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污泥-废水2相湍流与生物反应耦合模型及应用 被引量:4
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作者 许丹宇 张代钧 +2 位作者 唐运平 郭丽莎 陈园 《应用基础与工程科学学报》 EI CSCD 2010年第5期723-733,共11页
建立污泥-废水2相湍流与生物反应动力学耦合模型,实现对反应器污水两相3维流场及浓度场的同时模拟.采用活性污泥2号模型(ASM2)描述运输方程中的反应速率项、两相流混合物模型描述活性污泥-废水2相湍流的水力特性,并纳入污泥沉降运动;通... 建立污泥-废水2相湍流与生物反应动力学耦合模型,实现对反应器污水两相3维流场及浓度场的同时模拟.采用活性污泥2号模型(ASM2)描述运输方程中的反应速率项、两相流混合物模型描述活性污泥-废水2相湍流的水力特性,并纳入污泥沉降运动;通过数字粒子图像测速研究紊动条件下污泥沉降特性,对传统污泥沉降模型进行水力湍动影响修正,实测污水处理厂氧化沟流场与组分浓度以验证模型,数值模拟了不同曝气方式下氧化沟污泥-废水2相流场与水质,结果表明:流速是影响污泥沉积和水质浓度分布的主要因素,曝气方式的差异直接影响出水效果,在所研究的污水厂中采用半日间歇曝气方式运行,可提高出水效果,并降低能耗约23.84%. 展开更多
关键词 湍流-生物反应耦合模型 污泥沉降速率湍流修正 流场和组分分布 数字粒子图像测速 卡鲁塞尔氧化沟
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细菌堆浸中流动-反应-传热耦合过程数值模拟分析 被引量:1
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作者 吴爱祥 刘金枝 +1 位作者 尹升华 王洪江 《应用数学和力学》 EI CSCD 北大核心 2010年第12期1393-1400,共8页
针对辉铜矿微生物浸出过程进行数学建模,利用Comsol Multiphysics软件对浸堆中热量传递、氧气流动、目的金属离子分布以及氧化转化率等进行数值模拟分析.结果表明:沿堆体斜坡边界处氧的浓度较大,而在堆的中央部分,氧气的浓度非常小,导... 针对辉铜矿微生物浸出过程进行数学建模,利用Comsol Multiphysics软件对浸堆中热量传递、氧气流动、目的金属离子分布以及氧化转化率等进行数值模拟分析.结果表明:沿堆体斜坡边界处氧的浓度较大,而在堆的中央部分,氧气的浓度非常小,导致这部分区域浸出反应缓慢;沿浸堆边坡处的温度偏低,温度最高的部分在底部区域附近靠近边坡位置处,且温度升高值超过6℃;矿堆底部靠近边坡区域目的金属离子浓度最高;靠近底部和斜坡部分,浸出反应速率快、氧化转化率高.矿堆的其余部分,因氧浓度低,导致浸出反应速率缓慢、氧化转化率低. 展开更多
关键词 堆浸 流动-反应-传热耦合模型 细菌浸出 数值模拟
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锂离子电池硅电极的电化学-扩散耦合模型 被引量:1
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作者 王飞 周剑秋 《电力学报》 2020年第3期187-199,共13页
通过应力辅助扩散模型建立了在表面效应和位错效应共同影响下的反应-扩散应力耦合模型,对圆柱形纳米材料在锂离子电池电极中的电化学-机械行为进行了探索研究。该模型可以捕获在恒电流/电压充电情况下,电极纳米材料中电极表面效应、位... 通过应力辅助扩散模型建立了在表面效应和位错效应共同影响下的反应-扩散应力耦合模型,对圆柱形纳米材料在锂离子电池电极中的电化学-机械行为进行了探索研究。该模型可以捕获在恒电流/电压充电情况下,电极纳米材料中电极表面效应、位错效应、电化学反应和扩散之间的关系。同时研究在不同无量纲充电时间下电化学反应应力与电极尺寸和反应扩散相对速率的关系,以及反应-扩散应力受表面效应和位错效应影响时,在不同电极尺寸下的变化情况。数值计算结果表明,表面效应和位错效应综合作用会在电极材料中产生额外的应力场,使反应-扩散耦合模型的应力急剧减小,甚至使电极材料的应力状态由原本的拉伸状态变为压缩状态。这样的结果增加了电极的机械稳定性,同时为锂离子电池更高的充放电速率提供了可能。 展开更多
关键词 锂离子电池 应力缩减 反应-扩散耦合模型 表面效应 位错效应
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Coupled effect of cement hydration and temperature on rheological properties of fresh cemented tailings backfill slurry 被引量:6
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作者 吴迪 蔡嗣经 黄刚 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2014年第9期2954-2963,共10页
The fluidity of fresh cemented tailings backfill(CTB) slurry depends on its rheological properties. Hence, it is crucial to understand the rheology of fresh CTB slurry, which is related to the cement hydration progr... The fluidity of fresh cemented tailings backfill(CTB) slurry depends on its rheological properties. Hence, it is crucial to understand the rheology of fresh CTB slurry, which is related to the cement hydration progress and temperature evolution within CTB mixtures. For this reason, a numerical model was developed to predict the evolution of the rheological properties of fresh CTB slurry under the coupled effect of cement hydration and temperature. Experiments were conducted to investigate the rheological behaviours of the fresh CTB slurry. By comparing the simulated results with the experimental ones, the availability of this developed model was validated. Thereafter, the model was used to demonstrate the coupled effect of cement hydration and temperature on the evolution of fresh CTB slurry's rheological properties, under various conditions(initial CTB temperature, cement to tailings ratio, and water to cement ratio). The obtained results are helpful to better understanding the rheology of CTB slurry. 展开更多
关键词 cemented tailings backfill(CTB) HYDRATION temperature rheology coupled model
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堆浸工艺中流动-反应-传热耦合过程数值模拟 被引量:2
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作者 刘金枝 黄冬梅 吴爱祥 《湖南科技大学学报(自然科学版)》 CAS 北大核心 2009年第3期23-26,共4页
通过建立一组瞬态的流、固、热全耦合方程组,对浸出过程中浸堆内的温度、氧相对浓度、目的金属离子浓度等分布进行数值模拟.分析结果表明:沿堆体斜坡边界处氧的浓度较大,而在堆的中央部分,氧气的浓度非常小,导致这部分区域浸出反应缓慢... 通过建立一组瞬态的流、固、热全耦合方程组,对浸出过程中浸堆内的温度、氧相对浓度、目的金属离子浓度等分布进行数值模拟.分析结果表明:沿堆体斜坡边界处氧的浓度较大,而在堆的中央部分,氧气的浓度非常小,导致这部分区域浸出反应缓慢;沿浸堆边坡处的温度偏低,温度最高的部分在底部区域附近靠近边坡位置处,且温度升高值超过6℃;矿堆底部靠近边坡区域目的金属离子浓度最高.本文的数学建模与数值模拟方法对研究城市风暴潮洪水演进过程具有指导意义.图4,表1,参9. 展开更多
关键词 堆浸 流动-反应-传热耦合模型 风暴潮洪水模型 数值模拟
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Coupled simulation of recirculation zonal firebox model and detailed kinetic reactor model in an industrial ethylene cracking furnace 被引量:8
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作者 Zhou Fang Tong Qiu Weiguo Zhou 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2017年第8期1091-1100,共10页
A coupled system simulating both firebox and reactor is established to study the naphtha pyrolysis in an industrial tubular furnace.The firebox model is based on zone method including combustion,radiation,and convecti... A coupled system simulating both firebox and reactor is established to study the naphtha pyrolysis in an industrial tubular furnace.The firebox model is based on zone method including combustion,radiation,and convection to simulate heat transfer in the furnace.A two-dimensional recirculation model is proposed to estimate the flow field in furnace.The reactor model integrates the feedstock reconstruction model,an auto-generator of detail kinetic schemes,and the reactor simulation model to simulate the reaction process in the tubular coil.The coupled simulation result is compared with industrial process and shows agreement within short computation time. 展开更多
关键词 Ethylene cracking Coupled simulation Tubular furnace Recirculation zone modeling Detailed reaction kinetic
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Mathematical model for coupled reactive flow and solute transport during heap bioleaching of copper sulfide 被引量:5
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作者 尹升华 吴爱祥 +1 位作者 李希雯 王贻明 《Journal of Central South University》 SCIE EI CAS 2011年第5期1434-1440,共7页
Based on the momentum and mass conservation equations, a comprehensive model of heap bioleaching process is developed to investigate the interaction between chemical reactions, solution flow, gas flow, and solute tran... Based on the momentum and mass conservation equations, a comprehensive model of heap bioleaching process is developed to investigate the interaction between chemical reactions, solution flow, gas flow, and solute transport within the leaching system. The governing equations are solved numerically using the COMSOL Multiphysics software for the coupled reactive flow and solute transport at micro-scale, meso-scale and macro-scale levels. At or near the surface of ore particle, the acid concentration is relatively higher than that in the central area, while the concentration gradient decreases after 72 d of leaching. The flow simulation between ore particles by combining X-ray CT technology shows that the highest velocity in narrow pore reaches 0.375 m/s. The air velocity within the dump shows that the velocity near the top and side surface is relatively high, which leads to the high oxygen concentration in that area. The coupled heat transfer and liquid flow process shows that the solution can act as an effective remover from the heap, dropping the highest temperature from 60 to 38 ℃. The reagent transfer coupled with solution flow is also analyzed. The results obtained allow us to obtain a better understanding of the fundamental physical phenomenon of the bioleaching process. 展开更多
关键词 copper sulphide heap bioleaching leaching reaction solution flow solute transport
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The Neural Network Model for Backflushing in Enzymatic Membrane Reactor
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作者 何志敏 董春华 齐崴 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2005年第6期809-815,共7页
In the enzymatic membrane reactor for separating casein hydrolysate, backflushing technology has been used to decrease the fouling of the membrane. Predication of the backflushing efficiency poses a complex non-linear... In the enzymatic membrane reactor for separating casein hydrolysate, backflushing technology has been used to decrease the fouling of the membrane. Predication of the backflushing efficiency poses a complex non-linear problem as the system integrates enzymatic hydrolysis, membrane separation and periodic backflushing together. In this paper an alternative artificial neural network approach is developed to predict the backflushing efficiency as a function of duration and interval. A contour plot of backflushing performance is presented to model these effects, and the backflushing conditions have been optimized as duration of 10 s and interval of 10 min using this neural network. Also, simple neural networks are established to predict the time evolution of flux before and after backflushing. The results predicted by the models are in good agreement with the experimental data, and the average deviations for all the cases are well within ±5%. The neural network approach is found to be capable of modeling the backflushing with confidence. 展开更多
关键词 BACKFLUSHING neural network MODEL optimize PREDICT CASEIN
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化学反应-传热耦合体系中涨落展布指数的临界突跃律及其对耗散的效应
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作者 林风 赵南蓉 罗久里 《中国科学:化学》 CAS CSCD 北大核心 2011年第9期1489-1497,共9页
建立了在Dirichlet或零流边界条件下一维气体化学反应-传热-扩散耦合系统的随机模型,并以此为基础,推广了以Fokker-Plank方程为基础的临界涨落量级分析理论,并进一步建立了该类体系的随机热力学.同时,以非等温非均匀Schlogl模型体系为例... 建立了在Dirichlet或零流边界条件下一维气体化学反应-传热-扩散耦合系统的随机模型,并以此为基础,推广了以Fokker-Plank方程为基础的临界涨落量级分析理论,并进一步建立了该类体系的随机热力学.同时,以非等温非均匀Schlogl模型体系为例,通过对相应的Fokker-Plank方程中漂移及扩散对概率分布演化之贡献的量级分析,论证了受制于化学反应-传热耦合的涨落展布指数的临界突跃律;发现临界涨落导致的耗散(涨落熵产生)已达决定性层次,不可避免将通过其热力学效应影响该类系统中进行的物理化学过程. 展开更多
关键词 化学反应-传热-扩散体系的随机模型化学反应-传热耦合 程的随机热力学 临界涨落展布指数 涨落熵产生 涨落-耗散效应
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低碳高钒铁水复吹提钒的动力学模拟
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作者 赵志民 罗林根 +4 位作者 邸久海 庞建明 方建锋 黄晓丽 张强 《钢铁钒钛》 CAS 北大核心 2019年第2期137-143,共7页
构建了耦合反应模型,此模型包括传氧模型和渣金界面反应模型,可模拟低碳高钒铁水复吹提钒的动力学特征。由模拟结果可知,在顶吹强度为2.0 m^3/(min·t)时,最佳冷料加入量为50 kg/t,此时吹氧9 min后,熔池温度为1 410℃,铁液钒含量由1... 构建了耦合反应模型,此模型包括传氧模型和渣金界面反应模型,可模拟低碳高钒铁水复吹提钒的动力学特征。由模拟结果可知,在顶吹强度为2.0 m^3/(min·t)时,最佳冷料加入量为50 kg/t,此时吹氧9 min后,熔池温度为1 410℃,铁液钒含量由1.2%至0.04%。 展开更多
关键词 低碳高钒铁水 复吹提钒 动力学模拟 耦合反应模型
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