有机绝缘层材料聚(4-乙烯基苯酚)喷墨打印工艺研究

通过压电喷墨打印方式在氧化铟锡(ITO)玻璃上直接图案化打印聚(4-乙烯基苯酚)(PVP),研究了不同浓度PVP的电学特性,从电容、漏电流、击穿场强几个方面进行了分析。结果表明,采用打印方式得到的PVP绝缘层在0～40V的外加电压下,漏电流密度在10-11～10-8 A/cm2范围内,为打印方式制备高性能交联PVP(CL-PVP)介电层提供了必要的参考。

Study on an Organic Hybrid Made from Chlorinated Polyethylene and 2,2'-methylene-bis- (4-methyl-6-cyclohexylphenol)

The dynamic mechanical properties and miscibility of an organic hybrid made from chlorinated polyethylene (CPE) and 2, 2'-methyIene-bis-( 4-methyl-6-cyclohexylphenol) ( ZKF ) are mainly discussed in this paper. It is found that ZKF acts as an antiplasticizer in CPE matrix and has good miscibility even with large ratio in CPE /ZKF hybrids. The glass transition temperature of various CPE /ZKF hybrids determined by DSC give a good fit to Wood's equation. Bifunctional ZKF is supposed to improve the intermolecular force of CPE, and the improvement is developed when the ZKF content increases. On the other hand, the viscoelastic properties are highly improved with the addition of ZKF. TA and tanδ peak values increase when the ZKF content increase in the CPE /ZKF hybrids, the damping capacity has been improved during the glass transition of CPE /ZKF hybrids. In addition, the glass transition temperature shifts to room temperature from the low temperature with the continuous addition of ZKF to CPE.

温度响应的酶催化核交联胶束

以聚4-乙酰氧基苯乙烯P(4-ASt)和N-异丙基丙烯酰胺(NIPAm)为单体,通过可逆加成-断裂链转移聚合(RAFT)合成了结构明确窄相对分子质量分布(M_w/M_n=1.28)的两嵌段共聚物P(4-ASt-b-NIPAm)。通过水合肼将P(4-ASt-b-NIPAm)中的P(4-ASt)嵌段上的乙酰基团选择性水解后得到聚(4-乙烯基苯酚-b-N-异丙基丙烯酰胺)两嵌段共聚物P(4-VPh-b-NIPAm)。采用~1HNMR、FTIR和GPC对P(4-VPh-b-NIPAm)结构进行了表征,利用荧光光谱、透光率法和DLS研究了其水溶液的聚集行为和温度响应性。结果表明,P(4-VPh-b-NIPAm)在水中可自组装形成以P(4-VPh)为核、PNIPAm为壳的胶束,其临界胶束浓度(CMC)为0.015 g/L,室温下平均粒径约为137 nm,低临界溶解温度(LCST)为31.2℃。以辣根过氧化物酶(HRP)催化交联P(4-VPh)核制备了平均粒径约为119 nm的核交联胶束,TEM显示干态核交联胶束为球形,粒径为60~100 nm。核交联胶束水溶液具有良好的热稳定性和温度响应性,其相转变温度为32~36℃,LCST约为34.9℃,随温度升高平均粒径从25℃的119 nm减小至37℃的92.9nm。