建筑保温硬质聚氨酯泡沫塑料的发泡工艺与应用

介绍了建筑保温硬质聚氨酯泡沫塑料功用产品类型和特性,在此基础上阐述了聚酯氨的发泡原料及其添加剂,给出了聚酯氨泡沫的生产方法,最后论述了建筑保温用聚酯氨泡沫在建筑领域的应用。

Performance characterization, of rigid polyurethane foam with refined alkali lignin and modified alkali lignin

The two kinds of rigid polyurethane （PU） foams were prepared with respectively adding the refined alkali lignin and alkali lignin modified by 3-chloro-1,2-epoxypropane to be instead of 15% of the polyether glycol in weight. The indexes of mechanical performance, apparent density, thermal stability and aging resistance were separately tested for the prepared PU foams. The results show that the mechanical property, thermal insulation and thermal stability for PU foam with modified alkali lignin are excellent among two kinds of PU foams and control samples. The additions of the refined alkali lignin and modified alkali lignin to PU foam have little effect on the natural aging or heat aging resistance except for decreasing hot alkali resistance apparently. Additionally, the thermal conductivity of modified alkali lignin PU foam is lowest among two kinds of PU foams and control samples. The alkali lignin PU foam modified by 3-chloro-1,2-epoxypropane could be applied in the heat preservation field.

Numerical study of forward smoldering combustionof polyurethane foam

A two-dimensional and two-phase numerical model is presented for the smolder propagation in a horizontal polyurethane foam. The chemical processes considered include endothermic pyrolysis and exotherrnic oxidation degradation of polyurethane foam and exothermic oxidation of char. The governing equations are discretized in space using the finite element method and solved by the software package FEMLAB. Predicted profiles of solid temperature as well as evolutions of solid compositions （including foam, char and ash） are presented at an airflow velocity of 0. 28 cm/s. The computed average smoldering velocity is 0. 021 4 cm/s, and the average maximum temperature is 644. 67 K. Based on the evolutions of solid compositions, the packed bed can be obviously divided into four zones： unreacted zone, fuel pyrolysis and oxidation zone, char oxidation zone and fuel burned-out zone. Simultaneously, the effects of inlet air velocity and fuel properties （including thermal conductivity, specific heat, density and pore diameter） are studied on the smoldering propagation. The results show that the smoldering velocity and temperature have a roughly linear increase with increasing inlet air velocity; the fuel density is the most important factor in determining smoldering propagation; radiation has a non-negligible role on the smoldering velocity for larger pore diameters of porous material. The computational results are compared with the experimental data and a general agreement is reached.

Compression behavior and constitutive model establishment of fly ash cenosphere/polyurethane aluminum alloy syntactic foam

The aluminum matrix syntactic foam was fabricated by pressure infiltration technique,and the filling material is syntactic foam material with fly ash cenosphere as the main component and polyurethane foam as the binder.Split Hopkinson pressure bar(SHPB)dynamic compression and quasi-static tests were carried out to examine the compressive response of syntactic foam in this study.Then the dynamic constitutive model was established.Results show that the compressive stress-strain curve of syntactic aluminum foam is similar to that of other metallic foam materials:both kinds of aluminum matrix syntactic foams have strain rate effect,and the syntactic foam has higher compressive strength and energy absorption than the same density aluminum foams.However,due to the different sizes of cenospheres,the dynamic compression results of two kinds of syntactic foams are different,and the energy absorption effect of syntactic foam with small size under dynamic impact is the best.In the range of strain rate and density studied experimentally,the curves of constitutive model fit well with the curves of experimental data.

Effect of dosage of expandable graphite,dimethyl methylphosphonate,triethanolamine,and isocyanate on fluidity,mechanical,and flame retardant properties of polyurethane materials in coal reinforcement

In this study,orthogonal experiments were conducted to investigate the influence of expandable graphite(EG),dimethyl methylphosphonate(DMMP),triethanolamine(TEA),and isocyanate content on the compressive and bonding strengths,oxygen index,and fluidity of rigid polyurethane foam(RPUF).The results revealed that EG significantly increased the oxygen index of RPUF,enlarged the diameter of foam cells,and decreased the cell-closed content in foam;thus,leading to a pressure drop in RPUF.However,excessive EG was capable of reducing the fluidity of polyurethane slurry.TEA exhibited significant influence on the compressive strength of RPUF,which dropped initially,and then increased.DMMP had a remarkable effect on the flame retardant property and compressive strength of RPUF.Compressive strength of RPUF initially displayed an increase followed by a decrease with increasing dosage of DMMP,and achieved the maximum value at DMMP dosage of 4%.DMMP could effectively reduce the diameter of RPUF cells leading to an increase in the percentage of close area in foam.DMMP displayed the flame-retardation effects mainly in the gas phase leading to a significant enhancement in the oxygen index of RPUF.Moreover,the compressive strength and bonding strength of RPUF decrease significantly with the increase of isocyanate content due to the increased blowing efficiency by the CO_2.The oxygen index and flowing length of foam increased with the increase in isocyanate dosage.

Improvement of the riboflavin production by engineering the precursor biosynthesis pathways in Escherichia coli

3,4-Dihydroxy-2-butanone 4-phosphate （DHBP） and GTP are the precursors for riboflavin biosynthesis. In this research, improving the precursor supply for riboflavin production was attempted by overexpressing ribB and engineering purine pathway in a riboflavin-producing Escherichia colt strain. Initially, ribB gene was overexpressed to increase the flux from ribulose 5-phosphate （Ru-5-P） to DHBP. Then ndk and grnk genes were overexpressed to enhance GTP supply. Subsequently, a R419L mutation was introduced into purA to reduce the flux from IMP to AMP. Finally, co-overexpression of mutant purF and prs genes further increased riboflavin production. The final strain RF18S produced 387.6 mg riboflavin · L-1 with a yield of 44.8 mg riboflavin per gram glucose in shake-flask fermentations. The final titer and yield were 72.2% and 55.6% higher than those of RF01S, respectively. It was concluded that simultaneously engineering the DHBP synthase and GTP biosynthetic pathway by rational metabolic engineering can efficiently boost riboflavin production in E. coll.

Experimental Analysis on Local Buckling of GFRP?Foam Sandwich Pipe Under Axial Compressive Loading

To find out the local buckling behaviors of glass fiber reinforced plastic(GFRP)-foam sandwich pipe suffering axial loading,a series of quasi-static axial compression tests are carried out in the laboratory.Comparing with the test data,systematic numerical analysis on the local buckling behavior of this sandwich pipe is also conducted,and the buckling failure mechanism is revealed.The influences of the key parameters on bearing capacity of the sandwich structure are discussed.Test and numerical results show that the local buckling failure of the GFRPfoam sandwich pipe is dominated basically by two typical modes,i.e.,the conjoint buckling and the layered buckling.Local buckling at the end,shear failure at the end and interface peeling failure are less efficient than the local buckling failure at the middle height,and ought to be restrained by appropriate structural measures.The local buckling bearing capacity increases linearly with the core density of the sandwich pipe structure.When the core density is relatively high(higher than 0.05 g/cm3),the effect of increasing the core density on improving the bearing efficiency is less on the specimens with a large ratio of the wall thickness to the radius than on those with a small one.Local layered buckling is another failure mode with lower bearing efficiency than the local conjoint buckling,and it can be restrained by increasing the core density to ensure the cooperation of the inner and the outer GFRP surface layer.The bearing capacity of the GFRP-foam sandwich pipe increases with the height-diameter ratio;however,the bearing efficiency decreases with this parameter.

The Type of Catalyst to Physical Properties of Soy-Based Polyurethane

Flexible Polyurethane （PU） foam is the material most widely used among urethanes. The foams were synthesized via the reaction of soy polyol, mixtures of isocyanates MDI：TDI （80：20）, in the presence of water （blowing agent） with molding process. This experiment was to analyze the physical properties of soy polyol and elaborate the principle of catalyst within the synthesis. The use of liquid and solid catalyst on the polyol synthesis results in significant cellular morphology and properties of polyurethane foam. It is found that the PU which was synthesized using bentonite catalyst has an irregular form of cell morphology, and it has higher density than using sulphuric acid catalyst.

Usage of Polyurethane Foam Acoustic Insulation in Cineplex Steel Structure

Modern public buildings, such as multiplex cinemas and theaters, along with application of state of the art sound effects bring high acoustic insulation demands. Cinemas are often a part of building complexes such as shopping malls with subjects that produce serious level of noise and vibrations. Apart to regular use of polyurethane in thermal insulation purposes, it is widely used in field of acoustic insulation. Usage of polyurethane foam pads, with specific dynamic characteristics, as a base for structure supports gives a wide range of possibilities in controlling the amount of structural noise and vibrations transferred to the structure. Structure itself and acoustical pads becomes an integral system that behaves together and need to be analyzed as a whole in extensive design. Dynamic characteristics of acoustic pads depend on stress level and in same time they represent elastic supports to the structure and therefore analyzes and design is an iterative process. In other way, introduce of non-conventional material in bearing structure brings some issues, such as transfer of shear forces, that has to be governed by proper structural detailing. There are several possibilities of application in bearing structures, such as above and below steel structure. This paper gives an overall view on polyurethane as material, construction and design principles and example of usage of acoustic pads in steel structure of＂Ster＂ cineplex in Belgrade.