硅丙乳液聚合过程稳定性影响研究

为了考察硅丙乳液聚合过程稳定性的影响因素,对硅丙乳液进行配方设计,考察了有机硅单体的用量、滴加方式、种类、反应温度等对乳液聚合过程及乳液稳定性的影响。测试结果表明:有机硅单体用量为5%时,乳液聚合稳定性和乳胶膜耐水白性达到平衡,平均凝胶率为0.09%;采用核壳结合滴加方式,乳液聚合稳定性最佳;使用有机硅单体A-174所得乳液平均凝胶率最小;当反应温度为80℃时,单体平均转化率和聚合稳定性达到平衡。

乳化剂体系对纯丙乳液聚合过程稳定性影响研究

通过对纯丙乳液乳化体系设计,考察了阴/非离子乳化剂类型、配比、用量及分配方式等对乳液聚合过程稳定性的影响,确定了纯丙乳液聚合过程最佳的聚合过程工艺参数。

The Study of the Influence of Load＇s Chemical Composition in the Coking Process on the Efficiency and the Quality of Coke

This research was performed in order to allow the study of the chemical composition influence of the coking process load on the efficiency and the quality of coke. For this reason, the coking of the following loads was realized： Atmospheric residue （RAT）, vacuum Residue （RSV） and catalytic Residue of cracking （RCC）. （The residues are obtained from an Algerian crude oil）. As the oil residues are rich for their strongly polar composition, such as the asphaltene resins, and complex structures units （SCU）, which has a role in the formation of coke, and as the dispersion of these latter improves the quality of coke, a study on the stability of aggregation was carried out by the addition of one stabilizer （oil Extract） in the coking process load, The Compounding （Extracted from/RCC oil） has been drived to the best efficiency of coke. The study consists of the influence this is characterized by the analyses Infra-red （IR） and x-ray diffraction （XRD）.