浅析回采巷道支护改革的途径

从加速回采巷道支护改革的必要性和迫切性进行了论述，指出了回采巷道支护方面存在的主要问题和改进措施，提出了在回采巷道中使用锚杆支护时应注意的问题。

Elimination of matrix effects during analysis of perfluorinated acids in solid samples by liquid chromatography tandem mass spectrometry

Matrix effects can significantly hamper the accuracy and precision of the analysis results of perfluorinated acids （PFAs） in environmental solid samples. Several methods, such as standard addition, isotopically labeled internal standards, clean-up of SPE （solid phase extraction） eluents by dispersive graphitized carbon sorbent and substitution of eletrospray ionization （ESI） source by atmosphere pressure photoionization （APPI） source, were demonstrated for elimination of matrix effects in quantitative analysis of PFAs in solid samples. The resuRs indicate that matrix effects can be effectively eliminated by standard addition, but instrumental analysis time will be multiplied. Isotopically labeled internal standards can effectively negate matrix effects of PFAs with the same perfluorocarbon chain length, but is not valid for the other analytes. Although APPI can eliminate matrix effects for all analytes, it is only suitable for analysis of high pollution levels samples. Clean-up of SPE eluents by dispersive graphitized carbon sorbent not only effectively negate the impact of matrix effect, but also avoid frequent clean of the ESI in order to maintain instrumental sensitivity. Therefore, the best method for elimination of matrix effects is the usage of dispersive graphitized carbon sorbent for clean-up of SPE elution.

Enhancing the catalytic efficiency of the Heck coupling reaction by forming 5 nm Pd octahedrons using kinetic control

Heterogeneous catalysis occurs through a process of interfacial reactions; therefore, both surface facet and size control can increase catalytic efficiency. Octahedral Pd nanocrystals, enclosed by {111} facets, should be the ideal geometrical shape for Heck coupling reactions; however, it is challenging to synthesize 5 nm Pd octahedrons with a relatively uniform size distribution using existing capping-agent techniques. Here, we used palladium as a model system to investigate how the kinetics of atomic addition could be precisely controlled using a syringe pump. As a result, our method produced Pd octahedrons as small as 5 nm, which increased the catalytic efficiency of Heck coupling reactions while reducing the weight of catalyst used.

Band structure reconstruction across nematic order in high quality FeSe single crystal as revealed by optical spectroscopy study

We perform an in-plane optical spectroscopy measurement on high quality FeSe single crystals grown by a vapor transport technique. Below the structural transition at Ts - 90 K, the reflectivity spectrum clearly shows a gradual suppression around 400 cm-1 and the conductivity spectrum shows a peak at higher frequency. The energy scale of this gap-like feature is comparable to the width of the band splitting observed by ARPES. The low-frequency conductivity consists of two Drude components and the overall plasma frequency is smaller than that of the FeAs based compounds, suggesting a lower cartier density or stronger correlation effect. The plasma frequency becomes even smaller below Ts which agrees with the very small Fermi energy estimated by other experiments. Similar to iron pnictides, a clear temperature-induced spectral weight transfer is observed for FeSe, being indicative of strong correlation effect.

Chiral flux phase in the Kagome superconductor AV_(3)Sb_(5)

We argue that the topological charge density wave phase in the quasi-2D Kagome superconductor AV3Sb5 is a chiral flux phase.Considering the symmetry of the Kagome lattice,we show that the chiral flux phase has the lowest energy among those states which exhibit 2×2 charge orders observed experimentally.This state breaks the time-reversal symmetry and displays anomalous Hall effect.The explicit pattern of the density of state in real space is calculated.These results are supported by recent experiments and suggest that these materials are new platforms to investigate the interplay between topology,superconductivity and electron–electron correlations.

Electrostatic Surface Waves on Semi-Bounded Quantum Electron-Hole Semiconductor Plasmas

The electrostatic surface waves on semi-bounded quantum electron-hole semiconductor plasmas are studied within the framework of the quantum hydrodynamic model, including the electrons and holes quantum recoil effects,quantum statistical pressures of the plasma species, as well as exchange and correlation effects. The dispersion characteristics of surface electrostatic oscillations are investigated by using the typical values of Ga As, Ga Sb and Ga N semiconductors. Numerical results show the existence of one low-frequency branch due to the mass difference between the electrons and holes in addition to one high-frequency branch due to charge-separation effects.