Waste plastics are one of the biggest environmental concerns the world faces today. Waste plastics exposure to the environment is very hazardous. Over time waste plastics photo-degrade and become very tiny dust partic...Waste plastics are one of the biggest environmental concerns the world faces today. Waste plastics exposure to the environment is very hazardous. Over time waste plastics photo-degrade and become very tiny dust particles. These dust particles contain very harmful compounds including benzene, sulfur, carbon and many others. According to studies, waste plastic pollutions are one of the biggest reasons for the depletion of the ozone layer and contributor of global warming. Many scientists have been trying to figure out how to utilize these waste plastics and convert them into useful energy sources. It is possible to convert waste plastics into energy because they are made from petroleum. Scientists have succeeded in developing many methods including pyrolysis, catalytic cracking, thermal degrading and others. The purpose of this experiment is to convert these environmentally harmful waste materials into useful energy source using simple and viable methods. A particular thermal degradation process was successful in extracting fuel from waste plastics at 370-420 ~C. In this paper we will discuss our performed experiment and provide detailed analysis of the produced fuel. Thorough instrumental analysis of the produced fuel showed very considerable results including high energy contents, low levels of harmful emissions and compatibility with various types of existing appliances.展开更多
Reuse of concrete waste, especially in large quantity, can save not only material but also cost for its disposal. This paper presents experiment results on the use of fine and coarse aggregates from concrete waste in ...Reuse of concrete waste, especially in large quantity, can save not only material but also cost for its disposal. This paper presents experiment results on the use of fine and coarse aggregates from concrete waste in geopolymer mortars and concretes. Geopolymeric cement is an inorganic compounds of aluminosilicates synthesized from precursors with high content of silica and alumina activated by alkali silicate solutions. Geopolymer in this experiment was synthesized from fly ash as the precursor and sodium silicate solution as the activator. Hardening of geopolymers was performed by heating the casted paste in an oven at -60~Cfor 3 to 36 hours. Compressive strength of geopolymer pastes and mortars using either fresh or waste fine aggregates were in the range of 19-26 MPa. Hardening time of 3 hours at 60~C followed by leaving the test pieces at room temperature for 7 day before testing results in similar strength to that of mortars cured for 36 hours at 60~C followed by leaving the samples at room temperature for 3 days. It suggests that optimum strength can be achieved by combination of heating time and rest period before testing, i.e the specimens age. Applying mix design with a target strength of 40 MPa, conventional Portland cement concretes using fresh aggregates reached 70% of its target strength at day-7. Compressive strength of geopolymer concretes with waste aggregates was -25 MPa at day-3 while geopolymer concretes with fresh aggregates achieved -39 MPa at day-3. It can be concluded that geopolymer concretes can achieve the target strength in only 3 days. However, the expected reinforcing effect of coarse aggregates in concrete was ineffective if waste coarse aggregates were used as the strength of the concretes did not increase significantly from that of the mortars. On the other hand, waste fine aggregates can be reused for making geopolymer mortars having the same strength as the geopolymer mortars using fresh aggregates.展开更多
New route of the utilization of products obtained by waste plastic pyrolysis has been investigated. ct-olefin-succinic-anhydride intermediate based on new experimental additives has been developed and used for achievi...New route of the utilization of products obtained by waste plastic pyrolysis has been investigated. ct-olefin-succinic-anhydride intermediate based on new experimental additives has been developed and used for achieving the better properties of carbon fibre reinforced polymer composites. Hydrocarbon fractions were produced by the pure thermal pyrolysis of waste polymers in a tube reactor using 550 ℃ in the absence of oxygen. Selected compounds （C30-C50） from pyrolysis products have been used as raw materials in the additive synthesis step. Polymer composite specimens have been investigated among others by universal tensile machine, SEM （scanning electron microscopy） and FTIR （fourier transformed infrared spectroscopy） methods. The tensile strength could be increased by 29.9%, the E-modulus by 24.2% and the Charpy impact strength by 13.3% in the presence of the experimental additive. Fibre-matrix interaction has been studied on SEM micrographs of the fractured face of composites. The results of mechanical testes have been supported by the SEM micrographs and possible shames of the coupling have been proposed.展开更多
The search of biomass-based substitutes for fossil-based plastics has become a pressing task due to the severe long-term threats of plastic wastes to the ecosystem.However,the development in this area is strongly impe...The search of biomass-based substitutes for fossil-based plastics has become a pressing task due to the severe long-term threats of plastic wastes to the ecosystem.However,the development in this area is strongly impeded by the high cost of biomass separation and the poor processability of unseparated biomass.Herein,we demonstrate,for the first time,an efficient and scalable method to generate greener plastics by directly integrating unseparated biomass waste(i.e.,wood powder)with crosslinked covalent adaptable networks.Through a simple compression molding process,the wood biomass and polymer particles can be fused together to form a continuous material,which is endowed with repairability,reprocessibility,and closed-loop full recyclability.The method demonstrated in this work paves the way for largescale industrial production of environmentally friendly biomass-based plastics.展开更多
文摘Waste plastics are one of the biggest environmental concerns the world faces today. Waste plastics exposure to the environment is very hazardous. Over time waste plastics photo-degrade and become very tiny dust particles. These dust particles contain very harmful compounds including benzene, sulfur, carbon and many others. According to studies, waste plastic pollutions are one of the biggest reasons for the depletion of the ozone layer and contributor of global warming. Many scientists have been trying to figure out how to utilize these waste plastics and convert them into useful energy sources. It is possible to convert waste plastics into energy because they are made from petroleum. Scientists have succeeded in developing many methods including pyrolysis, catalytic cracking, thermal degrading and others. The purpose of this experiment is to convert these environmentally harmful waste materials into useful energy source using simple and viable methods. A particular thermal degradation process was successful in extracting fuel from waste plastics at 370-420 ~C. In this paper we will discuss our performed experiment and provide detailed analysis of the produced fuel. Thorough instrumental analysis of the produced fuel showed very considerable results including high energy contents, low levels of harmful emissions and compatibility with various types of existing appliances.
文摘Reuse of concrete waste, especially in large quantity, can save not only material but also cost for its disposal. This paper presents experiment results on the use of fine and coarse aggregates from concrete waste in geopolymer mortars and concretes. Geopolymeric cement is an inorganic compounds of aluminosilicates synthesized from precursors with high content of silica and alumina activated by alkali silicate solutions. Geopolymer in this experiment was synthesized from fly ash as the precursor and sodium silicate solution as the activator. Hardening of geopolymers was performed by heating the casted paste in an oven at -60~Cfor 3 to 36 hours. Compressive strength of geopolymer pastes and mortars using either fresh or waste fine aggregates were in the range of 19-26 MPa. Hardening time of 3 hours at 60~C followed by leaving the test pieces at room temperature for 7 day before testing results in similar strength to that of mortars cured for 36 hours at 60~C followed by leaving the samples at room temperature for 3 days. It suggests that optimum strength can be achieved by combination of heating time and rest period before testing, i.e the specimens age. Applying mix design with a target strength of 40 MPa, conventional Portland cement concretes using fresh aggregates reached 70% of its target strength at day-7. Compressive strength of geopolymer concretes with waste aggregates was -25 MPa at day-3 while geopolymer concretes with fresh aggregates achieved -39 MPa at day-3. It can be concluded that geopolymer concretes can achieve the target strength in only 3 days. However, the expected reinforcing effect of coarse aggregates in concrete was ineffective if waste coarse aggregates were used as the strength of the concretes did not increase significantly from that of the mortars. On the other hand, waste fine aggregates can be reused for making geopolymer mortars having the same strength as the geopolymer mortars using fresh aggregates.
文摘New route of the utilization of products obtained by waste plastic pyrolysis has been investigated. ct-olefin-succinic-anhydride intermediate based on new experimental additives has been developed and used for achieving the better properties of carbon fibre reinforced polymer composites. Hydrocarbon fractions were produced by the pure thermal pyrolysis of waste polymers in a tube reactor using 550 ℃ in the absence of oxygen. Selected compounds （C30-C50） from pyrolysis products have been used as raw materials in the additive synthesis step. Polymer composite specimens have been investigated among others by universal tensile machine, SEM （scanning electron microscopy） and FTIR （fourier transformed infrared spectroscopy） methods. The tensile strength could be increased by 29.9%, the E-modulus by 24.2% and the Charpy impact strength by 13.3% in the presence of the experimental additive. Fibre-matrix interaction has been studied on SEM micrographs of the fractured face of composites. The results of mechanical testes have been supported by the SEM micrographs and possible shames of the coupling have been proposed.
基金The authors would like to acknowledge Prof.Yifu Ding of the University of Colorado Boulder for the instrumentation support with DMA.This work was supported by the University of Colorado Boulder,Wong KC Education Foundation,and the National Natural Science Foundation of China(51673072).Su Z would like to thank China Scholarship Council(CSC)for financial support.
文摘The search of biomass-based substitutes for fossil-based plastics has become a pressing task due to the severe long-term threats of plastic wastes to the ecosystem.However,the development in this area is strongly impeded by the high cost of biomass separation and the poor processability of unseparated biomass.Herein,we demonstrate,for the first time,an efficient and scalable method to generate greener plastics by directly integrating unseparated biomass waste(i.e.,wood powder)with crosslinked covalent adaptable networks.Through a simple compression molding process,the wood biomass and polymer particles can be fused together to form a continuous material,which is endowed with repairability,reprocessibility,and closed-loop full recyclability.The method demonstrated in this work paves the way for largescale industrial production of environmentally friendly biomass-based plastics.
