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求耦合表的简便方法
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作者 傅丰林 谌骏 《西安电子科技大学学报》 EI CAS CSCD 北大核心 1995年第3期339-342,共4页
C.C.Wu提出了根据灵敏度计算耦合在的方法,但这种方法计算复杂,文中提出了一种直接由伪电路方程得出耦合表的简便方法。
关键词 伪电路法 故障诊断 耦合表 模拟电路
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无限大导体表面孔缝耦合电磁能量分析 被引量:3
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作者 曹祥玉 梁昌洪 +1 位作者 项铁铭 宗卫华 《电波科学学报》 EI CSCD 2002年第4期418-421,425,共5页
为有效设计电子设备 ,有必要了解它的最坏电磁工作环境 ,知道有多少电磁场通过耦合进入系统。采用矩量法分析了任意平面波通过无限大平板上小孔耦合的电磁能量 ,计算了电磁波通过小孔耦合能量传输系数。
关键词 无限大导体 面孔缝耦合 电磁能量 矩量法 小孔耦合 传输系数 电磁兼容
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Large Scale Homogeneous Growth Mechanics of Microcrystalline Silicon Films on Rough Surface
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作者 赵文锋 陈俊芳 +5 位作者 王燕 孟然 赵益冉 邵士运 李继宇 张宇 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2010年第4期447-450,I0002,共5页
Large scale homogenous growth of microcrystalline silicon (μ.c-Si:H) on cheap substrates by inductively coupled plasma (ICP) of Ar diluted Sill4 has been studied. From XRD and Raman spectrum, we find that substr... Large scale homogenous growth of microcrystalline silicon (μ.c-Si:H) on cheap substrates by inductively coupled plasma (ICP) of Ar diluted Sill4 has been studied. From XRD and Raman spectrum, we find that substrates can greatly affect the crystalline orientation, and the μc-Si:H films are comprised of small particles. Thickness detection by surface profilometry shows that the thin μc-Si:H films are homogenous in large scale. Distributions of both ion density and electron temperature are found to be uniform in the vicinity of substrate by means of diagnosis of Langmuir probe. Based on these experimental results, it can be proposed that rough surfaces play important roles in the crystalline network formation and Ar can affect the reaction process and improve the characteristics of μc-Si:H films. Also, ICP reactor can deposit the thin film in large scale. 展开更多
关键词 Microcrystalline silicon film Inductively coupled plasma Rough surface
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Application of a Coupled Land Surface-Hydrological Model to Flood Simulation in the Huaihe River Basin of China 被引量:2
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作者 LI Min LIN Zhao-Hui +1 位作者 YANG Chuan-Guo SHAO Quan-Xi 《Atmospheric and Oceanic Science Letters》 CSCD 2014年第6期493-498,共6页
A hydrological simulation in the Huaihe River Basin(HRB) was investigated using two different models: a coupled land surface hydrological model(CLHMS), and a large-scale hydrological model(LSX-HMS). The NCEP-NCAR rean... A hydrological simulation in the Huaihe River Basin(HRB) was investigated using two different models: a coupled land surface hydrological model(CLHMS), and a large-scale hydrological model(LSX-HMS). The NCEP-NCAR reanalysis dataset and observed precipitation data were used as meteorological inputs. The simulation results from both models were compared in terms of flood processes forecasting during high flow periods in the summers of 2003 and 2007, and partial high flow periods in 2000. The comparison results showed that the simulated streamflow by CLHMS model agreed well with the observations with Nash-Sutcliffe coefficients larger than 0.76, in both periods of 2000 at Lutaizi and Bengbu stations in the HRB, while the skill of the LSX-HMS model was relatively poor. The simulation results for the high flow periods in 2003 and 2007 suggested that the CLHMS model can simulate both the peak time and intensity of the hydrological processes, while the LSX-HMS model provides a delayed flood peak. These results demonstrated the importance of considering the coupling between the land surface and hydrological module in achieving better predictions for hydrological processes, and CLHMS was proven to be a promising model for future applications in flood simulation and forecasting. 展开更多
关键词 coupled land surface-hydrological model flood simulation Huaihe River Basin flood detention and storage
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Seepage-stress coupling constitutive model of anisotropic soft rock 被引量:2
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作者 张向霞 杨林德 闫小波 《Journal of Central South University》 SCIE EI CAS 2009年第1期149-153,共5页
To provide a seepage-stress coupling constitutive model that can directly describe the seepage-stress coupling relationship, a series of one-dimensional seepage-stress coupling tests on two kinds of soft rock (argilla... To provide a seepage-stress coupling constitutive model that can directly describe the seepage-stress coupling relationship, a series of one-dimensional seepage-stress coupling tests on two kinds of soft rock (argillaceous siltstone and brown mudstone) were performed by using an MTS-815.02 tri-axial rock mechanics test system, with which the stress-strain curves according to the seepage variation were obtained. Based on the experimental results and by employing Hooke's law, the formulation of the coefficient of strain-dependent permeability was presented and introduced to establish a coupling model. In addition, the mathematical expression and the incremental formulation for coupling model were advanced, in which five parameters that can be respectively determined by using the experimental results were included. The calculated results show that the proposed coupling model is capable of simulating the stress-strain relationship with considering the seepage-stress coupling in the nonlinear elastic stage of two kinds of soft rock. 展开更多
关键词 soft rock stress--strain relation seepage-stress coupling constitutive model coefficient of permeability
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A New Ocean Mixed-Layer Model Coupled into WRF 被引量:4
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作者 WANG Zi-Qian DUAN An-Min 《Atmospheric and Oceanic Science Letters》 2012年第3期170-175,共6页
A new mesoscale air-sea coupled model (WRF- OMLM-Noh) was constructed based on the Weather Research and Forecasting (WRF) model and an improved Mellor-Yamada ocean mixed-layer model from Noh and Kim (OMLM-Noh). Throug... A new mesoscale air-sea coupled model (WRF- OMLM-Noh) was constructed based on the Weather Research and Forecasting (WRF) model and an improved Mellor-Yamada ocean mixed-layer model from Noh and Kim (OMLM-Noh). Through off-line tests and a simulation of a real typhoon, the authors compared the performance of the WRF-OMLM-Noh with another existing ocean mixed-layer coupled model (WRF-OMLM-Pollard). In the off-line tests with Tropical Ocean Global Atmosphere Program's Coupled Ocean Atmosphere Response Experiment (TOGA-COARE) observational data, the results show that OMLM-Noh is better able to simulate sea surface temperature (SST) variational trends than OMLM -Pollard. Moreover, OMLM-Noh can sufficiently reproduce the diurnal cycle of SST. Regarding the typhoon case study, SST cooling due to wind-driven ocean mixing is underestimated in WRF-OMLM-Pollard, which artificially increases the intensity of the typhoon due to more simulated air-sea heat fluxes. Compared to the WRF- OMLM-Pollard, the performance of WRF-OMLM-Noh is superior in terms of both the spatial distribution and temporal variation of SST and air-sea heat fluxes. 展开更多
关键词 WRF-OMLM-Noh sea surface temperature ocean mixed layer air-sea coupled model
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Interannual variability of the sea surface salinity and its related freshwater flux in the tropical Pacific:A comparison of CMIP5 and CMIP6 被引量:2
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作者 Hai Zhi Yu Huang +2 位作者 Pengfei Lin Shiwei Shi Meng Dong 《Atmospheric and Oceanic Science Letters》 CSCD 2022年第4期6-12,共7页
This paper assesses the interannual variabilities of simulated sea surface salinity(SSS)and freshwater flux(FWF)in the tropical Pacific from phases 5 and 6 of the Coupled Model Intercomparison Project(CMIP5 and CMIP6)... This paper assesses the interannual variabilities of simulated sea surface salinity(SSS)and freshwater flux(FWF)in the tropical Pacific from phases 5 and 6 of the Coupled Model Intercomparison Project(CMIP5 and CMIP6).The authors focus on comparing the simulated SSS and FWF responses to El Nino–Southern Oscillation(ENSO)from two generations of models developed by the same group.The results show that CMIP5 and CMIP6 models can perform well in simulating the spatial distributions of the SSS and FWF responses associated with ENSO,as well as their relationship.It is found that most CMIP6 models have improved in simulating the geographical distribution of the SSS and FWF interannual variability in the tropical Pacific compared to CMIP5 models.In particular,CMIP6 models have corrected the underestimation of the spatial relationship of the FWF and SSS variability with ENSO in the central-western Pacific.In addition,CMIP6 models outperform CMIP5 models in simulating the FWF interannual variability(spatial distribution and intensity)in the tropical Pacific.However,as a whole,CMIP6 models do not show improved skill scores for SSS interannual variability,which is due to their overestimation of the intensity in some models.Large uncertainties exist in simulating the interannual variability of SSS among CMIP5 and CMIP6 models and some improvements with respect to physical processes are needed. 展开更多
关键词 Interannual variability Sea surface salinity Sea surface temperature Coupled model intercomparison project
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Density matrix of two interacting particles with kinetic coupling derived in bipartite entangled state representation
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作者 Guo Qi 郭琴 《Chinese Physics B》 SCIE EI CAS CSCD 2007年第9期2544-2548,共5页
A density matrix is usually obtained by solving the Bloch equation, however only a few Hamiltonians' density matrices can be analytically derived. The density matrix for two interacting particles with kinetic couplin... A density matrix is usually obtained by solving the Bloch equation, however only a few Hamiltonians' density matrices can be analytically derived. The density matrix for two interacting particles with kinetic coupling is hard to derive by the usual method due to this coupling; this paper solves this problem by using the bipartite entangled state representation. 展开更多
关键词 density matrix the bipartite entangled state representation kinetic coupling
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Application of Tripartite Entangled State Representation in Solving the Dynamics of a Kind of Three Coupled Oscillators
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作者 PANGQian-Jun 《Communications in Theoretical Physics》 SCIE CAS CSCD 2005年第6期1037-1041,共5页
We study the eigenstate problem of a kind of three coupled oscillators in anew quantum mechanical representation composed by the spontaneous eigenvectors 【 p,q_2,q_3| forthree operators (p_1 + p_2 + p_3), (x_3 - x_2)... We study the eigenstate problem of a kind of three coupled oscillators in anew quantum mechanical representation composed by the spontaneous eigenvectors 【 p,q_2,q_3| forthree operators (p_1 + p_2 + p_3), (x_3 - x_2), and (x_3 - x_1). The eigenvalues and eigenvectors ofthe Hamiltonian are obtained. With the same method, the eigenstate problem of a generalizedthree-coupled oscillator Hamiltonian is studied, which has never been studied before. 展开更多
关键词 entangled state representation coupled oscillator system
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Characterization and Catalytic Properties of Al-MCM-41 Mesoporous Materials Grafted with Tributyltin Chloride 被引量:1
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作者 宋伟明 刘星 +1 位作者 荆涛 邓启刚 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2012年第5期900-905,共6页
Surface organometallic chemistry (SOMC) is a recently developing research field. It is of great significance for the quantitative modification, restoration of solid surface, identification of the physical and chemical... Surface organometallic chemistry (SOMC) is a recently developing research field. It is of great significance for the quantitative modification, restoration of solid surface, identification of the physical and chemical nature of surface and the preparation of new catalyst. The production of R 3 Sn-O-MCM-41 (R 3 SnM) was obtained by heating tributyltin chloride and Al-MCM-41 mixture at 170 °C for 5 h under stirring in nitrogen atmosphere. The composition, structure and surface physical and chemical properties of the samples were characterized by inductively coupled plasma mass spectrometry (ICP-MS), 13 C, 119 Sn, 29 Si and 27 Al solid state NMR (nuclear magnetic resonance) spectra, in-situ pyridine infrared spectroscopy (Py-IR), N 2 adsorption-desorption, X-ray diffraction (XRD), transmission electron microscopy (TEM), etc. The results of ICP and organic elemental analysis shows that the grafting yield w Sn was 6.46% for R 3 SnM. H 0 (the negative logarithm of the acid concentration)and the number of acid sites for R 3 SnM respectively were 2.77-0.99 and 4.8 mmol·g-1 by the Hammett method. N 2 adsorption-desorption, XRD, TEM analysis showed that R 3 SnM with ordered hexagonal mesopore structure, resulted in the decease of surface areas and pore size as well as the increase of mesoporous volume and surface acidity, as compared to Al-MCM-41. R 3 SnM was used in the synthesis of isoamyl acetate. The yield of isoamyl acetate was 96% when n(isoamyl alcohol)︰n(acetic acid) 1.0︰1.0, 3 R SnM w 5%, 138 °C for 5 h. The catalyst can be reused and the yield of 86% can be attained when catalyst was reused five times at the same catalytic conditions. 展开更多
关键词 Al-MCM-41 molecular sieves tributyltin chloride grafting reaction CHARACTERIZATION CATALYSIS isoa-myl acetate
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Study on Surface Modification of Glass Bead by a Block Copolymer Coupling Agent
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作者 李殷 张冰 周晓东 《Journal of Donghua University(English Edition)》 EI CAS 2008年第4期453-457,共5页
A tri-block copolymer coupling agent polystyreneblock-poly (n-butyl-acrylate)-block-poly (y-methacryloxypro pylt rimethoxysilane)(PS-b-PnBA-b-PMPS) was synthesized by atom transfer radical polymerization (ATRP... A tri-block copolymer coupling agent polystyreneblock-poly (n-butyl-acrylate)-block-poly (y-methacryloxypro pylt rimethoxysilane)(PS-b-PnBA-b-PMPS) was synthesized by atom transfer radical polymerization (ATRP), and its molecular structure was characterized by fourier-transform infrared spectra, hydrogen nuclear magnetic resonance and gel permeation chromatography. The glass bead was treated with the block copolymer coupling agent, and then studied by transmission electron microscopy. The result showed that strong interaction was formed between the block copolymer coupling agent and the surface of glass bead, and then the block of poly(n-butylacrylate) formed a layer of film on the surface. 展开更多
关键词 block copolymer coupling agent glass bead surface modification INTERFACE
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Formulation of Green's Function in Solving Schroedinger Equation forBipartite System with Kinetic Coupling Gained by Virtue of Entangled States
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作者 FANHong-Yi LIUQiu-Yu 《Communications in Theoretical Physics》 SCIE CAS CSCD 2005年第5期791-794,共4页
Using the entangled state representation we present a formulation of Green'sfunction in solving Schrodinger equation for bipartite system with kinetic coupling.
关键词 Green's function bipartite system kinetic coupling entangled staterepresentation
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A New Method for Predicting the Decadal Component of Global SST 被引量:3
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作者 LUO Fei-Fei LI Shuanglin +1 位作者 GAO Yong-Qi Tore FUREVIK 《Atmospheric and Oceanic Science Letters》 2012年第6期521-526,共6页
A simple approach that considers both internal decadal variability and the effect of anthropogenic forcing is developed to predict the decadal components of global sea surface temperatures (SSTs) for the three decades... A simple approach that considers both internal decadal variability and the effect of anthropogenic forcing is developed to predict the decadal components of global sea surface temperatures (SSTs) for the three decades 2011-2040. The internal decadal component is derived by harmonic wave expansion analyses based on the quasiperiodic evolution of the Pacific Decadal Oscillation (PDO) and the Atlantic Multidecadal Oscillation (AMO), as obtained from observational SST datasets. Furthermore, the external decadal component induced by anthropogenic forcing is assessed with a second-order fit based on the ensemble of projected SSTs in the experiments with multiple coupled climate models associated with the third Coupled Model Intercomparison Project (CMIP3) under the Intergovernmental Panels on Climate Change (IPCC) Special Reports on Emissions Scenario (SRES) A1B. A validation for the years from 2002 to 2010 based on a comparison of the predicted and the observed SST and their spatial correlation, as well as the root mean square error (RMSE), suggests that the approach is reasonable overall. In addition, the predicted results over the 50°S-50°N global band, the Indian Ocean, the western Pacific Ocean, the tropical eastern Pacific Ocean, and the North and the South Atlantic Ocean are presented. 展开更多
关键词 decadal climate prediction internal decadal variability anthropogenic forcing SST
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Use of Spreadsheets as an Introductory Tool for Solving Fluid-Structure Interaction Problem
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作者 Lineu Jose Pedroso Danilo O. T. Belo Paulo Marcelo Vieira Ribeiro 《Journal of Civil Engineering and Architecture》 2014年第9期1098-1109,共12页
A simple and intuitive manner for solving fluid-structure interaction problem has been developed using Microsoft Excel spreadsheets. By eliminating the need of previous knowledge of any programming language, the metho... A simple and intuitive manner for solving fluid-structure interaction problem has been developed using Microsoft Excel spreadsheets. By eliminating the need of previous knowledge of any programming language, the method appears as an interesting introduction to numerical solutions of partial differential equations, due to the direct and didactic way that it is developed. Proposed procedure enables the analysis of tridimensional geometries using the finite difference method and can be extended to other differential equations or boundary conditions. The author's objective in this paper is to develop a simple and reliable preliminary method for solving acoustic fluid-structure interaction problems with application to dam-reservoir interaction phenomena and also contribute in the educational growth for undergraduate students that are beginning research in such matter. 展开更多
关键词 Fluid-structure interaction finite difference method Microsoft Excel spreadsheets.
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Solutions of the Schrdinger Equation for PT-Symmetric Coupled Quintic Potentials in Two Dimensions
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作者 Savita Fakir Chand 《Communications in Theoretical Physics》 SCIE CAS CSCD 2011年第9期419-422,共4页
This paper deals with the solutions of time independent Schrodinger wave equation for a two-dimensional PT-symmetric coupled quintic potential in its most general form. Employing wavefunction ansatz method, general an... This paper deals with the solutions of time independent Schrodinger wave equation for a two-dimensional PT-symmetric coupled quintic potential in its most general form. Employing wavefunction ansatz method, general analytic expressions for eigenvalues and eigenfunctions for first four states are obtained. Solutions of a particular case are also presented. 展开更多
关键词 Schrodinger equation quintic potential PT-syrametry EIGENVALUE EIGENFUNCTION
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Representation of the Arctic Oscillation in the CMIP5 Models 被引量:4
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作者 ZUO Jin-Qing LI Wei-Jing REN Hong-Li 《Advances in Climate Change Research》 SCIE 2013年第4期242-249,共8页
The temporal variability and spatial pattern of the Arctic Oscillation(AO)simulated in the historical experiment of26 coupled climate models participating in the Coupled Model Intercomparison Project Phase 5(CMIP5)are... The temporal variability and spatial pattern of the Arctic Oscillation(AO)simulated in the historical experiment of26 coupled climate models participating in the Coupled Model Intercomparison Project Phase 5(CMIP5)are evaluated.Spectral analysis of the monthly AO index indicates that 23 out of the 26 CMIP5 models exhibit no statistically significant spectral peak in the historical experiment,as seen in the observations.These models are able to reproduce the AO pattern in the sea level pressure anomaly field during boreal winter,but the intensity of the AO pattern tends to be overestimated in all the models.The zonal-mean zonal wind anomalies associated with the AO is dominated by a meridional dipole in the mid-high latitudes of the Northern Hemisphere during boreal winter,which is well reproduced by only a few models.Most models show significant biases in both strength and location of the dipole compared to the observation.In considering the temporal variability as well as spatial structures in both horizontal and vertical directions,the MPI-ESM-P model reproduces an AO pattern that resembles the observation the best. 展开更多
关键词 Arctic Oscillation model evaluation coupled climate model CMIP5
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Relationships of Interannual Variability Between the Equatorial Pacific and Tropical Indian Ocean in 17 CMIP5 Models 被引量:2
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作者 LIU Qinyu GUO Feiyan ZHENG Xiao-Tong 《Journal of Ocean University of China》 SCIE CAS 2013年第2期237-244,共8页
Seventeen coupled general circulation models from the Coupled Model Intercomparison Project Phase 5 (CMIP5) are employed to assess the relationships of interannual variations of sea surface temperature (SST) betwe... Seventeen coupled general circulation models from the Coupled Model Intercomparison Project Phase 5 (CMIP5) are employed to assess the relationships of interannual variations of sea surface temperature (SST) between the tropical Pacific (TP) and tropical Indian Ocean (TIO). The eastern/central equatorial Pacific features the strongest SST interannual variability in the models except for the model CSIRO-Mk3-6-0, and the simulated maximum and minimum are produced by models GFDL-ESM2M and GISS-E2-H respectively. However, It remains a challenge for these models to simulate the correct climate mean SST with the warm pool-cold tongue structure in the equatorial Pacific. Almost all models reproduce E1 Nifio-Southem Oscillation (ENSO), Indian Ocean Dipole mode (IOD) and Indian Ocean Basin-wide mode (lOB) together with their seasonal phase lock features being simulated; but the relationship between the ENSO and IOD is different for different models. Consistent with the observation, an Indian Ocean basin-wide warming (cooling) takes place over the tropical Indian Ocean in the spring following an E1 Nifio (La Nifia) in almost all the models. In some models (e.g., GFDL-ESM2G and MIROC5), positive ENSO and IOB events are stronger than the negative events as shown in the observation. However, this asymmetry is reversed in some other models (e.g., HadGEM2-CC and HadGEM2-ES). 展开更多
关键词 Coupled Model Intercomparison Project Phase 5 sea surface temperature E1 Nifio-Southern Oscillation tropical Indian Ocean tropical Pacific Ocean interannual variability
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Experimental Study on the Surface Modification of Ultra Thin DLC Films
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作者 朱守星 朱世根 《Journal of Donghua University(English Edition)》 EI CAS 2005年第3期85-87,共3页
Surface modification of Diamond-like carbon (DLC) films was carried out in order to estimate the reliability of the ultra thin DLC films. The wear resistance, conductivity and mechatronic reliability of the films were... Surface modification of Diamond-like carbon (DLC) films was carried out in order to estimate the reliability of the ultra thin DLC films. The wear resistance, conductivity and mechatronic reliability of the films were studied by contact atomic force microscope (AFM), electric force microscope (EFM) and conductive AFM. The failure mechanism of pits formed and the reason for conductivity changed of DLC films were examined. 展开更多
关键词 Atomic force microscope Diamond-like carbon Surface modification Electromechanical coupling
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Improvement of surface hydrophobicity on silicone rubber modified by CF_4 radio frequency capacitively coupled plasma
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作者 高松华 周克省 闻立时 《Journal of Central South University》 SCIE EI CAS 2009年第3期365-370,共6页
In order to improve the surface hydrophobicity, silicone rubber (SIR) samples were exposed to CF4 radio frequency (RF) capacitively coupled plasma (CCP). Attenuated total reflection Fourier transform infrared (... In order to improve the surface hydrophobicity, silicone rubber (SIR) samples were exposed to CF4 radio frequency (RF) capacitively coupled plasma (CCP). Attenuated total reflection Fourier transform infrared (ATR-FTIR) spectrum and X-ray photoelectron spectroscopy (XPS) were used to observe the variation of the functional groups of the modified SIR. Static contact angle (SCA) was employed to estimate the change of hydrophobicity of the modified SIR. The surface energy of SIR is reduced largely from 27.37 mJ/m^2 of original SIR sample to 2.94 mJ/m^2 of SIR sample treated by CF4 CCP modification at RF power of 200 W for a treatment time of 5 rnin. According to the XPS, ATR-FTIR and surface energy analysis, it is suggested that the improvement of hydrophobicity on the modified SIR surface is mainly ascribed to the decrease of surface energy, which is caused by the cooperation of the fluosilicic structure of Si--F or Si--F2 and the fluoric groups of C--CFn induced by the methyl replacement reaction and residual methyl groups of SIR surface. 展开更多
关键词 surface hydrophobicity silicone rubber radio frequency capacitively coupled plasma static contact angle
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Synthesis, characterization of triphenyltin grafted on SBA-15mesoporous silica and its catalytic performance for the synthesis of 4-methylacetophenone
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作者 邓启刚 覃志乐 +1 位作者 杨颖 宋伟明 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2015年第2期384-388,共5页
The production of Ph3Sn–O–SBA-15(Ph3Sn SBA)was achieved by heating triphenyltin chloride and SBA-15in N-methylpyrrolidone at 190°C for 5 h using triethylamine as a catalyst.The composition,structure,and surface... The production of Ph3Sn–O–SBA-15(Ph3Sn SBA)was achieved by heating triphenyltin chloride and SBA-15in N-methylpyrrolidone at 190°C for 5 h using triethylamine as a catalyst.The composition,structure,and surface physical and chemical properties of Ph3Sn SBA were characterized using inductively coupled plasma-atomic emission spectroscopy(ICP-AES),13C,119Sn and29Si solid-state nuclear magnetic resonance(NMR)spectroscopy in situ pyridine infrared spectroscopy(Py-IR),N2adsorption–desorption isotherms,X-ray diffraction(XRD)and transmission electron microscopy(TEM).The results of ICP-AES and organic elemental analysis showed that the grafting yield of Sn was 17%(by mass)for Ph3Sn SBA.The elemental analysis and solid-state NMR results for Ph3Sn SBA were consistent with grafting of triphenyltin on SBA-15.The N2adsorption–desorption,XRD and TEM analyses showed that Ph3Sn SBA retained an ordered hexagonal mesoporous structure,resulting in decreases in the surface area,pore size and mesopore volume,and an increase in acidity as compared with SBA-15.The Hammett acidity function(H0)value and the number of acid sites for Ph3Sn SBA,obtained by the Hammett methods,were 2.77–3.30 and 2.07 mmol·g-1,respectively.The Friedel–Crafts acylation of toluene and acetic anhydride over Ph3Sn SBA was investigated.The yield of methylacetophenone(MAP)and the selectivity for 4-methylacetophenone(PMAP)were 79.56%and 97.12%,respectively,when the conditions were n(toluene):n(anhydride)=2.0:1.0 with 6%(by mass)catalyst,and heating under reflux for 5 h.The PMAP selectivity still reached 93.11%when Ph3Sn SBA was used for the fifth time under the same reaction conditions. 展开更多
关键词 SBA-15 Triphenyltin chloride Grafting reaction CATALYSIS Friedel–Crafts
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