Hydroxyl-epoxy phosphate （HEP） as a reactive corrosion inhibitor was innovatively synthe- sized by the reaction of bisphenol A epoxy resin with phosphoric acid. HEP was mixed with hydroxyl acrylate resin, and crossl...Hydroxyl-epoxy phosphate （HEP） as a reactive corrosion inhibitor was innovatively synthe- sized by the reaction of bisphenol A epoxy resin with phosphoric acid. HEP was mixed with hydroxyl acrylate resin, and crosslinked with waterborne isocyanate curing agent, which was used to form waterborne HEP/acrylic polyurethane composite （HEP-APU） coatings on Q235 steel surfaces. Electrochemical impedance spectroscopy and polarization curves were applied to analyze the corrosion behavior of the HEP-APU coatings in 3.5wt% NaCl solutions. The results indicated that the HEP-APU coatings show a superior passivation property and efficient corrosion protection of Q235 steel. The waterborne acrylic polyurethane coating containing 0.5wt% HEP exhibited the best corrosion performance among all the coating specimens. The improved flash-rust resistance can be attributed to the introduction of the phosphate group which could form phosphate film on the steel substrate.展开更多
利用扫描电子显微镜(SEM)、差示扫描量热仪(DSC)、熔体流动速率仪和力学性能等测试方法研究了甲基丙烯酸环氧丙酯改性聚丙烯酸酯(ACR-g-GMA)核壳结构抗冲击改性剂粒子增韧尼龙(PA)1012共混物的相关性能。结果表明,当ACR-g-GMA加入量为9%...利用扫描电子显微镜(SEM)、差示扫描量热仪(DSC)、熔体流动速率仪和力学性能等测试方法研究了甲基丙烯酸环氧丙酯改性聚丙烯酸酯(ACR-g-GMA)核壳结构抗冲击改性剂粒子增韧尼龙(PA)1012共混物的相关性能。结果表明,当ACR-g-GMA加入量为9%时,PA1012/ACR-g-GMA共混体系的熔体质量流动速率降低到2.3 g/10min;SEM照片表明,弹性核壳粒子能均匀地分散在共混物中。共混物的缺口冲击强度先增加后降低,当ACR-gGMA加入量为9%时,缺口冲击强度达到最大值83.3 k J/m2,是纯PA1012的3.8倍,拉伸强度降低约18%。等温结晶得到的Avrami指数近似为2,表明共混体系成核机理为异相成核。展开更多
Two kinds of UV curable polyurethane acrylate oligomers （PUPA and PUCA） were synthesized via the addition reaction between isophorone diisocyanate （IPDI） and polyethylene glycol monoacrylate （PEA6） or polycaprol...Two kinds of UV curable polyurethane acrylate oligomers （PUPA and PUCA） were synthesized via the addition reaction between isophorone diisocyanate （IPDI） and polyethylene glycol monoacrylate （PEA6） or polycaprolactone modified hydroxyethyl acrylate （PCLA2）. The structures of PUPA and PUCA were characterized by Fourier transform infrared spectroscopy （FT-IR）, IH nuclear magnetic resonance （^H NMR）, gel permeation chromatography （GPC） and differential scanning calorimeter （DSC）, and the thermal stability and dynamic mechanical thermal properties of their cured films were measured by thermogravimetric analysis （TGA） and dynamic mechanical analysis （DMA）, respectively. The viscosity of the oligomers and mechanical properties of the cured films were also studied. The results show that both oligomers have narrow molecular weight distribution. The viscosity of PUPA is 2.310 Pa.s at 25 ℃, while that of PUCA is： up to 3.980 Pa-s. The UV cured PUPA and PUCA films have homogeneous phase structure, and the PUCA film shows higher glass transition temperature and storage modulus. Furthermore, the PUCA film possesses better mechanical properties than PUPA, while the latter shows better alkali resistance.展开更多
UV-curable hyperbranched polyurethane acrylate-polyurethane diacrylate/SiO2 dispersion （HBPUA-PUDA/SiO2） was prepared with isophorone diisocyanate （IPDI）, hyperbranched polyester Boltorn H20 （H20）, hydroxy-ethyl...UV-curable hyperbranched polyurethane acrylate-polyurethane diacrylate/SiO2 dispersion （HBPUA-PUDA/SiO2） was prepared with isophorone diisocyanate （IPDI）, hyperbranched polyester Boltorn H20 （H20）, hydroxy-ethyl acrylate （HEA）, polyethyleneglycol （PEG-200）and nano-SiO2. The UV curing kinetics of the films was investigated by FTIR. The results show that the curing speed of the films increases with the adding of nano-SiO2 and decreases with the adding of PUDA due to the slower chain movement. The thermal stability of the HBPUA-PUDA/SiO2 films was studied by using thermogravimetric analysis coupled with Fourier transform infrared spectroscopy （TGA/FTIR）. The results show that all films exhibit two degradation stages located at about 320 and 440℃ corresponding to the degradation for hard segments of urethane-acrylate and the degradation for soft segment and polyester core. In addition, the results from the analysis of TGA/FTIR also indicate that the decomposition temperature of HBPUA-PUDA/SiO2 film is 15℃ higher than that obtained for pure polymer. The degradation mechanism was proposed according to TGA/FTIR results.展开更多
The rubber composites with good thermal conductivity contribute to heat dissipation of tires. Graphite filled natural rubber composites were developed in this study to provide good thermal conductivity. Graphite was c...The rubber composites with good thermal conductivity contribute to heat dissipation of tires. Graphite filled natural rubber composites were developed in this study to provide good thermal conductivity. Graphite was coated with polyacrylate polymerized by monomers including methyl methacrylate, n-butyl acrylate and acrylic acid. The ratios between a filler and acrylate polymerization emulsion and those between monomers were varied. Eight types of surface modification formulas were experimentally investigated. Modification formula can affect coating results and composite properties greatly. The best coating type was achieved by a ratio of1:1 between methyl methacrylate and n-butyl acrylate. The coating of graphite was thermally stable in a running tire. Filled with modified graphite, the tire thermal conductivity reached up to 0.517–0.569 W·m-1·K-1. In addition, the mechanical performance was improved with increased crosslink density, extended scorch time and short vulcanization time.展开更多
Poly （methyl methacrylate） scrap was applied to prepare the impact modification of r-PMMA/PMMA-blend-PU/Ecoflex sheet by casting process. The Ecoflex and polyurethane were used as biodegradable polymer and impact mo...Poly （methyl methacrylate） scrap was applied to prepare the impact modification of r-PMMA/PMMA-blend-PU/Ecoflex sheet by casting process. The Ecoflex and polyurethane were used as biodegradable polymer and impact modified respectively. This research was ascertained tile way to reduce the processing cost of PMMA sheet and the industrial waste by recycled PMMA scrap into the production process. The r-PMMA/PMMA-blend-PU/Ecoflex sheet was studied potential degradation by landfills for six months. After degradation the percentage of weight loss of specimens was increasing depend on amount of Ecoflex content and degradation period. While, the surface morphology of r-PMMA/PMMA-blend-PU/Ecoflex sheet after six months was damaged and demonstrated that Ecoflex had an effect on PMMA-blend-PU sheet in potential biodegradation. The mechanical and physical properties of r-PMMA/PMMA-blend-PU/Ecoflex sheet were described. Finally, the impact strength of r-PMMA/PMMA-blend-PU/Ecoflex sheet from this research, it is possible to use r-PMMA and Ecoflex in the acrylic casting sheet product.展开更多
Transfer printing of nanomaterials onto target substrates has been widely used in the fabrication of nanodevices, but it remains a challenge to fully avoid contamination introduced in the transfer process. Here we rep...Transfer printing of nanomaterials onto target substrates has been widely used in the fabrication of nanodevices, but it remains a challenge to fully avoid contamination introduced in the transfer process. Here we report a metal-film- assisted method to realize an ultra-clean transfer of single-walled carbon nanotubes （SWCNTs） mediated by poly（methyl methacrylate） （PMMA）. The amount of PMMA residue can be greatly reduced due to its strong physical adhesion to the metal film, leading to ultra-clean surfaces of both the SWCNTs and the substrates. This metal-film-assisted transfer method is efficient, nondestructive, and scalable. It is also suitable for the transfer of graphene and other nanostructures. Furthermore, the relatively low temperature employed allows this technique to be compatible with nanomaterial-based flexible electronics.展开更多
文摘Hydroxyl-epoxy phosphate （HEP） as a reactive corrosion inhibitor was innovatively synthe- sized by the reaction of bisphenol A epoxy resin with phosphoric acid. HEP was mixed with hydroxyl acrylate resin, and crosslinked with waterborne isocyanate curing agent, which was used to form waterborne HEP/acrylic polyurethane composite （HEP-APU） coatings on Q235 steel surfaces. Electrochemical impedance spectroscopy and polarization curves were applied to analyze the corrosion behavior of the HEP-APU coatings in 3.5wt% NaCl solutions. The results indicated that the HEP-APU coatings show a superior passivation property and efficient corrosion protection of Q235 steel. The waterborne acrylic polyurethane coating containing 0.5wt% HEP exhibited the best corrosion performance among all the coating specimens. The improved flash-rust resistance can be attributed to the introduction of the phosphate group which could form phosphate film on the steel substrate.
文摘利用扫描电子显微镜(SEM)、差示扫描量热仪(DSC)、熔体流动速率仪和力学性能等测试方法研究了甲基丙烯酸环氧丙酯改性聚丙烯酸酯(ACR-g-GMA)核壳结构抗冲击改性剂粒子增韧尼龙(PA)1012共混物的相关性能。结果表明,当ACR-g-GMA加入量为9%时,PA1012/ACR-g-GMA共混体系的熔体质量流动速率降低到2.3 g/10min;SEM照片表明,弹性核壳粒子能均匀地分散在共混物中。共混物的缺口冲击强度先增加后降低,当ACR-gGMA加入量为9%时,缺口冲击强度达到最大值83.3 k J/m2,是纯PA1012的3.8倍,拉伸强度降低约18%。等温结晶得到的Avrami指数近似为2,表明共混体系成核机理为异相成核。
基金Project(2007168303) supported by Guangdong-Hong Kong Technology Cooperation Funding
文摘Two kinds of UV curable polyurethane acrylate oligomers （PUPA and PUCA） were synthesized via the addition reaction between isophorone diisocyanate （IPDI） and polyethylene glycol monoacrylate （PEA6） or polycaprolactone modified hydroxyethyl acrylate （PCLA2）. The structures of PUPA and PUCA were characterized by Fourier transform infrared spectroscopy （FT-IR）, IH nuclear magnetic resonance （^H NMR）, gel permeation chromatography （GPC） and differential scanning calorimeter （DSC）, and the thermal stability and dynamic mechanical thermal properties of their cured films were measured by thermogravimetric analysis （TGA） and dynamic mechanical analysis （DMA）, respectively. The viscosity of the oligomers and mechanical properties of the cured films were also studied. The results show that both oligomers have narrow molecular weight distribution. The viscosity of PUPA is 2.310 Pa.s at 25 ℃, while that of PUCA is： up to 3.980 Pa-s. The UV cured PUPA and PUCA films have homogeneous phase structure, and the PUCA film shows higher glass transition temperature and storage modulus. Furthermore, the PUCA film possesses better mechanical properties than PUPA, while the latter shows better alkali resistance.
文摘UV-curable hyperbranched polyurethane acrylate-polyurethane diacrylate/SiO2 dispersion （HBPUA-PUDA/SiO2） was prepared with isophorone diisocyanate （IPDI）, hyperbranched polyester Boltorn H20 （H20）, hydroxy-ethyl acrylate （HEA）, polyethyleneglycol （PEG-200）and nano-SiO2. The UV curing kinetics of the films was investigated by FTIR. The results show that the curing speed of the films increases with the adding of nano-SiO2 and decreases with the adding of PUDA due to the slower chain movement. The thermal stability of the HBPUA-PUDA/SiO2 films was studied by using thermogravimetric analysis coupled with Fourier transform infrared spectroscopy （TGA/FTIR）. The results show that all films exhibit two degradation stages located at about 320 and 440℃ corresponding to the degradation for hard segments of urethane-acrylate and the degradation for soft segment and polyester core. In addition, the results from the analysis of TGA/FTIR also indicate that the decomposition temperature of HBPUA-PUDA/SiO2 film is 15℃ higher than that obtained for pure polymer. The degradation mechanism was proposed according to TGA/FTIR results.
基金the National Natural Science Foundation of China(51076070,51276091)the Natural Science Foundation of Shandong Province(ZR2012EEQ017)the Research Award Fund for Outstanding Young Scientists in Shandong province(BS2012CL014)
文摘The rubber composites with good thermal conductivity contribute to heat dissipation of tires. Graphite filled natural rubber composites were developed in this study to provide good thermal conductivity. Graphite was coated with polyacrylate polymerized by monomers including methyl methacrylate, n-butyl acrylate and acrylic acid. The ratios between a filler and acrylate polymerization emulsion and those between monomers were varied. Eight types of surface modification formulas were experimentally investigated. Modification formula can affect coating results and composite properties greatly. The best coating type was achieved by a ratio of1:1 between methyl methacrylate and n-butyl acrylate. The coating of graphite was thermally stable in a running tire. Filled with modified graphite, the tire thermal conductivity reached up to 0.517–0.569 W·m-1·K-1. In addition, the mechanical performance was improved with increased crosslink density, extended scorch time and short vulcanization time.
文摘Poly （methyl methacrylate） scrap was applied to prepare the impact modification of r-PMMA/PMMA-blend-PU/Ecoflex sheet by casting process. The Ecoflex and polyurethane were used as biodegradable polymer and impact modified respectively. This research was ascertained tile way to reduce the processing cost of PMMA sheet and the industrial waste by recycled PMMA scrap into the production process. The r-PMMA/PMMA-blend-PU/Ecoflex sheet was studied potential degradation by landfills for six months. After degradation the percentage of weight loss of specimens was increasing depend on amount of Ecoflex content and degradation period. While, the surface morphology of r-PMMA/PMMA-blend-PU/Ecoflex sheet after six months was damaged and demonstrated that Ecoflex had an effect on PMMA-blend-PU sheet in potential biodegradation. The mechanical and physical properties of r-PMMA/PMMA-blend-PU/Ecoflex sheet were described. Finally, the impact strength of r-PMMA/PMMA-blend-PU/Ecoflex sheet from this research, it is possible to use r-PMMA and Ecoflex in the acrylic casting sheet product.
文摘Transfer printing of nanomaterials onto target substrates has been widely used in the fabrication of nanodevices, but it remains a challenge to fully avoid contamination introduced in the transfer process. Here we report a metal-film- assisted method to realize an ultra-clean transfer of single-walled carbon nanotubes （SWCNTs） mediated by poly（methyl methacrylate） （PMMA）. The amount of PMMA residue can be greatly reduced due to its strong physical adhesion to the metal film, leading to ultra-clean surfaces of both the SWCNTs and the substrates. This metal-film-assisted transfer method is efficient, nondestructive, and scalable. It is also suitable for the transfer of graphene and other nanostructures. Furthermore, the relatively low temperature employed allows this technique to be compatible with nanomaterial-based flexible electronics.
