泡泡刺叶磷酸烯醇式丙酮酸羧化酶季节性聚态变化

以不同季节的泡泡刺为研究对象 ,利用电泳并结合底物活性染色技术发现 ,在 5月 (春季 )的电泳图谱上未出现磷酸烯醇式丙酮酸羧化酶 (PEPC) ;7月 (夏季 )的 PEPC分子量 473k D,为四聚体 ;9月 (秋季 )的 PEPC以二聚体和四聚体两种形式存在 ,分子量分别大约是 192 k D和 473k D。泡泡刺不同季节叶片 δ1 3C值为 - 2 4‰～ -2 5‰ ,其解剖结构无“Kranz”结构。 5月和 7月叶片中苹果酸 (Mal)含量不具有昼夜波动 ,而 9月的 Mal含量具有昼低夜高的 CAM植物酸波动特征。结合泡泡刺不同季节的天门冬氨酸 (Asp)含量以及叶片细胞液 p H的测定结果 ,可初步判定泡泡刺为 C3植物 ,但在干旱胁迫较严重的 9月 ,在水分及温度等环境因子的作用下 ,PEPC的性质和作用发生了变化。

Effects of silica additive on the NH_3-SCR activity and thermal stability of a V_2O_5/WO_3-TiO_2 catalyst

V2O5/WO3‐TiO2 and V2O5/WO3‐TiO2‐SiO2 catalysts were prepared by a wetness impregnation method, and both the catalysts were hydrothermally aged at 750℃ in 10 vol%H2O/air for 24 h. The catalysts were evaluated for NOx conversion using NH3 as the reductant. Hydrothermal ageing decreased the NOx conversion of V2O5/WO3‐TiO2 catalyst severely over the entire measured tem‐perature range. Interestingly, the NH3‐SCR activity of the silica‐modified catalyst at 220–480℃ is enhanced after ageing. The catalysts were characterized by X‐ray diffraction, nitrogen adsorption, X‐ray fluorescence, Raman spectroscopy, H2 temperature‐programmed reduction, and NH3 temper‐ature‐programmed desorption. The addition of silica inhibited the phase transition from anatase to rutile titania, growth of TiO2 crystallite size and shrinkage of catalyst surface area. Consequently, the vanadia species remained highly dispersed and the hydrothermal stability of the V2O5/WO3‐TiO2 catalyst was significantly improved.

Coalescence Behaviors of Drop Swarms on Liquid-Liquid Interface

The trajectory model of dispersed phase drops and distribution model of drop diameters were derived.By numerical simulation,the analytical results indicate that a large number of dispersed phase drops accumulate on the upper plate in different directions and form a hydrodynamic area with the stream-wise location in the range of 0—0.4m,where the flow of trickling film obtains kinetic drive from flowing field.The flowing field of trickling film exhibits an unstable state if the stream-wise location is less than 0.02m,and a stable state otherwise.Moreover,different velocity vectors of drops in the x-y plane result in different interactions between the trickling film and drops.For the non-uniform distribution of drop diameters,there is a stronger interaction between the trickling film and drop if the stream-wise location is less than 0.02m,because the amplitudes of velocity vectors are higher than those in the range of 0.02—1.0m.The result reveals a complexity and diversity of stratified two-phase flowing field.On the other hand,both the basic flowing field and distributions of drop diameters have a great influence on the distributions of comparable kinetic energy of drops.The complicated motions of larger drops are helpful to coalescence because they will consume much more kinetic energy on the trickling film than those of smaller drops.The change of comparable kinetic energy of smaller drops is continuous and steady.The smaller drops are easily entrained by the liquid-liquid flowing field.

Source of the condensates from the Hetianhe Field and the genetic relationship between the condensates and their associated gases

A detailed correlation of Hetianhe condensates versus typical source rocks from the Tarim Basin was established. Moreover, the genetic relationship between the condensates and their associated gases was also studied based on their geochemical com- positions and fluid inclusion data. Hetianhe condensates are characterized by high pristine/phytane （Pr/Ph） ratios, high relative abundances of Czs regular steranes, C26-C27 triaromatic steroids, and triaromatic dinosteranes, and relatively heavy stable car- bon isotopic compositions. They geochemically correlate well with the Cambrian source rocks, indicating that these conden- sates are derived from the Cambrian rocks. Based on several molecular maturity parameters, the condensates are recognized as being moderately to highly mature, which are too low in maturity to extensively crack into gases. The gases and condensates of the Hetianhe Field are derived from the same source rocks and the gases are from oil-cracking; however, clear evidence indi- cates that the gases were not cracked from their associated condensates and that the gas generation from oil-cracking did not occur in the present reservoirs. The liquid condensates produced from wellheads were likely dissolved in their associated gases underground and carried into the reservoirs by the gases.

A strong Lewis acid imparts high ionic conductivity and interfacial stability to polymer composite electrolytes towards all-solid-state Li-metal batteries

The development of high-performance solid polymer electrolytes is crucial for producing all-solid-state lithium metal batteries with high safety and high energy density.However,the low ionic conductivity of solid polymer electrolytes and their unstable electrolyte/electrode interfaces have hindered their widespread utilization.To address these critical challenges,a strong Lewis acid(aluminum fluoride(AIF_(3)))with dual functionality is introduced into poly(ethylene oxide)(PEO)-based polymer electrolyte.The AlF;facilitates the dissociation of lithium salt,increasing the iontransfer efficiency due to the Lewis acid-base interaction;further the in-situ formation of lithium fluoride-rich interfacial layer is promoted,which suppresses the uneven lithium deposition and continuous undesired reactions between the Li metal and PEO matrix.Benefiting from our rational design,the symmetric Li/Li battery with the modified electrolyte exhibits much longer cycling stability(over 3600 h)than that of the pure PEO/lithium bis(trifluoromethanesulfonyl)imide(LiTFSI)electrolyte(550 h).Furthermore,the all-solid-state LiFeP04 full cell with the composite electrolyte displays a much higher Coulombic efficiency(98.4%after 150 cycles)than that of the electrolyte without the AlF;additive(63.3%after 150 cycles)at a large voltage window of 2.4-4.2 V,demonstrating the improved interface and cycling stability of solid polymer lithium metal batteries.

Energetics and kinetics of direct phase conversion from graphite to diamond

The atomistic mechanism for direct conversion of graphite to diamond is a long-standing problem in condensed matter physics. The newly identified cold-compressed graphite phases of M, W and 0 carbon provide a crucial link to understand the graphite-to- diamond phase transformation. We demonstrate by ab initio calculations that pressure has a dual role in lowering the conversion barrier and enhancing the production stability during the first-stage cold-compressed phase conversion of graphite toward the intermediate metastable M, W and 0 carbon phases. However, it has little effect on the relative enthalpy and high conversion barrier during the second-stage conversion process toward the diamond polytypes, showing a temperature dominated conversion process. These results may give explanation regarding the necessity of high pressure and high temperature during the graphite-to- diamond reaction.

Discrete-Time Chaotic Systems Synchronization Based on Vector Norms Approach

Suitable stabilization conditions obtained for continuous chaotic systems are generalized to discrete-time chaotic systems. The proposed approach, leading to these conditions for complete synchronization is based on the use of state feedback and aggregation techniques for stability studies associated with the arrow form matrix for system description. The results are successfully applied for two identical discrete-time hyper chaotic Henon maps with different orders and also for non-identical discrete-time chaotic systems with same order namely the Lozi and the Ushio maps.