微正则系综中理想气体能壳厚度问题

对于微正则系综中能壳的厚度,不同文献中有不同的表述。与以往的结论不同,本文利用理想气体的熵的详细推导,指出理想气体系统的能壳厚度必须大于系统中单个粒子的平均能量。

外置耗能壳板的钢框架桥墩抗震性能数值研究

将结构震后功能可恢复和耗能构件可更换引入钢框架桥墩:在墩柱塑性铰区外置低屈服耗能壳板来保护墩柱主体结构,且外置耗能壳板易于震后修复或更换。采用数值模拟方法比较研究了钢框架桥墩与外置耗能壳板的钢框架桥墩的滞回曲线、耗能能力、等效黏滞阻尼比、刚度和强度等抗震性能,探讨了外置耗能壳板参数(如材料屈服应力、安装高度和厚度等)对钢框架桥墩抗震性能的影响及其规律。结果表明:外置耗能壳板的钢框架桥墩抗震性能优于钢框架桥墩,且外置耗能壳板先于墩柱屈服,可有效保护墩柱主体免遭地震损伤;外置耗能壳板安装高度和厚度明显影响钢框架桥墩的抗震性能,而外置耗能壳板屈服应力对钢框架桥墩抗震性能的影响可忽略。

Antoioxidant Activity of Carboxymethyl Chitosan with Different Substituted Degrees

[Objective] In order to study the relations among different positions, degrees of substitution and antioxidant ability. [Method] N, O-carboxymethyl chitosan （NOA, NOB and NOC）with various degrees of substitution （DS）were obtained by etherizing chito-oligosacchaside. Their structure and substituted degree were characterized and their antioxldant activity to·OH was evaluated. [ Result] The IC50 s of NOA ,NOB and NOC were 0.15 ,0. 29 ,0. 23 mg/ml while their DSs of -NH2 position（DSN） were 0.51,0.29 and 0.38 and DSo were 0. 74 ,0. 84 ,0. 97respectively.[ Conclusion] With the increase of DSN ,antioxidant activity of N,O-carboxymethyl chitosan oligosaccharide to·OH was up.

In vitro corrosion resistance and antibacterial properties of layer-by-layer assembled chitosan/poly-L-glutamic acid coating on AZ31 magnesium alloys

Surface functionalization of magnesium(Mg)alloys is desired to obtain the surfaces with both improved corrosion resistance and antibacterial property.A corrosion-resistant and antimicrobial coating was prepared on Mg alloy surface by layer-by-layer(LbL)assembly of chitosan(CHI)and poly-L-glutamic acid(PGA)by electrostatic attraction.The functionalized surfaces of the Mg alloys were characterized by field-emission scanning electron microscopy(FE-SEM),Fourier transform infrared(FT-IR)spectroscopy and electrochemical tests.The bactericidal activity of the samples against Staphylococcus aureus was assessed by the zone of plate-counting method.The obtained coating on the Mg alloy substrates exhibits good corrosion resistance and antibacterial performance.

Structure, properties and application to water-soluble coatings of complex antimicrobial agent Ag-carboxymethyl chitosan-thiabendazole

The structure, properties and application to water-soluble coatings of a new complex antimicrobial agent Ag-carboxylmethyl citosan-thiabendazole （Ag-CMCTS-TBZ） prepared from different materiel ratios were reported. The silver ions were preferably coordinated with the free-NH2 groups and the -OH groups of secondary alcohol and carboxyl in CMCTS. TBZ preferably bonded to carboxyl group in CMCTS by electrostatic force and hydrogen bonding. Increase in silver ions content in the complex agent improved to some limited extent the antibacterial activity, but enhanced coloring and cost of the complex agent. Increase in TBZ content resulted in increase of antifungal activity, but decrease of water solubility of the complex agent. The antimicrobial MICs of the complex agent to Esherichia coil, Staphylococcus aureus, Candida albicans, Aspergillus niger, Mucor sp. were 20 -80, 15 -60, 20 - 55, 40 - 250, and 400 - 1700 mg/kg, respectively. Addition of 0.1% of this complex agent to acrylic emulsion paint made the paint without substantial change in color, luster, viscosity, odor or pH value, but with an excellent and chronically persisting broad-spectra antimicrobial activity.

Pharmacokinetics and Biodegradation Performance of a Hydroxypropyl Chitosan Derivative

Hydroxypropyl chitosan(HP-chitosan) has been shown to have promising applications in a wide range of areas due to its biocompatibility, biodegradability and various biological activities, especially in the biomedical and pharmaceutical fields. However, it is not yet known about its pharmacokinetics and biodegradation performance, which are crucial for its clinical applications. In order to lay a foundation for its further applications and exploitations, here we carried out fluorescence intensity and GPC analyses to determine the pharmacokinetics mode of fluorescein isothiocyanate-labeled HP-chitosan(FITC-HP-chitosan) and its biodegradability. The results showed that after intraperitoneal administration at a dose of 10 mg per rat, FITC-HP-chitosan could be absorbed rapidly and distributed to liver, kidney and spleen through blood. It was indicated that FITC-HP-chitosan could be utilized effectively, and 88.47% of the FITC-HP-chitosan could be excreted by urine within 11 days with a molecular weight less than 10 k Da. Moreover, our data indicated that there was an obvious degradation process occurred in liver(< 10 k Da at 24 h). In summary, HP-chitosan has excellent bioavailability and biodegradability, suggesting the potential applications of hydroxypropyl-modified chitosan as materials in drug delivery, tissue engineering and biomedical area.

Recent crustal movement and great earthquakes in Qinghai-Tibet sub-plate

Crustal movement and incremental-movement data observed repeatedly at GPS stations during 1999 -2009 were analyzed to study the effect of two earthquakes of Ms8.1 and Ms8.0 that occurred in 2001 and 2008, respectively, in Qinghai-Tibet sub-plate and its eastern margin. The result revealed certain anoma- lous pre-earthquake deformation and some large co-seismic changes. Prior to the 2008 Wcnchuan Ms8.0 earthquake, the seismogenic Kunlunshan fault zone became a geographic boundary between different regional movements. At the time of the earthquake, there was an average cross-fault crustal shortening of - 1.04 m and an average right-lateral strike slip of 0.76 m along the ruptured segment, as well as a strain-energy release of -62.66 ×10.7.

A Numerical Verification of Self-Similar Multiplicative Theory for Small-Scale Atmospheric Turbulent Convection

The self-similar multiplicative theory(SSM theory), aims to interpret the scaling behavior of the temperature structure function. In the present paper, the author report results from a numerical simulation of atmospheric turbulent convection in order to verify this theory. The simulation was based on a shell model which was deduced from simplified atmospheric convection equations. The numerical results agreed well with the theory prediction of scaling law from the first order to the eighth order. They also showed that the prediction of this theory was better than that given by the Kolmogorov's theory in 1941, log-normal, and β model theories.

Obstacle performance of cobalt-enriching crust wheeled mining vehicle

A cobalt-enriching crust mining vehicle with four independent driven wheels was proposed. The influence of center-of-gravity position of mining vehicle on obstacle performance was studied. The results show that the mining vehicle has optimal obstacle performance with center-of-gravity position in the middle of suspension. A virtual prototype based on ADAMS software was built and its obstacle performance was simulated. Simulation results show that the mining vehicle with four independent driven wheels has excellent obstacle performance, the maximum climbing capacity is no less than 30°, the maximal ditch width and shoulder height are no less than wheel radius of mining vehicle. Thus wheeled mining vehicle is feasible for cobalt-enriching crust commercial mining.

Effects of Shape and Quantity of Helical Baffle on the Shell-side Heat Transfer and Flow Performance of Heat Exchangers

Shape and quantity of helical baffles have great impact on the shell-side performance of helical baffled heat exchangers （HBHE）. In this work, three physical models of HBHE with baffles of different shape （trisection, quadrant and sextant sector） were investigated. Numerical simulations were performed on HBHE at three helix an- gles （10°, 25° and 40°） by the software ANSYS CFX. Analyses of numerical results indicate that the sextant HBHE shows relatively better fluid flow performance because the leakage flow in the triangle area is evidently reduced and the fluid streamline appears much closer to an ideal spiral flow, while the trisection and quadrant HBHE show more scattered and disordered streamline distributions. The convective heat transfer coefficient and pressure drop in three types of HBHE were presented. Further investigations on the shell side performance with different helical baf- fles were implemented by the field synergy theory. Both theoretical and numerical analyses gave support on the re- lations between helical baffle shape and shell-side performance. This paper may provide useful reference for the selection of baffle shade and auantitv in HBHE.

Modeling and optimal vibration control of conical shell with piezoelectric actuators

In this paper numerical simulations of active vibration control for conical shell structure with dis-tributed piezoelectric actuators is presented.The dynamic equations of conical shell structure are derivedusing the finite element model (FEM) based on Mindlin's plate theory.The results of modal calculationswith FEM model are accurate enough for engineering applications in comparison with experiment results.The Electromechanical influence of distributed piezoelectric actuators is treated as a boundary conditionfor estimating the control force.The independent modal space control (IMSC) method is adopted and theoptimal linear quadratic state feedback control is implemented so that the best control performance withthe least control cost can be achieved.Optimal control effects are compared with controlled responses withother non-optimal control parameters.Numerical simulation results are given to demonstrate the effective-ness of the control scheme.

Natural frequency characteristics of thin-walled homogeneous and manifold layered cylindrical shells under pressure using energy method

Energy method for the vibration of two types of cylindrical shells,namely thin-walled homogeneous isotropic and manifold layered isotropic cylindrical shells under uniform external lateral pressure is presented.The study is carried out based on strain-displacement relationship from Love's shell theory with beam functions as axial modal function.A manifold layered cylindrical shell configuration is formed by three layers of isotropic material where the inner and outer layers are stainless steel and the middle layer is aluminum.The homogeneous cylindrical shell is made-up of isotropic one layer with stainless steel.The governing equations with uniform external lateral pressure for homogeneous isotropic and manifold layered isotropic cylindrical shells are obtained using energy functional by the Lagrangian function with Rayleigh-Ritz method.The boundary conditions that are presented at the end conditions of the cylindrical shell are simply supported-simply supported,clamped-clamped and free-free.The influences of uniform external lateral pressure and symmetrical boundary conditions on the natural frequency characteristics for both homogeneous and manifold layered isotropic cylindrical shells are examined.For all boundary conditions considered,the natural frequency of both cylindrical shells with symmetric uniform lateral pressure increases as h/R ratio increases and those considering natural frequency of the both cylindrical shells with symmetric uniform lateral pressure decrease as L/R ratio increases.

Variations in retention efficiency of bivalves to different concentrations and organic content of suspended particles

Retention efficiencies (RE) of scallop (Chlamys farreri),oyster (Crassostrea gigas) and mussel (Mytilus edulis) in a flow-through system were measured to understand the short-term response to various particle and organic matter concentrations.By comparing the RE of C.farreri with that of C.gigas and M.edulis,we gained further knowledge on the feeding physiological characteristics of C.farreri and ascertained the possible cause of high summer mortalities of this species.The experimental feeding conditions included natural differences in the abundance and composition of suspended seston,as well as conditions in which seston abundance and composition were manipulated by adding natural silt or cultured microalgae.The results show that in natural sea water,the minimum particle size for maximal retention in M.edulis,C.gigas and C.farreri was approximately 4,6,and 8 μm,respectively;the RE of 2-μm (equivalent spherical diameter) particles was 17%,19%,and 8%,respectively;and the relative standardized RE was 58%,49%,and 18%,respectively.In C.gigas and M.edulis,the minimal particle size for maximal retention did not change with food quality (organic content).C.farreri was more sensitive to fluctuations in particle concentration and organic content.With particle concentration increase,the minimal particle size for maximal retention in scallop shifted to large particles and the RE for 2-μm particle decreased from 8% in natural seawater to 1.6%-6% in silt-enriched groups.With organic content increase,the minimal particle size for maximal retention shifted from 8 to 5 μm in natural seawater.Variation in RE of C.farreri with food conditions and the relationship between lower RE and smaller particle size may hamper C.farreri from food taking due to the decrease in the size distribution of phytoplankton in Sungo Bay.

Effect of fin attachment on thermal stress reduction of exhaust manifold of an off road diesel engine

The effect of fin attachment on the thermal stress reduction of exhaust manifold of an off road diesel engine(Komatsu HD325-6) was investigated.For doing this,coupled thermo-fluid-solid analysis of exhaust manifold of the off road diesel engine was carried out.The thermal analysis,including thermal flow,thermal stress,and the thermal deformation of the manifold was investigated.The flow inside the manifold was simulated and then its properties including velocity,pressure,and temperature were obtained.The flow properties were transferred to the solid model and then the thermal stresses and the thermal deformations of the manifold under different operating conditions were calculated.Finally,based on the predicted thermal stresses and thermal deformations of the manifold body shell,two fin types as well as body shell thickness increase were applied in the critical induced thermal stress area of the manifold to reduce the thermal stress and thermal deformation.The results of the above modifications show that the combined modifications,i.e.the thickness increase and the fin attachment,decrease the thermal stresses by up to 28% and the contribution of the fin attachment in this reduction is much higher compared to the shell thickness increase.

Design of Portable Shell and Tube Heat Exchanger for a Solar Powered Water Distiller

This study presents theoretical considerations and results of a portable shell and tube heat exchanger in a solar water distiller system. The device is composed of a glass heat exchanger, which served as a condenser for vapor condensing which were produced in black paint solar absorber. It was also composed of a tank for water source and a tank for produced distilled water. Shell and tube was designed and simulated using an implicit numerical scheme. Simulation results showed that accumulated mass water greatly depended on the inlet vapor temperature and volume, heat exchanger material, coolant water temperature and volume. Thus, changing the material from stainless steel to glass in the same condition （vapor temperature, vapor volume, coolant temperature and coolant volume）. These inexpensive shell and tube heat exchangers permitted to produce 40 litre/day, distilled water from vapor with 378 K inlet temperature in atmosphere pressure. If inlet pressure increases, vapor temperature will decline and thereupon, heat exchanger＇s efficiency tangibility will increase.

Design and energy absorption enhancement of vehicle hull under high dynamic loads

V-shape hulls are widely used in peacekeeping efforts such as demining vehicles in order to deflect the blast energy and reduce the effects of mine blast. Blast resistant design and energy absorption enhancement of V-shape plates were carried out using finite element analysis package ABAQUS. Various geometries of V-shape plates with and without interlayer of materials like Al-foams and honeycomb were employed to analyze their effects on the deformation of the plate and applied stresses and strains. The results obtained show that application of metallic foams leads to better response of the plate and consequently results in more energy dissipation, less dame to vehicle and enhances crew survivability.

Hydration process of rice husk ash cement paste and its corrosion resistance of embedded steel bar

Thermogravimetric analysis and electrical resistivity were used to determine the hydration process of cement paste with rice husk ash(RHA)(0−15%)and water-cement ratio of 0.4 in this work.X-ray diffraction(XRD)method and scanning electron microscopy(SEM)were used to survey crystal composition and microstructures of specimens cured for 3 h,1 d,7 d and 28 d.Finally,electrical parameters(electrical resistance and AC impedance spectroscopy)of steel bars reinforced cement paste were investigated to study the effect of RHA on the corrosion resistance.Results showed that RHA could affect the cement hydration by hydration promotion and pozzolanic effect.The evaluation function for electrical resistivity and curing ages fitted well with linear increasing function.The addition of RHA higher than 5%demonstrated a decreasing role in the electrical resistivity of cement paste at earlier curing ages(3−7 d).Meanwhile,when at later curing ages(7−28 d)the result was the opposite.Moreover,RHA demonstrated positive effects on corrosion resistance of steel bars in cement paste.

Influence of Velocity Shell Correlations on Anomalous Scaling Exponents of Passive Scalars in Shell Models

We propose a new approach to the old-standing problem of the anomaly of the scaling exponents of passive scalars of turbulence. Different to the original problem, the distribution function of the prescribed random velocity field is multi-dimensional normal and delta-correlated in time. Here, our random velocity field is spatially correlative. For comparison, we also give the result obtained by the Gaussian random velocity field without spatial correlation. The anomalous scaling exponents H（p） of passive scalar advected by two kinds of random velocity above are determined for structure function up to p= 15 by numerical simulations of the random shell model with Runge-Kutta methods to solve the stochastic differential equations. We observed that the H（p） ＇s obtained by the multi-dimeasional normal distribution random velocity are more anomalous than those obtained by the independent Gaussian random velocity.

Study on graft copolymerization of chitosan with AA （acrylic acid） and flocculating ability of the product

Graft copolymerization is one of the most attractive methods to modify natural polymers. In this study, graft copolymerization of acylic acid onto chitosan in aqueous media by ceric ammonium nitrate was investigated. The graft copolymerization reaction was carried out in a three necked flask maintained at 70＋/-0.05 ℃ under nitrogen atmosphere in a homogeneous aqueous phase （containing a small potion of acetic acid） by using ceric ammonium nitrate as an initiator. Evidence of grafting was obtained. The synthetic conditions were systematically optimized through studying the influential factors on grafting. The effectiveness of each individual factor was investigated by calculating and monitoring the variations of the grafting parameters [like monomer conversation Cm, grafting efficiency （Ge） and viscosity]. Under optimum conditions monomer conversion of 100.5% and graft efficiency of 94% were obtained, at temperature of 70℃. Flocculating ability of the copolymerization product of chitosan was studied by using Kaolin suspension as the flocculating object. And the application of the product was applied in Huayue dyeing plant. The results indicate that the higher the viscosity is, the better the flocculating ability of the copolymerization product of chitosan will be. The flocculating percentage reaches 96.0%, when the concentration of the product is only 1.0 mg/L and pH fixed at 7.0. Suitable separating mixtures for the grafted copolymer were chosen and the investigation of flocculation ability of the grafted copolymer was carried out with the aim of developing a good flocculant for wastewater treatment. A test of treating dyeing wastewater with the grafted copolymer was carried out and showed that grafting of Acrylic Acid with chitosan has a high COD removal rate 75% to the dyeing wastewater when the concentration is only 6.0 mg/L.

Study on Heat Dissipater for High-Power Thyristors in Explosion-Proof Shell

A new type water-cooled heat dissipater for multiple high-power thyristors in explosion-proof shell used in coal mine was designed, and then, the numerical computation of the three-dimensional steady-state temperature distributions under different working conditions for cooling core was conducted in order to understand in detail the heat transfer performance. Based on the computation results, the temperature differences and the maximum heat transfer rates were given. These results of the study on the heat dissipater lay a basis for optimising its structure design and guiding its operation.