. The results obtained herein can provide some theoretical support for the thermal design of rectangular fins.
基金supported by the National Key Technologies R & DProgram (2009GJD20033)the International Scientific and Technological Cooperation Project (2007DFA40680) from the Ministry of Scienceand Technology of China
文摘The thermodynamic systems and dynamic model suitable for determining the nonlinear chemical fingerprints of samples were analyzed.The results indicated that the damp nonlinear chemical reactions in close systems away from the equilibrium and open systems without the complementarity of the dissipation substances have important significance for the throng characterization and whole content analysis of chemical components in samples.Various factors influencing on nonlinear chemical fingerprint,such as reactant species and their concentrations,electrode types,temperature,stir rate,the sort,dosage and granularity of the sample,etc.were amply researched by a nonlinear chemistry reaction,namely,damp B-Z oscillation which used acetone and glucose as the main dissipative substances.In addition,the quantitative information on the whole of chemical components in samples and the traits and applications of the fingerprint were investigated.The method and its important conditions for determining nonlinear chemistry fingerprint used in distinguishing and evaluating complex samples were successfully put forward.
基金supported by the Fundamental Research Funds for the Central Universities (2016JX01, BLX2015-01)the National Natural Science Foundation of China (31671489, 31601149 and 31271433)+2 种基金the Beijing Nova Programme (Z131109000413013)the Special Program for Applied Research on Super Computation of the NSFC-Guangdong Joint Fundthe Chemical Grid Program and Excellent Talent of Beijing University of Chemical Technology
文摘Layered double hydroxides （LDHs） are effective molecular carriers in cytological research, gene therapy, and transgenic applications. Herein, we investigated the internalization behavior of the LDH-DNA biocon- jugates via a microscopic approach and analyzed the internalization pathway by dissipative particle dynamics （DPD） simulations. We experimentally found that LDH can efficiently carry DNA into the nucleus of cell in BY-2 suspension cells. Furthermore, atomic force microscopy and X-ray diffraction anal- ysis demonstrated that the LDH-DNA bioconjugates mainly exist as a DNA-LDH-DNA sandwich complex, while the LDH-DNA-LDH sandwich complex and DNA-LDH complex cannot be excluded. The DPD simu- lations further indicated that only the DNA-LDH-DNA sandwich structure could penetrate the plasma membrane （PM）, while PM is impermeable to the LDH-DNA-LDH sandwich complex and the DNA-LDH complex. This work provides novel perspective for understanding the membrane penetration mechanism of LDH nano-sheets and new insights into the design of novel molecular delivery systems.
