2-Chloro-5-chloromethylpyridine is a crucial intermediate of pesticides.Its solid-liquid equilibrium data will provide essential support for industrial design and further theoretical studies.The solubilities of 2-chlo...2-Chloro-5-chloromethylpyridine is a crucial intermediate of pesticides.Its solid-liquid equilibrium data will provide essential support for industrial design and further theoretical studies.The solubilities of 2-chloro-5-chloromethylpyridine in water,methanol,ethanol,ethyl acetate,acetone,trichloromethane and toluene at different temperatures were measured using the synthetic method by a laser monitoring observation technique. The solubility data were correlated with the modified Apelblat equation and Wilson equation.The calculated values were in good agreement with the experimental values.展开更多
ERT(electrical resistance tomography) is effective method for visualization of multiphase flows,offering some advantages of rapid response and low cost,so as to explore the transient hydrodynamics.Aiming at this targe...ERT(electrical resistance tomography) is effective method for visualization of multiphase flows,offering some advantages of rapid response and low cost,so as to explore the transient hydrodynamics.Aiming at this target,a fully programmable and reconfigurable FPGA(field programmable gate array)-based Compact PCI(peripheral component interconnect) bus linked sixteen-channel ERT system has been presented.The data acquisition system is carefully designed with function modules of signal generator module;Compact PCI transmission module and data processing module(including data sampling,filtering and demodulating).The processing module incorporates a powerful FPGA with Compact PCI bus for communication,and the measurement process management is conducted in FPGA.Image reconstruction algorithms with different speed and accuracy are also coded for this system.The system has been demonstrated in real time(1400 frames per second for 50 kHz excitation) with signal-noise-ratio above 62 dB and repeatability error below 0.7%.Static experiments have been conducted and the images manifested good resolution relative to the actual object distribution.The parallel ERT system has provided alternative experimental platform for the multiphase flow measurements by the dynamic experiments in terms of concentration and velocity.展开更多
Sensors are ubiquitous in the Internet of Things for measuring and collecting data. Analyzing these data derived from sensors is an essential task and can reveal useful latent information besides the data. Since the I...Sensors are ubiquitous in the Internet of Things for measuring and collecting data. Analyzing these data derived from sensors is an essential task and can reveal useful latent information besides the data. Since the Internet of Things contains many sorts of sensors, the measurement data collected by these sensors are multi-type data, sometimes contai- ning temporal series information. If we separately deal with different sorts of data, we will miss useful information. This paper proposes a method to dis- cover the correlation in multi-faceted data, which contains many types of data with temporal informa- tion, and our method can simultaneously deal with multi-faceted data. We transform high-dimensional multi-faeeted data into lower-dimensional data which is set as multivariate Gaussian Graphical Models, then mine the correlation in multi-faceted data by discover the structure of the multivariate Gausslan Graphical Models. With a real data set, we verifies our method, and the experiment demonstrates that the method we propose can correctly fred out the correlation among multi-faceted meas- urement data.展开更多
Aiming at the shortage of sufficient continuous parameters for using models to estimate farmland soil organic carbon(SOC) content, an acquisition method of factors influencing farmland SOC and an estimation method of ...Aiming at the shortage of sufficient continuous parameters for using models to estimate farmland soil organic carbon(SOC) content, an acquisition method of factors influencing farmland SOC and an estimation method of farmland SOC content with Internet of Things(IOT) are proposed in this paper. The IOT sensing device and transmission network were established in a wheat demonstration base in Yanzhou Distict of Jining City, Shandong Province, China to acquire data in real time. Using real-time data and statistics data, the dynamic changes of SOC content between October 2012 and June 2015 was simulated in the experimental area with SOC dynamic simulation model. In order to verify the estimation results, potassium dichromate external heating method was applied for measuring the SOC content. The results show that: 1) The estimated value matches the measured value in the lab very well. So the method is feasible in this paper. 2) There is a clear dynamic variation in the SOC content at 0.2 m soil depth in different growing periods of wheat. The content reached the highest level during the sowing period, and is lowest in the flowering period. 3) The SOC content at 0.2 m soil depth varies in accordance with the amount of returned straw. The larger the amount of returned straw is, the higher the SOC content.展开更多
文摘2-Chloro-5-chloromethylpyridine is a crucial intermediate of pesticides.Its solid-liquid equilibrium data will provide essential support for industrial design and further theoretical studies.The solubilities of 2-chloro-5-chloromethylpyridine in water,methanol,ethanol,ethyl acetate,acetone,trichloromethane and toluene at different temperatures were measured using the synthetic method by a laser monitoring observation technique. The solubility data were correlated with the modified Apelblat equation and Wilson equation.The calculated values were in good agreement with the experimental values.
基金Supported by the National Natural Science Foundation of China (51176141)the Natural Science Foundation of Tianjin(11JCZDJC22500)
文摘ERT(electrical resistance tomography) is effective method for visualization of multiphase flows,offering some advantages of rapid response and low cost,so as to explore the transient hydrodynamics.Aiming at this target,a fully programmable and reconfigurable FPGA(field programmable gate array)-based Compact PCI(peripheral component interconnect) bus linked sixteen-channel ERT system has been presented.The data acquisition system is carefully designed with function modules of signal generator module;Compact PCI transmission module and data processing module(including data sampling,filtering and demodulating).The processing module incorporates a powerful FPGA with Compact PCI bus for communication,and the measurement process management is conducted in FPGA.Image reconstruction algorithms with different speed and accuracy are also coded for this system.The system has been demonstrated in real time(1400 frames per second for 50 kHz excitation) with signal-noise-ratio above 62 dB and repeatability error below 0.7%.Static experiments have been conducted and the images manifested good resolution relative to the actual object distribution.The parallel ERT system has provided alternative experimental platform for the multiphase flow measurements by the dynamic experiments in terms of concentration and velocity.
基金the Project"The Basic Research on Internet of Things Architecture"supported by National Key Basic Research Program of China(No.2011CB302704)supported by National Natural Science Foundation of China(No.60802034)+2 种基金Specialized Research Fund for the Doctoral Program of Higher Education(No.20070013026)Beijing Nova Program(No.2008B50)"New generation broadband wireless mobile communication network"Key Projects for Science and Technology Development(No.2011ZX03002-002-01)
文摘Sensors are ubiquitous in the Internet of Things for measuring and collecting data. Analyzing these data derived from sensors is an essential task and can reveal useful latent information besides the data. Since the Internet of Things contains many sorts of sensors, the measurement data collected by these sensors are multi-type data, sometimes contai- ning temporal series information. If we separately deal with different sorts of data, we will miss useful information. This paper proposes a method to dis- cover the correlation in multi-faceted data, which contains many types of data with temporal informa- tion, and our method can simultaneously deal with multi-faceted data. We transform high-dimensional multi-faeeted data into lower-dimensional data which is set as multivariate Gaussian Graphical Models, then mine the correlation in multi-faceted data by discover the structure of the multivariate Gausslan Graphical Models. With a real data set, we verifies our method, and the experiment demonstrates that the method we propose can correctly fred out the correlation among multi-faceted meas- urement data.
基金Under the auspices of National High-tech R&D Program of China(No.2013AA102301)National Natural Science Foundation of China(No.71503148)
文摘Aiming at the shortage of sufficient continuous parameters for using models to estimate farmland soil organic carbon(SOC) content, an acquisition method of factors influencing farmland SOC and an estimation method of farmland SOC content with Internet of Things(IOT) are proposed in this paper. The IOT sensing device and transmission network were established in a wheat demonstration base in Yanzhou Distict of Jining City, Shandong Province, China to acquire data in real time. Using real-time data and statistics data, the dynamic changes of SOC content between October 2012 and June 2015 was simulated in the experimental area with SOC dynamic simulation model. In order to verify the estimation results, potassium dichromate external heating method was applied for measuring the SOC content. The results show that: 1) The estimated value matches the measured value in the lab very well. So the method is feasible in this paper. 2) There is a clear dynamic variation in the SOC content at 0.2 m soil depth in different growing periods of wheat. The content reached the highest level during the sowing period, and is lowest in the flowering period. 3) The SOC content at 0.2 m soil depth varies in accordance with the amount of returned straw. The larger the amount of returned straw is, the higher the SOC content.