To prevent expanded polystyrene (EPS) beads from rising up to the surface in the molding process of EPS lightweight concrete, vibration with pressure was applied and the polyvinyl acetate (PVA) emulsion was adopte...To prevent expanded polystyrene (EPS) beads from rising up to the surface in the molding process of EPS lightweight concrete, vibration with pressure was applied and the polyvinyl acetate (PVA) emulsion was adopted to improve its mechanical properties. The mechanical properties, thermal properties and durability of EPS lightweight concrete were tested. The microstruetures of EPS lightweight concrete were observed by scanning electron microscope (SEM). Vibration with pressure reduces the number of small cracks. The 180 d compressive strength and flexural strength increase obviously as a large amount of PVA was added. The mixed amount of PVA has no obvious influence on the thermal performance when it is not more than 10% of the cement. Vibration with pressure and surface modification of EPS beads by PVA improve the combination of EPS beads with cement stone and the mechanical properties of EPS lightweight concrete.展开更多
Polyethylene glycol(PEG) membranes with different molecular mass cut-offs were used to treat oil/water emulsion, and the effects of experimental conditions including pressure, temperature and different opera- ting mod...Polyethylene glycol(PEG) membranes with different molecular mass cut-offs were used to treat oil/water emulsion, and the effects of experimental conditions including pressure, temperature and different opera- ting modes on permeate flux and removal rate of chemical oxygen demand (COD_ Cr) were studied. The results show that the permeate flux of ultrafiltration membrane is influenced by pressure and temperature; practical pressure is chosen to be 0.30.7MPa for the PEG with molecular mass cut-offs of 8000 and 0.71.0 MPa for the PEG with molecular mass cut-offs of 2500; and the practical temperature is chosen to be 2532℃. Different operating modes of ultrafiltration also influence the permeate flux and removal rate of COD_ Cr. The ultrafiltration membrane of intermittent cross-flow operating mode is easier to be influenced by blocky polarization and contamination than that of sequential cross-flow operating mode. Removal rate of COD_ Cr in intermittent cross-flow and sequential cross-flow condition can be maintained at about 93%.展开更多
In this paper, the surface imprinted cross-linked polystyrene beads were prepared via suspension polymerization with styrene (St), divinylbezene (DVB), polyvinyl alcohol (PVA1788), the mixture of Span 85 and xylene or...In this paper, the surface imprinted cross-linked polystyrene beads were prepared via suspension polymerization with styrene (St), divinylbezene (DVB), polyvinyl alcohol (PVA1788), the mixture of Span 85 and xylene or the mixture of Span 85 and paraffin as monomer, cross-linking agent, dispersion stabilizer and templates, respectively. The results indicate that there are dense cavities on the surface of beads, and the diameter and density of cavity are related with the composition and amount of emulsion template. The forming mechanism of cavity from thermodynamics and dynamics was proposed.展开更多
基金Supported by Tianjin Natural Science Foundation (No.06YFJMJC05900)Science and Technology Key Project of Hebei Province (No.05213810)
文摘To prevent expanded polystyrene (EPS) beads from rising up to the surface in the molding process of EPS lightweight concrete, vibration with pressure was applied and the polyvinyl acetate (PVA) emulsion was adopted to improve its mechanical properties. The mechanical properties, thermal properties and durability of EPS lightweight concrete were tested. The microstruetures of EPS lightweight concrete were observed by scanning electron microscope (SEM). Vibration with pressure reduces the number of small cracks. The 180 d compressive strength and flexural strength increase obviously as a large amount of PVA was added. The mixed amount of PVA has no obvious influence on the thermal performance when it is not more than 10% of the cement. Vibration with pressure and surface modification of EPS beads by PVA improve the combination of EPS beads with cement stone and the mechanical properties of EPS lightweight concrete.
文摘Polyethylene glycol(PEG) membranes with different molecular mass cut-offs were used to treat oil/water emulsion, and the effects of experimental conditions including pressure, temperature and different opera- ting modes on permeate flux and removal rate of chemical oxygen demand (COD_ Cr) were studied. The results show that the permeate flux of ultrafiltration membrane is influenced by pressure and temperature; practical pressure is chosen to be 0.30.7MPa for the PEG with molecular mass cut-offs of 8000 and 0.71.0 MPa for the PEG with molecular mass cut-offs of 2500; and the practical temperature is chosen to be 2532℃. Different operating modes of ultrafiltration also influence the permeate flux and removal rate of COD_ Cr. The ultrafiltration membrane of intermittent cross-flow operating mode is easier to be influenced by blocky polarization and contamination than that of sequential cross-flow operating mode. Removal rate of COD_ Cr in intermittent cross-flow and sequential cross-flow condition can be maintained at about 93%.
文摘In this paper, the surface imprinted cross-linked polystyrene beads were prepared via suspension polymerization with styrene (St), divinylbezene (DVB), polyvinyl alcohol (PVA1788), the mixture of Span 85 and xylene or the mixture of Span 85 and paraffin as monomer, cross-linking agent, dispersion stabilizer and templates, respectively. The results indicate that there are dense cavities on the surface of beads, and the diameter and density of cavity are related with the composition and amount of emulsion template. The forming mechanism of cavity from thermodynamics and dynamics was proposed.