A validated numerical model was established to simulate gas−liquid flow behaviors in the oxygen-enriched side-blown bath furnace.This model included the slip velocity between phases and the gas thermal expansion effec...A validated numerical model was established to simulate gas−liquid flow behaviors in the oxygen-enriched side-blown bath furnace.This model included the slip velocity between phases and the gas thermal expansion effect.Its modeling results were verified with theoretical correlations and experiments,and the nozzle-eroded states in practice were also involved in the analysis.Through comparison,it is confirmed that the thermal expansion effect influences the flow pattern significantly,which may lead to the backward motion of airflow and create a potential risk to production safety.Consequently,the influences of air injection velocity and furnace width on airflow behavior were investigated to provide operating and design guidance.It is found that the thin layer melt,which avoids high-rate oxygen airflow eroding nozzles,shrinks as the injection velocity increases,but safety can be guaranteed when the velocity ranges from 175 to 275 m/s.Moreover,the isoline patterns and heights of thin layers change slightly when the furnace width increases from 2.2 to 2.8 m,indicating that the furnace width shows a limited influence on production safety.展开更多
Two dense pellicular agarose-glass matrices of different sizes and densities, i.e., AG-S and AG-L, have been characterized for their bed expansion behavior, flow hydrodynamics and particle classifications in an expand...Two dense pellicular agarose-glass matrices of different sizes and densities, i.e., AG-S and AG-L, have been characterized for their bed expansion behavior, flow hydrodynamics and particle classifications in an expanded bed system. A 26 mm ID column with side ports was used for sampling the liquid-solid suspension during expanded bed operations. Measurements of the collected solid phase at different column positions yielded the particle size and density distribution data. It was found that the composite matrices showed particle size as well as density classifications along the column axis, i.e., both the size and density of each matrix decreased with increasing the axial bed height. Their axial classifications were expressed by a correlation related to both the particle size and density as a function of the dimensionless axial bed height. The correlation was found to fairly describe the solid phase classifications in the expanded bed system. Moreover, it can also be applied to other two commercial solid matrices designed for expanded bed applications.展开更多
The supercritical fluid crystallization technique is a novel technology for preparing ultrafine particles. This paper introduced the concept and features of the technique with an emphasis on three kinds of supercritic...The supercritical fluid crystallization technique is a novel technology for preparing ultrafine particles. This paper introduced the concept and features of the technique with an emphasis on three kinds of supercritical fluid crystallization techniques, i.e. rapid expansion of supercritical solutions, supercritical fluid anti-solvent and particles from gas saturated solutions Some questions and the prospect of this technique were also discussed.展开更多
A method named as 'volume-expanding and pressure-reducing adsorption' is proposed. It can be used to measure the isotherms under supercritical condition. The adsorption isotherms of phenol on activated carbons...A method named as 'volume-expanding and pressure-reducing adsorption' is proposed. It can be used to measure the isotherms under supercritical condition. The adsorption isotherms of phenol on activated carbons and polymeric adsorbents are estimated and compared respectively for the systems of 'phenol-activated carbon-supercritical fluid CO2' and 'phenol-polymeric adsorbent-supercritical fluid CO2'. The results show that the amount of phenol adsorbed on the activated carbons and the polymeric adsorbents under the supercritical condition is much less than that under the general condition, which can be utilized to develop a technology regenerating the activated carbon with supercritical fluid. Moreover, the effects of ethyl alcohol, used as the third component, on the isotherms of phenol on the activated carbons and polymeric adsorbents under the supercritical condition are also investigated.展开更多
Despite the developments of sectors which aim at valorizing recyclable materials, landfills remain essential in integrated waste management. The construction of such infrastructures is an engineering challenge that mu...Despite the developments of sectors which aim at valorizing recyclable materials, landfills remain essential in integrated waste management. The construction of such infrastructures is an engineering challenge that must be proven over the long term. The purpose of this study is to understand the modification of the hydromechanical properties of bottom liners of landfills that may occur during their exploitation under leachate action. To do so, on the basis of its parameters of nature, a swelling clay from Burkina Faso is selected from soils of seven localities in Burkina Faso （West Africa）. Laboratory tests carried out with distilled water and then with a young synthetic leachate show a degradation of the permeability of this clay from 2.42 × 10^-10 m/s to 1.01 × 10^-9 m/s. In addition, leachate leads to an inhibition of the swelling and a remarkable increase of its compressibility, inducing significant settlement. With the increase in permeability, the primary consolidation settlement is increasing faster. Changes in the hydromechanical behavior can be attributed to the clays mineralogy, mainly cation exchange and the development of the diffuse double layer.展开更多
Experimental study is performed to design and develop a cylindrical micro-pump driven by expansion and contraction of the heat deformation material, whose variation is caused with the aid of heating and cooling proper...Experimental study is performed to design and develop a cylindrical micro-pump driven by expansion and contraction of the heat deformation material, whose variation is caused with the aid of heating and cooling properties of Peltier devices. The pump consists of the diffuser valve unit, the heat deformation material unit, the nozzle valve unit, the Peltier devices and the cover. The input current of the Peltier devices is controlled by the bipolar power supply so that the Peltier devices are heated and cooled periodically. The working fluid flow in the micro-pump is caused by the periodical thermal deformation of material which is caused by the periodical heating and cooling of the Peltier devices. In order to measure the fluid flow in the micro-pump, micro air bubbles are employed as a tracer. The corresponding movement is recorded by X-ray apparatus and its velocity is measured by PIV （particle image velocimetry）. It is found that, the micro-pump developed here can make the working fluid flow. The corresponding fluid flow in the micro pump is confirmed by the numerical method.展开更多
The leakage research on supercritical carbon dioxide fluid in rolling piston expander was investigated experimentally.Using expander instead of throttle valve is an important way to improve the efficiency of carbon di...The leakage research on supercritical carbon dioxide fluid in rolling piston expander was investigated experimentally.Using expander instead of throttle valve is an important way to improve the efficiency of carbon dioxide refrigeration system.However,the supercritical fluid leakage in expander is serious and is the main factor affecting the expander's efficiency.This paper presented and compared four classic leakage models.The analysis indicated that laminar leakage model is suitable in leakage simulation of expander.A leakage test system,including the leakage test part which has two types of leakage specimens with different gaps ranging from 5 to 15 m,was established.The experimental results indicated that lubricant film played an important role.When the leakage clearance of cylindrical specimen was 5 m,the mass flow rate of leakage was about 0.88 g s-1.The data was 3.638 g s-1 with leakage clearance being 10 m and 7.11g s-1 with leakage clearance being 15 m.A modified leakage model was developed,whose average deviation was within 10% compared with the experimental data.At last,this paper simulated the leakage in rolling piston expander presented by Tian et al.(2010).The leakage between rolling piston and cylinder was the most serious part with the value up to 0.04 kg s-1.展开更多
A simulation for piston effect in supercritical carbon dioxide by employing a simple model is conducted. In the first place, the thermal properties of carbon dioxide near its liquid-vapor critical point are discussed....A simulation for piston effect in supercritical carbon dioxide by employing a simple model is conducted. In the first place, the thermal properties of carbon dioxide near its liquid-vapor critical point are discussed. It is calcu- lated that the heat capacity ratio and isobaric expansion coefficient of supercritical fluids are extremely high. Furthermore, the simulation for piston effect in supereritical carbon dioxide between two infinite vertical walls is presented. The numerical results prove that piston effect has a much faster speed of heat transfer than thermal conduction under mierogravity conditions. Moreover, the piston effect turns out to be stronger when closer to the critical point.展开更多
Tin selenides have been attracting great attention as anode materials for the state-of-the-art rechargeable sodium-ion batteries(SIBs)due to their high theoretical capacity and low cost.However,they deliver unsatisfac...Tin selenides have been attracting great attention as anode materials for the state-of-the-art rechargeable sodium-ion batteries(SIBs)due to their high theoretical capacity and low cost.However,they deliver unsatisfactory performance in practice,owing to their intrinsically low conductivity,sluggish kinetics and volume expansion during the charge-discharge process.Herein,we demonstrate the synthesis of SnSe2 nanocrystals coupled with hierarchical porous carbon(SnSe2 NCs/C)microspheres for boosting SIBs in terms of capacity,rate ability and durability.The unique structure of SnSe2 NCs/C possesses several advantages,including inhibiting the agglomeration of SnSe2 nanoparticles,relieving the volume expansion,accelerating the diffusion kinetics of electrons/ions,enhancing the contact area between the electrode and electrolyte and improving the structural stability of the composite.As a result,the as-obtained SnSe2 NCs/C microspheres show a high reversible capacity(565 mA h g^-1 after 100 cycles at 100 mA g^-1),excellent rate capability,and long cycling life stability(363 mA h g^-1 at1 A g^-1 after 1000 cycles),which represent the best performances among the reported SIBs based on SnSe2-based anode materials.展开更多
We present a general analysis on non-static axial system with dissipative shear-free anisotropic fluid using polynomial inflationary f(R) model.We study the effects of dissipation on the dynamics of geodesic matter di...We present a general analysis on non-static axial system with dissipative shear-free anisotropic fluid using polynomial inflationary f(R) model.We study the effects of dissipation on the dynamics of geodesic matter distribution.This leads the system either to rotation-free or expansion-free but not both simultaneously under geodesic condition.It is found that the system preserves its symmetry in both cases.For the rotation-free case,when there is no dissipation and Ricci scalar is constant,the axial system reduces to FRW universe model.This is exactly the same result obtained in general relativity.展开更多
基金the support from the National Key R&D Program of China(No.2018YFC1901606).
文摘A validated numerical model was established to simulate gas−liquid flow behaviors in the oxygen-enriched side-blown bath furnace.This model included the slip velocity between phases and the gas thermal expansion effect.Its modeling results were verified with theoretical correlations and experiments,and the nozzle-eroded states in practice were also involved in the analysis.Through comparison,it is confirmed that the thermal expansion effect influences the flow pattern significantly,which may lead to the backward motion of airflow and create a potential risk to production safety.Consequently,the influences of air injection velocity and furnace width on airflow behavior were investigated to provide operating and design guidance.It is found that the thin layer melt,which avoids high-rate oxygen airflow eroding nozzles,shrinks as the injection velocity increases,but safety can be guaranteed when the velocity ranges from 175 to 275 m/s.Moreover,the isoline patterns and heights of thin layers change slightly when the furnace width increases from 2.2 to 2.8 m,indicating that the furnace width shows a limited influence on production safety.
基金Supported by the National Natural Science Foundation of China (No. 20025617).
文摘Two dense pellicular agarose-glass matrices of different sizes and densities, i.e., AG-S and AG-L, have been characterized for their bed expansion behavior, flow hydrodynamics and particle classifications in an expanded bed system. A 26 mm ID column with side ports was used for sampling the liquid-solid suspension during expanded bed operations. Measurements of the collected solid phase at different column positions yielded the particle size and density distribution data. It was found that the composite matrices showed particle size as well as density classifications along the column axis, i.e., both the size and density of each matrix decreased with increasing the axial bed height. Their axial classifications were expressed by a correlation related to both the particle size and density as a function of the dimensionless axial bed height. The correlation was found to fairly describe the solid phase classifications in the expanded bed system. Moreover, it can also be applied to other two commercial solid matrices designed for expanded bed applications.
文摘The supercritical fluid crystallization technique is a novel technology for preparing ultrafine particles. This paper introduced the concept and features of the technique with an emphasis on three kinds of supercritical fluid crystallization techniques, i.e. rapid expansion of supercritical solutions, supercritical fluid anti-solvent and particles from gas saturated solutions Some questions and the prospect of this technique were also discussed.
基金Supported by the National Natural Science Foundation of China(No.29936100)and the National Science Foundation ofGuangdong Province(No.990629).
文摘A method named as 'volume-expanding and pressure-reducing adsorption' is proposed. It can be used to measure the isotherms under supercritical condition. The adsorption isotherms of phenol on activated carbons and polymeric adsorbents are estimated and compared respectively for the systems of 'phenol-activated carbon-supercritical fluid CO2' and 'phenol-polymeric adsorbent-supercritical fluid CO2'. The results show that the amount of phenol adsorbed on the activated carbons and the polymeric adsorbents under the supercritical condition is much less than that under the general condition, which can be utilized to develop a technology regenerating the activated carbon with supercritical fluid. Moreover, the effects of ethyl alcohol, used as the third component, on the isotherms of phenol on the activated carbons and polymeric adsorbents under the supercritical condition are also investigated.
文摘Despite the developments of sectors which aim at valorizing recyclable materials, landfills remain essential in integrated waste management. The construction of such infrastructures is an engineering challenge that must be proven over the long term. The purpose of this study is to understand the modification of the hydromechanical properties of bottom liners of landfills that may occur during their exploitation under leachate action. To do so, on the basis of its parameters of nature, a swelling clay from Burkina Faso is selected from soils of seven localities in Burkina Faso （West Africa）. Laboratory tests carried out with distilled water and then with a young synthetic leachate show a degradation of the permeability of this clay from 2.42 × 10^-10 m/s to 1.01 × 10^-9 m/s. In addition, leachate leads to an inhibition of the swelling and a remarkable increase of its compressibility, inducing significant settlement. With the increase in permeability, the primary consolidation settlement is increasing faster. Changes in the hydromechanical behavior can be attributed to the clays mineralogy, mainly cation exchange and the development of the diffuse double layer.
文摘Experimental study is performed to design and develop a cylindrical micro-pump driven by expansion and contraction of the heat deformation material, whose variation is caused with the aid of heating and cooling properties of Peltier devices. The pump consists of the diffuser valve unit, the heat deformation material unit, the nozzle valve unit, the Peltier devices and the cover. The input current of the Peltier devices is controlled by the bipolar power supply so that the Peltier devices are heated and cooled periodically. The working fluid flow in the micro-pump is caused by the periodical thermal deformation of material which is caused by the periodical heating and cooling of the Peltier devices. In order to measure the fluid flow in the micro-pump, micro air bubbles are employed as a tracer. The corresponding movement is recorded by X-ray apparatus and its velocity is measured by PIV （particle image velocimetry）. It is found that, the micro-pump developed here can make the working fluid flow. The corresponding fluid flow in the micro pump is confirmed by the numerical method.
基金supported by the National Natural Science Foundation of China (Grant No. 50676064)
文摘The leakage research on supercritical carbon dioxide fluid in rolling piston expander was investigated experimentally.Using expander instead of throttle valve is an important way to improve the efficiency of carbon dioxide refrigeration system.However,the supercritical fluid leakage in expander is serious and is the main factor affecting the expander's efficiency.This paper presented and compared four classic leakage models.The analysis indicated that laminar leakage model is suitable in leakage simulation of expander.A leakage test system,including the leakage test part which has two types of leakage specimens with different gaps ranging from 5 to 15 m,was established.The experimental results indicated that lubricant film played an important role.When the leakage clearance of cylindrical specimen was 5 m,the mass flow rate of leakage was about 0.88 g s-1.The data was 3.638 g s-1 with leakage clearance being 10 m and 7.11g s-1 with leakage clearance being 15 m.A modified leakage model was developed,whose average deviation was within 10% compared with the experimental data.At last,this paper simulated the leakage in rolling piston expander presented by Tian et al.(2010).The leakage between rolling piston and cylinder was the most serious part with the value up to 0.04 kg s-1.
基金financially supported by the National Basic Research Program of China (973 Program) under Grant No.2012CB933200the National Natural Science Foundation of China under Grant No.51161140332
文摘A simulation for piston effect in supercritical carbon dioxide by employing a simple model is conducted. In the first place, the thermal properties of carbon dioxide near its liquid-vapor critical point are discussed. It is calcu- lated that the heat capacity ratio and isobaric expansion coefficient of supercritical fluids are extremely high. Furthermore, the simulation for piston effect in supereritical carbon dioxide between two infinite vertical walls is presented. The numerical results prove that piston effect has a much faster speed of heat transfer than thermal conduction under mierogravity conditions. Moreover, the piston effect turns out to be stronger when closer to the critical point.
基金supported by the National Key R&D Research Program of China (2016YFB0100201)Beijing Natural Science Foundation (JQ18005)+2 种基金the National Natural Science Foundation of China (51671003, 21802003)China Postdoctoral Science Foundation (2019TQ0001)the start-up supports from Peking University and Young Thousand Talented Program
文摘Tin selenides have been attracting great attention as anode materials for the state-of-the-art rechargeable sodium-ion batteries(SIBs)due to their high theoretical capacity and low cost.However,they deliver unsatisfactory performance in practice,owing to their intrinsically low conductivity,sluggish kinetics and volume expansion during the charge-discharge process.Herein,we demonstrate the synthesis of SnSe2 nanocrystals coupled with hierarchical porous carbon(SnSe2 NCs/C)microspheres for boosting SIBs in terms of capacity,rate ability and durability.The unique structure of SnSe2 NCs/C possesses several advantages,including inhibiting the agglomeration of SnSe2 nanoparticles,relieving the volume expansion,accelerating the diffusion kinetics of electrons/ions,enhancing the contact area between the electrode and electrolyte and improving the structural stability of the composite.As a result,the as-obtained SnSe2 NCs/C microspheres show a high reversible capacity(565 mA h g^-1 after 100 cycles at 100 mA g^-1),excellent rate capability,and long cycling life stability(363 mA h g^-1 at1 A g^-1 after 1000 cycles),which represent the best performances among the reported SIBs based on SnSe2-based anode materials.
文摘We present a general analysis on non-static axial system with dissipative shear-free anisotropic fluid using polynomial inflationary f(R) model.We study the effects of dissipation on the dynamics of geodesic matter distribution.This leads the system either to rotation-free or expansion-free but not both simultaneously under geodesic condition.It is found that the system preserves its symmetry in both cases.For the rotation-free case,when there is no dissipation and Ricci scalar is constant,the axial system reduces to FRW universe model.This is exactly the same result obtained in general relativity.
