废旧聚氯乙烯-粉煤灰复合材料的研究

以废旧聚氯乙烯和粉煤灰为原料 ,采用开放式塑炼机混炼、平板流化机层压成型工艺生产的复合制品 ,能满足使用要求 ,可作水泥等地板砖的替代品。实验中得出了最佳成型工艺参数和配方。此外 。

用DSC研究线形多嵌段聚氨酯与聚氯乙烯、氯化聚氯乙烯共混相容性

用示差扫描量热法（DSC）研究了线形多嵌段聚氨酯（PU）与聚氯乙烯（PVC）、氯化聚氯乙烯（CPVC）共混相容性，说明了PU／VC、PU／CPVC的相容是由于共混物中形成了新的氢键的缘故．聚酯型聚氨酯与PVC、CPVC的相容性要好子聚酸型聚氨酯，CPVC与PU的相容性又要好于PVC．聚氨酯中硬段的引入不利于PU／PVC、PU／CPVC的相容性．

采用变温变压吸附技术回收聚氯乙烯生产中的精馏尾气

介绍了聚氯乙烯精馏尾气变温变压吸附技术的应用情况及对该技术的调整和改进。

PVC/NBR/无机物混合发泡吸声材料

利用ＰＶＣ、ＮＢＲ、无机物等制成了一种吸声材料，该吸声材料具有低频吸声系数高、成型加工简单、成本低等优点。讨论了ＮＢＲ用量、厚度、容重等因素对吸声材料的吸声性能的影响。

PP-HBP改性PP/PVC的流变行为

研究了聚丙烯接枝超支化聚(酰胺-酯)(PP-HBP)/PP/聚氯乙烯(PVC)共混体系的流变行为。讨论了PP-HBP用量对PP/PVC共混体系流变行为的影响。结果表明,当PP/PVC共混体系中加入PP-HBP不大于5份时,PP/PVC/PP-HBP共混体系的表观粘度大于PP/PVC共混体系的;当加入PP-HBP大于5份时,PP/PVC/PP-HBP共混体系的表观粘度小于PP/PVC共混体系的;随着温度升高,PP/PVC和PP/PVC/PP-HBP共混体系表观粘度减小。

弱界面无机刚性粒子改性UPVC力学性能的研究

考察了硬脂酸包覆沉淀CaCO3的粒径、用量及塑炼温度对UPVC力学性能的影响。研究结果表明:减少CaCO3用量或CaCO3的粒径均有利于获得较高的屈服强度;增加CaCO3的用量或减少所用CaCO3的粒径均有利于UPVC弹性模量提高;适当增加亚微米或纳米CaCO3的用量可提高PVC的缺口冲击强度,亚微米CaCO3的最佳用量为15份,纳米CaCO3的最佳用量为40份。为了获得力学性能优化的UPVC,填充亚微米CaCO3的UPVC宜于较高温度加工,填充纳米CaCO3的UPVC宜于较低温度加工。在纳米CaCO3填充的UPVC中,仅用少量CPE即可得到超韧的UPVC材料。

Synthesis and characterization of colored layered double hydroxides for thermal stabilizer

Colored layered double hydroxides （LDHs） can be synthesized by introducing colored cations such as Fe^3＋ and Cr^3 ＋, which call be used as thermal stabilizers for polyvinyl chloride （PVC）. The yellowish Mg/Fe and bluish Mg/Cr LDHs are prepared by the co-precipitation method. The results show that the MgsCr_ CO3 and Mg3Fe_ CO3 colored layered double hydroxides can stabilize PVC for more than 30 min under the thermal aging temperature of 180 ℃. The preparation can use cheap Mg（OH） 2 instead of MgCl2, which produces a much smaller amount of the by-product NH4Cl. It is known that NH4Cl is a cheap fertilizer that is difficult to sell; therefore, the preparation is much greener and more economic than the one using magnesium salt.

Vinyl chloride monomer production catalysed by gold: A review

In this review we discuss the history of research into the use of gold for the acetylene hydrochlorin‐ation reaction, and describe the recent developments which have led to its commercialisation. We discuss the use of different precursors and the addition to gold of a secondary metal as methods which attempt to improve these catalysts, and consider the nature of the active gold species. The vast majority of poly vinyl chloride （PVC） produced globally still uses a mercuric chloride as a cata‐lyst, despite the environmental problems associated with it. Due to the agreement by the Chinese government to remove mercury usage in the PVC industry over the course of the next few years there is an obvious need to find a replacement catalyst;the potential use of gold for this process has been well known for several decades and to date gold seems to be the best candidate for this, pri‐marily due to its superior selectivity when compared to other metals.

Thermogravimetric-Mass Spectrometric Study of the Pyrolysis Behavior of PVC

The pyrolysis characteristics of PVC were systematically investigated using a Netzschne TG thermo-balance coupled to a quadrupole mass spectrometer. The pyrolysis conditions were 0.1 MPa of Ar, a heating rate of 10 ℃/min and a final temperature of 1000℃. Both the thermogravimetric properties and the simultaneous evolution of gaseous products during pyrolysis were studied. The TG/DTG results showed that as the pyrolysis temperature increases the weight loss and weight loss rate of PVC increases. Near 412℃ the weight loss rate attained its peak value. At higher temperatures the rate of loss gradually decreases. The gases evolved during thermogravimetric analysis were analyzed by a mass spectrometer, monitoring the relative intensity of HC1, C6H6, light hydrocarbon and chlorine-containing gases The evolution curves showed that HC1, C6H6, light hydrocarbon and chlorine-containing gases all peak at about 416℃. This is consistent with the fact that the weight loss curves also peak at about 412℃. The extensive HCl evolution is consistent with the high chlorine content of PVC. The formation of these gases can be explained by considering these reactions： dehydrochlorination, intramolecular cyclization and the addition of HCl to unsaturated hydrocarbons.

Faulty Sensor Detection and Reconstruction for a PVC Making Process

Based on principal component analysis, this paper presents an application of faulty sensor detection and reconstruction in a batch process, polyvinylchloride (PVC) making process. To deal with inconsistency in process data, it is proposed to use the dynamic time warping technique to make the historical data synchronized first,then build a consistent multi-way principal component analysis model. Fault detection is carried out based on squared prediction error statistical control plot. By defining principal component subspace, residual subspace and sensor validity index, faulty sensor can be reconstructed and identified along the fault direction. Finally, application results are illustrated in detail by use of the real data of an industrial PVC making process.

Influence of Suspended Emulsion Polymerization Conditions on Particle Characteristics of Polyvinyl Chloride Resin

Suspended emulsion polymerization of vinyl chloride was carried out in a 5 L autoclave. The influence of agitation, polymerization conversion, dispersant and surfactant on the average particle size (PS) and particle size distribution (PSD), particle morphology and porosity of polyvinyl chloride (PVC) resin was investigated. It showed that the agitator had great influence on the smooth operation of polymerization, PS and PSD. The PS increased and PSD became narrow as polymerization conversion became high. The porosity decreased with the increase of conversion. A convenient choice of additives, both dispersants and non-ionic surfactants, allows one to adjust PS and PSD. The PS decreased with the addition of polyvinyl alcohol or hydroxypropyl methylcellulose dispersants,and increased with the addition of Span surfactants. The addition of dispersants or surfactants also affected the morphology and porosity of resin, and PVC resin with looser agglomeration and homogeneous distribution of primary particles was prepared.

Synthesis of CaZnAl-CO3 ternary layered double hydroxides and its application on thermal stability of poly(vinyl chloride)resin

In this work,hydrothermal method was used to prepare the CaZnAl-CO3 ternary layered double hydroxides(CaZnAl-CO3-LDHs)with various Ca/Zn/Al molar ratios,which were characterized by X-ray diffraction(XRD),Fourier transform infrared spectroscope(FT-IR)and scanning electron microscopy(SEM)techniques.The obtained results demonstrate that the samples were well-crystallized and flake-structured.The CaZnAl-CO3-LDHs used alone for thermal stability of poly(vinyl chloride)(PVC)resin,with different Ca/Zn/Al molar ratios and varying additive amounts,were investigated through the tests such as static thermal aging,mass loss and congo red,respectively.The optimum Ca/Zn/Al molar ratio and additive amount were 3.6:0.4:2 and 5 phr(parts per hundred PVC resin),respectively.In addition,the synergistic effects of Ca3.6Zn0.4Al2-CO3-LDHs and CaSt2 were discussed in detail,showing better thermal stability compared with Ca3.6Zn0.4Al2-CO3-LDHs used alone,and the optimum additive amounts of Ca3.6Zn0.4Al2-LDHs and CaSt2 were 6 and 1.0 phr,respectively.

Phase Partition of Acrylonitrile(AN)in Vinylidene Chloride(VDC)/Water System and Its Effect on VDC-AN Copolymer Composition

Phase partition of acrylonitrile in the vinylidene chloride/water system at different temperature and under pressure was studied. A calculation method for average VDC-AN copolymer composition with AN phase partition considered was proposed. The calculated results are in good agreement with the experimental data nearly the entire conversion range. VDC-AN copolymer with narrower composition distribution can be prepared in the suspension process and interpreted with dynamic equilibrium of AN between the oil and water phases continuously.

Study on Removal of Bilirubin with Magnetic Affinity Separation Technique

An affinity adsorbent, Cibacron Blue 3GA immobilized magnetic polyvinyl alcohol (PVA) microspheres was used for bilirubin removal taking the advantage of easy separation of magnetic sorbent from the biosystem. Fe3O4 superparamagnetic particles was synthesized with hydrothermal reaction of ferrous chloride (FeCl2) and ferric chloride (FeCl3). Such magnetic particles are then encapsulated in biocompatible PVA to form magnetic polymer microspheres sized from 2 to 15 nm with hydroxyl groups on its surface. Cibacron Blue 3GA, a dye-ligand, was covalently coupled with the polyvinyl alcohol through the nucleophilic reaction between the chloride of its triazine ring and the hydroxyl groups of PVA molecules under alkaline condition. The affinity adsorbent carried 21.1μmol Cibacron Blue 3GA per gram magnetic polymer microspheres was used to remove unconjugated and conjugated bilirubin from the solution which was composed of bilirubin or bilirubin and protein. After the adsorption, the adsorbent loaded with bilirubin was removed easily in the magnetic field.

Teflon-pad shaping process of circular metal blanks into quasi-cup specimens by theoretical and experimental methods

Teflon-pad shaping process of circular metal blanks into quasi-cup specimens is investigated by theoretical and experimental methods in the quasi-static condition. In the experiments, circular metal sheets are formed into the quasi-cup samples by compressing them between a Teflon-filled die and a rigid punch with desirable shape. To investigate influences of different parameters on the forming progress, 12 rigid punches with different dimensions, two blank material types of aluminum and galvanized iron, three blank thicknesses of 0.6, 1.1 and 1.5 mm, and two Teflon-fillers of PVC and polyurethane are used in several experimental tests. In the analytical part, theoretical deformation models of metal blank and Teflon-filler are introduced and based on energy method, energy absorptions by the blank and Teflon-filler are calculated to derive a theoretical formula for predicting total required energy of the forming process. For this purpose, several energy absorption mechanisms are considered in the blank and filler. Furthermore, predictions by theoretical equation are compared with the corresponding experimental tests to study the verity of the calculated formulas. Theoretical and experimental results illustrate change trend of forming energy with respect to blank thickness. Also, the performed forming tests show that when external cone angle of rigid punch with respect to the horizontal direction increases, forming energy increases nonlinearly; and when the depth of spherical part of rigid punch increases, the probability of rupture increases. Additionally, the experiments demonstrate that there is a direct relationship between the forming energy and flow stress of the blanks. Furthermore, experimental observations illustrate that forming energy of a certain blank with PVC Teflon-filler is higher than that of a similar specimen with polyurethane Teflon-filler; but, the probability of wrinkling decreases when PVC Teflon-pad is used as the filler; and it is advantage of PVC Teflon-filler with respect to polyurethane Teflon.

Study on an Organic Hybrid Made from Chlorinated Polyethylene and 2,2'-methylene-bis- (4-methyl-6-cyclohexylphenol)

The dynamic mechanical properties and miscibility of an organic hybrid made from chlorinated polyethylene (CPE) and 2, 2'-methyIene-bis-( 4-methyl-6-cyclohexylphenol) ( ZKF ) are mainly discussed in this paper. It is found that ZKF acts as an antiplasticizer in CPE matrix and has good miscibility even with large ratio in CPE /ZKF hybrids. The glass transition temperature of various CPE /ZKF hybrids determined by DSC give a good fit to Wood's equation. Bifunctional ZKF is supposed to improve the intermolecular force of CPE, and the improvement is developed when the ZKF content increases. On the other hand, the viscoelastic properties are highly improved with the addition of ZKF. TA and tanδ peak values increase when the ZKF content increase in the CPE /ZKF hybrids, the damping capacity has been improved during the glass transition of CPE /ZKF hybrids. In addition, the glass transition temperature shifts to room temperature from the low temperature with the continuous addition of ZKF to CPE.

Preparation and characterization of polyvinylchloride membrane embedded with Cu nanoparticles for electrochemical oxidation in direct methanol fuel cell

Copper nanoparticles were prepared by the chemical reduction method.These copper particles were embedded into the polyvinylchloride(PVC)matrix as support and used as an electrode(PVC/Cu)for the oxidation of methanol fuel for improving the current response.The PVC/Cu electrodes were characterized by thermal gravimetric analysis(TGA)for thermal stability of the electrode,X-ray diffraction(XRD)for identification of copper nanoparticles in the electrode,Fourier transform infrared spectroscopy(FTIR)to identify the interaction between PVC and Cu and scan electron microscopy(SEM)with EDAX for the morphology of the electrode.The electrocatalytic activity of the electrode was characterized by the cyclic voltammetry,linear sweep voltammetry,and chronoamperometry techniques.An increase in the electrode activity was observed with the increase of copper quantity from 0.18 g(PVC/Cu-0.18 g)to 0.24 g(PVC/Cu-0.24 g)and the maximum was found at 0.24 g of copper in the electrode.Also,it was observed that the electrode achieved the maximum catalytic current in 0.5 mol/L CH3OH+1 mol/L Na OH solution.FTIR identified that water molecules,C—H group,copper nanoparticle and its oxide were available in the electrode.SEM images with EDAX showed that copper particles were properly embedded in the polyvinylchloride matrix.

Mechanism of Photo-Fenton Degradation of Ethanol and PVA

Contrast degradation experiments between ethanol and polyvinyl alcohol (PVA) were conducted during H2O2, UV/H2O2, Fenton, and Photo-Fenton processes in this study. UV/VIS spectra showed' that complexes between Fe(Ⅲ) and organics were easily formed and degraded within reaction time. Compared with ,the degradation of complex, hydroxyl radicals acted weakly in Fenton or Photo-Fenton process. Hydroxyl radi'cals involved in Photo-Fenton process were deemed to be generated from the split decomposition of H2O2, photolysis of Fe_aq^3+, and degradation of hydrated Fe(Ⅳ)-complex but not traditional Fenton reaction. Experimental evidence to support this point was presented in this paper.

Thermogravimetric characteristics and different kinetic models for medical waste composition containing polyvinyl chloride-transfusion tube

Thermogravimetric study of medical transfusion tube （MTT） waste containing polyvinyl chloride （PVC） was carried out using the thermogravimetric analyser （TGA） with N2, at different heating rates of 5, 10, 20, 30, 50 ℃/min. The purpose is to obtain pyrolysis characteristics and kinetic parameters of medical waste. The experimental results indicate that the pyrolysis behavior of the MTT sample is in agreement with its main ingredient of PVC, appearing two stair stepping stages. The influence of the additives in MTT on pyrolysis behavior was also revealed, which could improve MTT pyrolysis at lower temperature in the first stage, and cause obvious unsmoothness and asymmetry of the second DTG peak. Four n-order kinetic models of Coats-Redfern, Ozawa, Kissinger and Freeman-carroll were used to get the kinetic parameters. Furthermore, a novel ＂two-step four-reaction model＂ was established to simulate the whole continuous process. The different methods and the kinetic parameters thus obtained were discussed and compared with each other in literatures. The reasons of deviation among kinetic values were tried to be elucidated. The new established model could more satisfactorily describe the pyrolysis process of MTT, being more mechanistic and conveniently serving for the engineering.