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双酚A型苯并噁嗪改性酚醛树脂模塑料的制备及性能研究 被引量:1
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作者 张博 王汝敏 +2 位作者 胡睿 王道翠 强雪原 《粘接》 CAS 2015年第8期59-63,共5页
通过溶剂法,制备了双酚A型苯并噁嗪(BOZ-A)。采用预浸料模压成型工艺制备出聚乙烯醇缩醛纤维(PVAF)增强BOZ-A改性酚醛树脂(PF)模塑料。分别采用FT-IR、1H-NMR、DSC、SEM等对BOZ-A结构、BOZ-A/PF共混树脂固化行为和模塑料的力学性能、热... 通过溶剂法,制备了双酚A型苯并噁嗪(BOZ-A)。采用预浸料模压成型工艺制备出聚乙烯醇缩醛纤维(PVAF)增强BOZ-A改性酚醛树脂(PF)模塑料。分别采用FT-IR、1H-NMR、DSC、SEM等对BOZ-A结构、BOZ-A/PF共混树脂固化行为和模塑料的力学性能、热性能进行了研究。结果表明,合成了预期结构的BOZ-A,噁嗪环成环率92.6%;BOZ-A/PF共混树脂工艺性良好,固化反应表观活化能为111.09 kJ/mol和73.73 kJ/mol;BOZ-A/PF质量比40/60时,模塑料性能最佳:收缩率、吸水性、冲击强度和弯曲强度分别为0.19%、0.187%、36.93 kJ/m^2、156.0 MPa,但其马丁耐热温度较改性前略有下降,为149.7℃。 展开更多
关键词 酚醛树脂 双酚A型苯并噁嗪 改性 聚乙烯醇缩醛纤维 模塑料
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Natural Gas-to-Acetylene Project Passed Acceptance Check at Sichuan Vinylon Works
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《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2005年第2期32-32,共1页
The natural gas-to-acetylene project at SINOPEC Sichuan Vinylon Works (SVW) had passed the acceptance examination on December 10, 2004. Completion of the project construction has expanded the production capacity at ... The natural gas-to-acetylene project at SINOPEC Sichuan Vinylon Works (SVW) had passed the acceptance examination on December 10, 2004. Completion of the project construction has expanded the production capacity at SVW, while raising on a higher rung the overall market competitiveness and risk response ability of this enterprise. 展开更多
关键词 天然气 乙炔 四川 聚乙烯醇缩醛纤维 中国石油化工集团公司
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Electrokinetic phenomena of poly(vinyl butyral) hollow fiber membranes in different electrolyte solutions
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作者 漆静 王永前 邱运仁 《Journal of Central South University》 SCIE EI CAS 2013年第6期1490-1495,共6页
The streaming potential of poly(vinyl butyral) (PVB) hollow fiber membrane was studied in different electrolyte solutions (including NaCl, KCl, CaCl2 and MgCl2), the effects of ionic strength, ion valence and pH... The streaming potential of poly(vinyl butyral) (PVB) hollow fiber membrane was studied in different electrolyte solutions (including NaCl, KCl, CaCl2 and MgCl2), the effects of ionic strength, ion valence and pH value on the streaming potential (SP) of the membrane were investigated. The zeta potentials and surface charge densities of the membrane were estimated on the basis of Helmholtz-Smoluchowski equation and Gouy-Chapmann theory. The results show that the PVB membrane has a weak negative charge due to the specific adsorption of ions. Moreover, the streaming potential, the zeta potential and the surface charge density of the membrane depend strongly on the salt concentration and the type and valence of ions. The iso-electric point (IEP) of the PVB membrane is arotmd 3.0 in the monovalent media (NaC1 and KC1) and 3.5 in divalent electrolytes (CaCl2 and MgCl2). A few retentions were obtained for PVB membrane in low concentration solutions. This result verifies that the negative charged membrane surface can reject inorganic solutes by means of electrostatic repulsion effect even though the size of membrane pores is much larger than the size of salts. 展开更多
关键词 streaming potential zeta potential poly(vinyl butyral) hollow fiber membrane
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