A planar metal complex NiL, H2L=acenaphthenequinone bis(S benzyldithiocarbazate), 1, has been prepared via the template effect of nickel ion. Crystal structure of 1 was determined by X ray diffraction analysis and sho...A planar metal complex NiL, H2L=acenaphthenequinone bis(S benzyldithiocarbazate), 1, has been prepared via the template effect of nickel ion. Crystal structure of 1 was determined by X ray diffraction analysis and shows the planar coordination configuration around the central nickel atom. Z scan measurements show that 1 is a transition metal complex exhibiting high third order nonlinear optical effect.展开更多
文摘A planar metal complex NiL, H2L=acenaphthenequinone bis(S benzyldithiocarbazate), 1, has been prepared via the template effect of nickel ion. Crystal structure of 1 was determined by X ray diffraction analysis and shows the planar coordination configuration around the central nickel atom. Z scan measurements show that 1 is a transition metal complex exhibiting high third order nonlinear optical effect.