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室温离子液体催化合成聚对苯乙酰 被引量:5
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作者 张田林 缪晓亮 《石油化工高等学校学报》 CAS 2004年第2期43-46,共4页
 研究了由1,3-二烷基咪唑和烷基吡啶与无水三氯化铝构成的室温离子液体作为溶剂催化剂,通过苯乙酰氯发生Friedel-Crafts聚合反应,合成聚对苯乙酰的方法。实验结果表明,在室温离子液体中,苯乙酰氯的Friedel-Crafts聚合反应可在20~25℃...  研究了由1,3-二烷基咪唑和烷基吡啶与无水三氯化铝构成的室温离子液体作为溶剂催化剂,通过苯乙酰氯发生Friedel-Crafts聚合反应,合成聚对苯乙酰的方法。实验结果表明,在室温离子液体中,苯乙酰氯的Friedel-Crafts聚合反应可在20~25℃下顺利进行,聚对苯乙酰收率高于90%,并且Mw/Mn高达16500/7890。光谱分析数据证实:苯乙酰氯分子间的Friedel-Crafts聚合反应产物为聚对苯乙酰。 展开更多
关键词 聚对苯乙酰 1 3-二烷基咪唑 无水三氯化铝 催化剂 合反应 发光材料
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Structural Changes of Polyethylene Terephthalate Fibers Grafted by Acrylamide
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作者 施琴芬 戴礼兴 《Journal of Donghua University(English Edition)》 EI CAS 2003年第3期1-4,共4页
A group of grafted PET fibers with different graft yield are formed by grafting acrylamide onto the PET main chains. The structure of grafted fibers are studied by scanning electronic microscope ( SEM ), infra-red spe... A group of grafted PET fibers with different graft yield are formed by grafting acrylamide onto the PET main chains. The structure of grafted fibers are studied by scanning electronic microscope ( SEM ), infra-red spectrophotometer ( IR ), and differential scanning calorimetry(DSC). At the same time, the moisture regain, dyeability, strength, and elongation at break of the samples are measured and their relations with structural changes are discussed. Compared with ungrafted fiber, shape of the fiber cross-section, IR characteristic absorption peaks, and melting behavior of the grafted fibers have been changed, causing the fiber dyeability and moisture regain to be increased, and mechanical properties to be changed. 展开更多
关键词 polyethylene terephthalate fiber GRAFT ACRYLAMIDE STRUCTURE
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