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载铈凝胶型离子交换树脂/H_(2)O_(2)体系去除水中As(Ⅲ)特性 被引量:1
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作者 黄宇豪 单超 +1 位作者 张炜铭 潘丙才 《中国科学:技术科学》 EI CSCD 北大核心 2021年第12期1530-1540,共11页
地下水砷污染是重要的全球性环境问题.As(Ⅲ)是地下水中砷的主要价态,通常以电中性分子形式存在,难以通过常规水处理工艺有效去除.将As(Ⅲ)预氧化为As(V)再进一步吸附处理是高效除砷的有效策略.本文通过前体导入-原位沉淀法制备了兼具催... 地下水砷污染是重要的全球性环境问题.As(Ⅲ)是地下水中砷的主要价态,通常以电中性分子形式存在,难以通过常规水处理工艺有效去除.将As(Ⅲ)预氧化为As(V)再进一步吸附处理是高效除砷的有效策略.本文通过前体导入-原位沉淀法制备了兼具催化H_(2)O_(2)氧化和吸附功能的载铈凝胶型阴离子交换树脂纳米复合材料Ce-201×4,探究了Ce-201×4/H_(2)O_(2)体系去除As(Ⅲ)的特性和过程.XRD和SEM-EDS等表征表明,Ce-201×4负载的纳米铈氧化物主要为无定形,呈环状立体分布,负载后树脂的比表面积和孔容均增加了约33倍.静态批次实验表明,Ce-201×4/H_(2)O_(2)体系去除As(Ⅲ)吸附容量为121.4 mg/g,相较无H_(2)O_(2)的单一吸附体系提高了5.1倍,且Ce-201×4在有/无H_(2)O_(2)体系中吸附量均高于载铈大孔型离子交换树脂纳米复合材料Ce-D201.Ce-201×4/H_(2)O_(2)体系去除As(Ⅲ)效率随pH上升而提高,与H_(2)O_(2)在碱性条件下直接氧化As(Ⅲ)效率提高有关.Ce-201×4/H_(2)O_(2)体系除As(Ⅲ)抗硅酸盐干扰性能略优于Ce-D201/H_(2)O_(2)体系.静态再生实验表明,Ce-201×4/H_(2)O_(2)除As(Ⅲ)后材料再生性能良好,适宜长期循环使用.XPS分析表明,Ce-201×4/H_(2)O_(2)体系去除As(Ⅲ)的机理主要包括纳米氧化铈催化H_(2)O_(2)将As(Ⅲ)氧化为As(V)并通过离子交换和专属吸附等作用从水中进一步去除的过程. 展开更多
关键词 地下水除砷 纳米复合材料 耦合型功能材料 催化氧化 吸附
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Coupled thermal-mechanical analysis of two ITER-like first wall mockups under heat shock of plasma disruptions
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作者 HUANG ShengHong ZHAO YongQiang WANG WeiHua 《Science China(Technological Sciences)》 SCIE EI CAS CSCD 2016年第3期476-487,共12页
The first wall of the fusion reactor is a plasma-facing component and is a key link to maintain the integrity of structure during thermal shock induced by plasma disruptions. Be and W/Cu functionally graded materials ... The first wall of the fusion reactor is a plasma-facing component and is a key link to maintain the integrity of structure during thermal shock induced by plasma disruptions. Be and W/Cu functionally graded materials are two kinds of important plas- ma-facing materials (PFM) of first wall in fusion reactor currently. Previous researches seldom comparatively evaluated the normal servicing and heat shock resistance performance of first walls with those two kinds of PFMs. And also there lacks cou- pled thermal/mechanical analysis on the heat shock process in consideration of multiple thermal/mechanical phenomena, such as material melting, solidification, evaporation, etc., which is significant to further understand the heat shock damage mecha- nism of the first wall with different PFMs. With the aim of learning more detailed mechanical mechanism of thermal shock damage and then improving the thermal shock resistance performance of different first wall designs, the coupled ther- mal/mechanical response of two typical ITER-like first walls with PFM of Be and functionally graded W-Cu respectively un- der the heat shock of 1 2 GW/m2 are computed by the finite element method. Special considerations of elastic-plastic defor- mation, material melting, and solidification are included in numerical models and methods. The mechanical response behaviors of different structures and materials under the normal servicing operation as well as plasma disruption conditions are analyzed and investigated comparatively. The results reveal that heat is mainly deposited on the PFM layer in thc high energy shock pulse induced by plasma disruptions, resulting in complex thermal stress change as well as mechanical itTeversible damage of thermal elastic and plastic expansion, contraction and yielding. Compared with the first wall with Be PFM, which mitigates the damages from heat shock at most only in the PFM layer with cost of whole PFM layer plastic yielding, the first wall with graded W-Cu PFM is demonstrated to be possessed both of higher heat shock resistance performance and normal servicing performance, provided its material gradient and cooling capacity are well optimized under practical loading conditions. 展开更多
关键词 first wall plasma facing component plasma disruptions thermal shock resistance finite element method
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