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聚二烷基硅烷的合成及其表征 被引量:5
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作者 宋恩峰 孙文艳 冯圣玉 《有机硅材料》 CAS 2007年第4期202-205,共4页
以二甲基二氯硅烷、二苯基二氯硅烷为原料,通过Wurtz还原反应合成出聚二甲基硅烷、聚二苯基硅烷,并用UV、1HNMR、FT-IR以及GPC、DSC-TGA等方法进行了光谱分析和结构表征。
关键词 二甲基 聚二苯基硅烷 二甲基二氯 二苯基二氯 Wurtz反应
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聚甲基氢硅烷及其共聚物的合成及发光性能的研究
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作者 廖学巍 史保川 +1 位作者 邓建平 张茂根 《有机硅材料》 CAS 2001年第4期8-10,共3页
以甲基二氯硅烷、二甲基二氯硅烷、二苯基二氯硅烷及甲基乙烯基二氯硅烷为原料 ,采用钠缩合法合成了聚甲基氢硅烷及聚甲基氢硅烷与聚二甲基硅烷、聚二苯基硅烷和聚甲基乙烯基硅烷的共聚物。并用IR、UV、1HNMR。
关键词 甲基 甲基二氯 甲基-二甲基 甲基-二苯基 合成 发光性能
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Toluene degradation by a water/silicone oil mixture for the design of two phase partitioning bioreactors 被引量:3
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作者 Maxime Guillerm Annabelle Couvert +3 位作者 Abdeltif Amrane Edith Norrant Audrey Breton éric Dumont 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2017年第10期1512-1518,共7页
Toluene degradation performances were studied in a 10 L Two-Phase Partitioning Bioreactor(TPPB).The liquid phase consisted of a mixture of water and PDMS 50(Poly Di Methyl Siloxane,i.e.silicone oil,viscosity of 46 m P... Toluene degradation performances were studied in a 10 L Two-Phase Partitioning Bioreactor(TPPB).The liquid phase consisted of a mixture of water and PDMS 50(Poly Di Methyl Siloxane,i.e.silicone oil,viscosity of 46 m Pa·s) in the volume ratio of 75%/25%.Two series of experiments were carried out:in the first,the reactor was sequentially supplied with toluene whereas in the second,toluene was continuously supplied.Activated sludge from the wastewater treatment plant of Beaurade(Rennes,France) was used at an initial concentration of 0.5 dry mass g·(mixture L)^(-1).The elimination capacity(EC) was investigated as well as the change in biomass concentration over time.Toluene biodegradation was very ef ficient(removal ef ficiency,RE=100%) for toluene flows ranging from 0.2 to 1.2 ml·h^(-1),corresponding to elimination capacities of up to 104 g·m^(-3)·h^(-1).For a toluene flow of 1.2 ml·h^(-1),the biomass concentration measured at the end of the experiment was 4.7 dry mass g·(mixture L)^(-1).The oxygen concentration in the liquid phase was clearly not a limiting factor in these operating conditions.Based on these results,an extrapolation leading to the design of a large-scale pilot TPPB can now be considered to study toluene degradation performances in industrial conditions. 展开更多
关键词 Degradation Toluene Silicone oil Multiphase reactor Biomass
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