胶结石掏挖基础挖方定额编制及原始数据分析研究

缘于西北荒漠地区特殊的胶结石地质掏挖基础爆破挖方施工的特殊性,其成本费用无法通过现行行业定额得到精确体现。为了提高精益化投资控制,通过实测4项具有此类地质的掏挖基础爆破挖方样本工程,测算出成本费用,并对成本构成及成本费用水平的对比分析,得出成本费用的合理性。弥补了行业定额计价体系针对胶结石地质挖孔基础爆破挖方成本的缺陷。

结石康胶囊抗尿路结石的作用

目的 :研究结石康抗尿路结石的作用。方法 :用乙二醇和氯化铵喂饲大鼠制备肾结石模型 ;用人尿路结石植入大鼠膀胱制备大鼠膀胱结石模型 ;结石康灌胃 2周 ,观察对肾结石大鼠的影响。结果 :结石康对肾结石大鼠肾组织含水量、肾结石程度、肾组织中草酸和钙离子含量均有明显降低作用 ,对大鼠植入性膀胱结石的形成有一定的抑制作用。结论 :结石康有较好的抗尿路结石的作用。

Failure mechanisms and destruction characteristics of cemented coal gangue backfill under compression effect of non-uniform load

Backfill mining is one of the most important technical means for controlling strata movement and reducing surface subsidence and environmental damage during exploitation of underground coal resources. Ensuring the stability of the backfill bodies is the primary prerequisite for maintaining the safety of the backfilling working face, and the loading characteristics of backfill are closely related to the deformation and subsidence of the roof. Elastic thin plate model was used to explore the non-uniform subsidence law of the roof, and then the non-uniform distribution characteristics of backfill bodies’ load were revealed. Through a self-developed non-uniform loading device combined with acoustic emission (AE) and digital image correlation (DIC) monitoring technology, the synergistic dynamic evolution law of the bearing capacity, apparent crack, and internal fracture of cemented coal gangue backfills (CCGBs) under loads with different degrees of non-uniformity was deeply explored. The results showed that: 1) The uniaxial compressive strength (UCS) of CCGB increased and then decreased with an increase in the degree of non-uniformity of load (DNL). About 40% of DNL was the inflection point of DNL-UCS curve and when DNL exceeded 40%, the strength decreased in a cliff-like manner;2) A positive correlation was observed between the AE ringing count and UCS during the loading process of the specimen, which was manifested by a higher AE ringing count of the high-strength specimen. 3) Shear cracks gradually increased and failure mode of specimens gradually changed from “X” type dominated by tension cracks to inverted “Y” type dominated by shear cracks with an increase in DNL, and the crack opening displacement at the peak stress decreased and then increased. The crack opening displacement at 40% of the DNL was the smallest. This was consistent with the judgment of crack size based on the AE b-value, i. e., it showed the typical characteristics of “small b-value-large crack and large b-value-small crack”. The research results are of significance for preventing the instability and failure of backfill.

东庄水利枢纽围堰选型研究

东庄上游围堰是陕西省首座采用胶结石渣料填筑的水利工程,堰高55.2m,堰前库容2582万m^(3),为4级建筑物。堰址距拱坝较近,不具备布置当地材料围堰条件,加之工程区灰岩石渣丰富,可选择胶结颗粒料填筑围堰。对胶结石渣料、堆石混凝土两种筑坝型式从断面设计、原材料选择、配合比设计、施工方法及工期投资等方面进行对比分析,采用工期较短、连续拌和、填筑快速、投资较少的胶结石渣填筑围堰。2022年2月15日~5月3日用时2.5个月完成堰体填筑,平均月上升22m.节省工期28%,为坝基提前1个月开挖创造了条件,可促进胶结颗粒料筑坝新技术推广应用。随着智慧水利和3D打印大坝技术的进一步发展,胶结石渣料筑坝技术将具有更好的发展前景。

Sandstone Diagenesis and Porosity Evolution of Paleogene in Huimin Depression

The sandstones of the paleogene in the Huimin Depression have undergone numerous diagenetic processes, such as compaction, cementation, dissolution, metasomasis and recrystallization. The first three — compaction, cementation and dissolution — affect reservoir properties most intensively. An average porosity loss due to compaction is 0.78% per 100 meters, slightly higher in the central and southern parts and lower in the northern. Cementation has resulted in the porosity loss from 8% to 20% at a depth below 1,500 meters. Dissolution, which in most cases is the dissolution of feldspar and of carbonate cement, primarily occurs in two depth intervals, from 1,400 to 2,500 meters and 2,700 to 4,000 meters respectively. New porosity is created through dissolution from 4% to 14%. The sandstones experienced stage A and stage B of early diagenesis and stage A of late diagenesis. At present, most of them are experiencing Phase A2 of late diagenesis. The types of pores in the sand reservoir can be grouped into primary and secondary ones.

Performance of cemented coal gangue backfill

Possibility of cemented gangue backfill was studied with gangue of Suncun Coal Mine, Xinwen Coal Group, Shandong, and fly ash of nearby thermal power plant, in order to treat enormous coal gangue on a large scale and to recovery safety coal pillars. The results indicate that coal gangue is not an ideal aggregate for pipeline gravity flow backfill, but such disadvantages of gangue as bad fluidity and serious pipe wear can be overcome by addition of fly ash. It is approved that quality indexes such as strength and dewatering ratio and piping feature of slurry can satisfy requirement of cemented backfill if mass ratio of cement to fly ash to gangue is 1:4:15 and mass fraction of solid materials reaches 72%-75%. Harden mechanism suggests that the cemented gangue fill has a higher middle and long term comprehensive strength.

Effects of curing under step-by-step load on mechanical and deformation properties of cemented gangue backfill column

A step-by-step load was utilized to mimic the load history of the backfill column in the in-situ curing process.The inner damage of the specimen during curing and uniaxial compressive testing was monitored by electrical resistivity and ultrasonic equipment.Results show that:1)Uniaxial compressive strength(UCS)and elastic modulus(EM)of the samples curing under pressure are higher than those of the control samples without pressure,ranging in ratio from 0.5%to 20.2%and 7.1%to 52.3%,respectively,and are influenced by the initial loading age(ILA)and stress strength ratio(SSR).The SSR during curing should not exceed 80%.2)The earlier the ILA is,the higher the total strain becomes.The higher the SSR applies,the larger the total strain gets.The creep strain increases with the increase of SSR and can be described by Burger’s viscoelastic creep model.When SSR is less than 80%,the earlier the ILA is,the smaller the creep strain becomes after the last step-loading.3)The stability of the early age backfill column under pressure can be monitored based on the change of ultrasonic pulse velocity(UPV)and electrical resistivity.

Effects of temperature and age on physico-mechanical properties of cemented gravel sand backfills

Cemented backfill used in deep mines would inevitably be exposed to the ambient temperature of 20−60℃in the next few decades.In this paper,two types of cemented gravel sand backfills,cemented rod-mill sand backfill(CRB)and cemented gobi sand backfill(CGB),were prepared and cured at various temperatures(20,40,60℃)and ages(3,7,28 d),and the effects of temperature and age on the physico-mechanical properties of CRB and CGB were investigated based on laboratory tests.Results show that:1)the effects of temperature and age on the physico-mechanical properties of backfills mainly depend on the amount of hydration products and the refinement of cementation structures.The temperature has a more significant effect on thermal expansibility and ultrasonic performance at early ages.2)The facilitating effect of temperature and age on the compressive strength of CGB is higher than that on CRB.With the increase of temperature,the compressive failure modes changed from X-conjugate shear failure to tensile failure,and the integrity of specimens was significantly improved.3)Similarly,the shear performance of CGB is generally better than that of CRB.The temperature has a weaker effect on shear strength than age,but the shear deformation and shear plane morphology are closely related to temperature.

Mechanical properties of bimrocks with high rock block proportion

For the investigation of mechanical properties of the bimrocks with high rock block proportion,a series of laboratory experiments,including resonance frequency and uniaxial compressive tests,are conducted on the 64 fabricated bimrocks specimens.The results demonstrate that dynamic elastic modulus is strongly correlated with the uniaxial compressive strength,elastic modulus and block proportions of the bimrocks.In addition,the density of the bimrocks has a good correlation with the mechanical properties of cases with varying block proportions.Thus,three crucial indices(including matrix strength)are used as basic input parameters for the prediction of the mechanical properties of the bimrocks.Other than adopting the traditional simple regression and multi-regression analyses,a new prediction model based on the optimized general regression neural network(GRNN)algorithm is proposed.Note that,the performance of the multi-regression prediction model is better than that of the simple regression model,owing to the consideration of various influencing factors.However,the comparison between model predictions indicates that the optimized GRNN model performs better than the multi-regression model does.Model validation and verification based on fabricated data and experimental data from the literature are performed to verify the predictability and applicability of the proposed optimized GRNN model.

The Cemented Material Dam： A New, Environmentally Friendly Type of Dam

The first author proposed the concept of the cemented material dam （CMD） in 2009. This concept was aimed at building an environmentally friendly dam in a safer and more economical way for both the dam and the area downstream. The concept covers the cemented sand, gravel, and rock dam （CSGRD）, the rockfill concrete （RFC） dam （or the cemented rockfill dam, CRD）, and the cemented soil dam （CSD）. This paper summarizes the concept and principles of the CMD based on studies and practices in projects around the world. It also introduces new developments in the CSGRD, CRD, and CSD.

Temperature effect on shear behavior of ore-backfill coupling specimens at various shear directions

Understanding the temperature effect on shear behavior of the ore-backfill coupling structure is critical for the safety and stability of backfill stope under the condition of high horizontal stress in deep mining.Direct shear tests were carried out on the cemented rod-mill sand backfill(CRB)and ore-CRB(OCRB)coupling specimens at various temperatures(20,40 and 60°C).The shear behavior and AE characteristic parameters of OCRB at different shear directions were compared and analyzed.The results show that the temperature effect on the shear performance of CRB mainly depends on the characteristics of microstructures and main mineral phases;the performance of CRB at 40°C is relatively good;the shear deformation of OCRB has one more“peak fluctuation stage”than CRB and has a good correlation with AE characteristic parameters.The temperature can positively or negatively impact the shear strength of OCRB,depending on the temperature and shear direction;the shear performance of OCRB along the axis direction(D1)is significantly better than that perpendicular to the axis direction(D2).The co-bearing capacity of the ore-backfill coupling structure(i.e.,stopes)is closely related to the ambient temperature and principal stress orientation.

Water-resisting ability of cemented broken rocks

Using the self-designed testing system, the seepage tests for cemented broken rocks were conducted, and the impact of different factors on water-resisting ability was analyzed. The results show that(1) seepage process of the cemented broken rocks can be divided into two categories: in one category, seepage instability occurs after a period of time, in the other, the permeability decreases slowly and tends to be stable,and seepage instability does not occur;(2) cementing performance of cementing agent and grain size distribution are the decisive factors for water-resisting ability, with the increase of cementing performance and the mass percentage of large grains, the water-resisting ability of the specimen strengthens;(3)aggregate type has little effect on seepage stability, for the specimens with different aggregate types,the permeability and the duration of seepage instability have small difference;(4) initial porosity has a certain effect on the water-resisting ability of the specimen, but has no decisive role. With the increase of the initial porosity, the duration of seepage instability decreases.

Cemented backfill technology based on phosphorous gypsum

Physical-chemical properties of phosphorous gypsum, proportion and cemented mechanism of slurry with gypsum as aggregate were studied to remove the harms of gypsum pile, combining with difficult problems of excessive mined-out gobs, enormous ore body under roadway and low recovery ratio of Yongshaba Mine, Kaiyang Phosphor Mine Group, Guizhou Province, China. An appropriate backfill system and craflwork were designed, using shattering milling method to crush gypsum, double-axles mixing and strong activation mixing way to mix slurry, cemented slurry and mullock backfill alternately process. The results show that gypsum is fit for backfilling afterwards by adding fly ash, though it is not an ideal aggregate for fine granule and coagulate retardation. The suggested dosage （the mass ratio of cement to fly ash to gypsum） is 1：1：6-1：1：8 with mass fraction of solid materials 60%-63%. Slurry is transported in suspend state with non-plastic strength, and then in concretion state after backfilling. The application to mine shows the technology is feasible, and gypsum utilization ratio is up to 100%. Transportation and backfill effect is very good for paste-like slurry and drenching cemented slurry into mullock, and the compressive strength and recovery ratio are 2.0 MPa and 82.6%, respectively, with the maximum subsidence of surface only 1.307 mm. Furthermore, the investment of system is about 7 × 10^6 yuan （RMB）, only 1/10 of that of traditional paste backfill system.

Theoretical analysis of a new segmented anchoring style in weakly cemented soft surrounding rock

According to the tensile failure of rock bolt in weakly cemented soft rock, this paper presents a new segmented anchoring style in order to weaken the cumulative effect of anchoring force associated with the large deformation. Firstly, a segmented mechanical model was established in which free and anchoring section of rock bolt were respectively arranged in different deformation zones. Then, stress and displacement in elastic non-anchoring zone, elastic anchoring zone, elastic sticking zone, softening sticking zone and broken zone were derived respectively based on neural theory and tri-linear strain softening constitutive model of soft rock. Results show that the anchoring effect can be characterized by a supporting parameter b. With its increase, the peak value of tangential stress gradually moves to the roadway wall, and the radial stress significantly increases, which means the decrease of equivalent plastic zone and improvement of confining effect provided by anchorage body. When b increases to 0.72, the equivalent plastic zone disappears, and stresses tend to be the elastic solutions. In addition, the anchoring effect on the displacement of surrounding rock can be quantified by a normalization factor δ.

Diagenesis characteristics and their influence on porosity and permeability of sandstone from Yingcheng Formation in Jinshan field

In order to understand the diagenesis and its influence on porosity and permeability of sandstones from Yingcheng Formation in Jinshan field,applying thin sections,casting and scanning electron microscope,the authors studied petrography,diagenesis,porosity and permeability of Yingcheng Formation sandstone reservoir. The results show that the reservoir of Yingcheng Formation is mainly composed of lithic arkoses. Sandstones experienced compaction,pressolution,cementation,metasomatism and dissolution. The primary pores of the sandstones are undeveloped; most of pores are the secondary pores,which are mainly intragranular dissolution pores in feldspar and debris. The compaction and cementation reduced the primary pores in sandstones,the porosity and permeability decreased; while the dissolution formed the secondary pores,resulting in the porosity and permeability increase. Due to compaction and cementation,the porosity and permeability are reduced with increasing of depth. There exists an abnormal enlargement of porosity and permeability within a depth range 2310--2450 m. In combination with analysis of petrology,the dissolution of feldspar and debris is most developed in the depth range. Therefore,compaction,cementation and dissolution are the important factors which affect the porosity and permeability of sandstones.

Effect of the Alumosilicate Gels pH on Zeolite Phase Composition for the Co-crystallization of BEA/MOR Zeolites in Na2O-TEABr-Al2O3-SiO2-H2O System

This paper deals with the method of zeolites BEA （beta） and MOR （mordenite） synthesis and the co-crystallization method of zeolites BEA/MOR. Synthesized zeolites were studied based on the SEM （scanning electron microscopy）, XRD （x-ray diffraction） and chemical analysis. The porous structure of these zeolites was investigated by nitrogen low-temperature adsorption. It has been illustrated that regulation of the BEA/MOR co-crystalline zeolites phase composition is possible due to variations of the initial alumosilicate gels composition and hydrogen ions concentration. Zeolites containing the co-crystalline phases of BEA/MOR could to be attractive in the processes using the catalysts, which based on the pure phases BEA or MOR zeolites.

Degradation Characteristics and Community Structure of a Hydrocarbon Degrading Bacterial Consortium

A hydrocarbon degrading bacterial consortium KO5-2 was isolated from oil-contaminated soil of Karamay in Xinjiang, China, which could remove 56.9% of 10 g/L total petroleum hydrocarbons(TPH) at 30 ℃ after 7 days of incubation, and could also remove 100% of fluorene, 98.93% of phenanthrene and 65.73% of pyrene within 3, 7 and 9 days, respectively. Twelve strains from six different genera were isolated from KO5-2 and only eight ones were able to utilize the TPH. The denaturing gradient gel electrophoresis(DGGE) was used to investigate the microbial community shifts in five different carbon sources(including TPH, saturated hydrocarbons, fluorene, phenanthrene and pyrene). The test results indicated that the community compositions of KO5-2 in carbon sources of TPH and saturated hydrocarbons, respectively, were roughly the same, while they were distinctive in the three different carbon sources of PAHs. Rhodococcus sp. and Pseudomonas sp. could survive in the five kinds of carbon sources. Bacillus sp., Sphingomonas sp. and Ochrobactrum sp. likely played key roles in the degradation of saturated hydrocarbons, PAHs and phenanthrene, respectively. This study showed that specific bacterial phylotypes were associated with different contaminants and complex interactions between bacterial species, and the medium conditions influenced the biodegradation capacity of the microbial communities involved in bioremediation processes.

cDNA cloning and expression of a collectin from red-spotted grouper(Epinephelus akaara)

Lectins play a crucial role in the innate immunity of invertebrates and vertebrates by recognizing and disposing of pathogens. We obtained the complete cDNA of a C-type lectin （EALecl） from Epinephelus akaara using RACE. The complete EALecl cDNA sequence was 827 bp. The 5-UTR and 3-UTR were 28 bp and 151 bp, respectively, in length. The sequence also contained a polyadenylation signal AATAAA and a poly（A） tail. The EALecl cDNA encodes polypeptides with 215 amino acids, including a signal peptide of 31 amino acids. The protein has a cysteine-rich region at the N terminal, a collagenous region characterized by G-X-Y repeats, a neck region, and a typical carbohydrate-recognition domain （CRD）, indicating that EALecl is a collectin. The key recognition positions of this CRD are EPD, isolated for the first time in fish. These are likely the interim types, between mannan-binding lectin and galactose-binding lectin. We evaluated the expression pattern of EALecl in 12 different tissues using RT-PCR. EALecl was expressed in all tissues, though at different levels. In addition, we inserted EALecl into an expression vector （pET-28a） for transformation into the BL21 engineering bacteria. Based on enzyme digestion and sequencing of the positive clone, we successfully constructed the EALecl recombinant expression vector.

Cementation and diagenetic fluid of algal dolomites in the Sinian Dengying Formation in southeastern Sichuan Basin

The Sinian Dengying Formation in China hosts one of the oldest gas-bearing reservoirs in the world.With a long geological history,it has developed into the reservoir rocks,whose quality depends on chemical dissolution and cementation.Despite presence of cavities and pores in the algal dolomites of the Dengying Formation,they were mostly filled with various forms of dolomite cements.Therefore,the investigation of these dolomites and their evolution is significant for analyzing the mechanism of pore space preservation.There are five types of cements in the Dengying Formation,which were well sampled for lab measurements such as thin section,cathodeluminescence,minor elements,isotope analysis of carbon,oxygen and strontium,in attempt to explore the fillers' geochemical characteristics and the diagenetic fluids.They are characterized as follows:firstly,fibrous rim dolomite cement is a typical product formed at sea bottom,and geochemically very similar to the matrix(micrite and microcrystalline dolomite),which could be a reflection of the geochemical characteristics of water at that time;secondly,the diagenetic fluids of the foliated dolomite cements tend to be inheriting,derived from the shallow burial "imprisoned" seawater;thirdly,fine-to medium-grained dolomite cements with fairly high strontium isotopes and low carbon and oxygen isotopes were precipitated chiefly in freshwater during the period of uplifting caused by Tongwan tectonic movement;fourthly,coarse-grained dolomite cements bear a relatively high percentage of Mn element,but low in Fe and Sr,with carbon and oxygen isotopes remarkably shifted to negative values,which all show that they are related to hydrocarbon maturation and migration,and corresponding Thermochemical Sulfate Reduction;lastly,saddle-shaped dolomite cements are hydrothermally associated,and they were formed in high-temperature brine,which had passed through the areas rich in radioactive strontium isotopes.