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二乙烯基苯改性中乙烯基聚丁二烯橡胶的研究
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作者 王玉荣 范赤 顾明初 《沈阳化工学院学报》 1996年第1期50-56,共7页
以n-BuLi为引发剂、环己烷为溶剂、二乙二醇二甲醚(2G)为调节剂、二乙烯基苯(DVB)为第二单体或偶联剂,由丁二烯以阴离子均聚合或共聚合方法全成了支化型中乙烯基聚丁二烯.考察了基础分子量(MB)、DVB及2G的加... 以n-BuLi为引发剂、环己烷为溶剂、二乙二醇二甲醚(2G)为调节剂、二乙烯基苯(DVB)为第二单体或偶联剂,由丁二烯以阴离子均聚合或共聚合方法全成了支化型中乙烯基聚丁二烯.考察了基础分子量(MB)、DVB及2G的加入量、反应时间对聚合物的支化度(f)、分子量分布指数(ID)、特性粘度([η])以及屈服强度(Ty)影响的规律性,结果表明:DVB的两种加入方式均能形成不同支化形式以及不同支化程度的中乙烯基聚丁二烯,使f、ID、以及Ty都得到相应的提高. 展开更多
关键词 中乙 基苯 聚乙二烯橡胶 改性
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The Effect of Ionizing Radiation and Magnetic Field on Deformation Properties of High Density PolyethylenelAcrylonitrile-Butadiene Composites
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《Journal of Chemistry and Chemical Engineering》 2012年第3期242-249,共8页
The effect of magnetic field and ionizing radiation on the mechanical properties of polymer blends consisting of high density polyethylene (HDPE) and acrylonitrile-butadiene rubber (NBR) has been investigated. The... The effect of magnetic field and ionizing radiation on the mechanical properties of polymer blends consisting of high density polyethylene (HDPE) and acrylonitrile-butadiene rubber (NBR) has been investigated. The purpose of the work was to create HDPE/NBR blend composites of significantly different compositions (with an excess of HDPE, intermediate ones, and with an excess of NBR) and to investigate the role of composition on mechanical deformation properties under the influence of magnetic field. The investigation has importance from the engineering viewpoint, since thermoplastic composite materials have been used as structural elements in thermonuclear and engineering fields, like wires, insulation materials and others, which are frequently subjected to mechanical loadings under the effect of magnetic field greater than 1 T. One part of the blends has been irradiated with 5 MeV accelerated electrons up to absorbed dose D equal to 150 kGy. Unirradiated and the radiation modified blends have been exposed to a constant magnetic field with induction B equal to 1.0 T, 1.5 T and 1.7 T. It is found that the action of magnetic field decreases the elastic modulus of unirradiated materials. Decrement of elastic modulus is reduced with increase of the content of NBR in composites. It is also found that preliminary irradiation noticeably decreases the effect of magnetic field. Data of the influence of the magnetic field, radiation cross-linking, and the ratio of the components on the creep are also obtained. 展开更多
关键词 Magnetic field radiation modification creep compliance POLYETHYLENE acrylonitrile-butadiene rubber.
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