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石墨烯基材料的能带调控技术研究进展 被引量:1
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作者 唐利斌 姬荣斌 项金钟 《红外技术》 CSCD 北大核心 2015年第11期897-905,共9页
石墨烯具有一系列特殊的物理和化学性质,因而近年来受到人们的极大关注。然而目前石墨烯在光电子领域的应用尚不广泛,其主要原因是由石墨烯的半金属性决定的,所以将石墨烯由半金属转变为半导体就成为人们关注的一个焦点问题。我们针对... 石墨烯具有一系列特殊的物理和化学性质,因而近年来受到人们的极大关注。然而目前石墨烯在光电子领域的应用尚不广泛,其主要原因是由石墨烯的半金属性决定的,所以将石墨烯由半金属转变为半导体就成为人们关注的一个焦点问题。我们针对石墨烯能带调制问题开展了系统的石墨烯基材料与器件的制备研究,开发了单层、双层石墨烯的CVD制备技术、氧化石墨烯的"Tang-Lau Method"制备技术、石墨烯量子点的微波辅助水热制备技术及软模板制备技术、氯/硫掺杂石墨烯量子点水热制备技术等。系统地研究了制备参数对石墨烯基材料的性质影响,探讨了尺寸效应、掺杂元素等因素对石墨烯基材料能级的影响,成功制备得到了一系列具有半导体性质的石墨烯基材料,并初步探讨了这些材料在光电器件中的应用。我们经过多年的研究,掌握了石墨烯基材料制备的核心技术,并成功建立了一套石墨烯能带调制技术。 展开更多
关键词 石墨烯 氧化石墨烯 石墨烯量子点 掺杂 能带调制
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二硫化钼/石墨烯异质结的界面结合作用及其对带边电位影响的理论研究 被引量:12
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作者 危阳 马新国 +2 位作者 祝林 贺华 黄楚云 《物理学报》 SCIE EI CAS CSCD 北大核心 2017年第8期267-276,共10页
采用基于色散修正的平面波超软赝势方法研究了二硫化钼/石墨烯异质结的界面结合作用及其对电荷分布和带边电位的影响.研究表明二硫化钼与石墨烯之间可以形成范德瓦耳斯力结合的稳定堆叠结构.通过能带结构计算,发现二硫化钼与石墨烯的耦... 采用基于色散修正的平面波超软赝势方法研究了二硫化钼/石墨烯异质结的界面结合作用及其对电荷分布和带边电位的影响.研究表明二硫化钼与石墨烯之间可以形成范德瓦耳斯力结合的稳定堆叠结构.通过能带结构计算,发现二硫化钼与石墨烯的耦合导致二硫化钼成为n型半导体,石墨烯转变成小带隙的p型体系.并通过电子密度差分图证实了界面内二硫化钼附近聚集负电荷,石墨烯附近聚集正电荷,界面内形成的内建电场可以抑制光生电子-空穴对的复合.石墨烯的引入可以调制二硫化钼的能带,使其导带底上移至-0.31 eV,提高了光生电子还原能力,有利于光催化还原反应. 展开更多
关键词 异质结光催化 二硫化钼 能带调制 第一性原理
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Al_(2)O_(3)与SnO_(2)对碲化镉太阳能电池前电极的界面钝化作用
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作者 郑根华 王东明 +3 位作者 吴玲玲 王光伟 蔡彦博 王德亮 《中国科学技术大学学报》 CAS CSCD 北大核心 2020年第4期450-456,共7页
采用磁控溅射法分别生长Al_(2)O_(3)和SnO_(2),将其作为MgxZn_(1-x)O(MZO)/CdTe薄膜太阳能电池前电极钝化层进行了相关研究.时间分辨光致发光(TRPL)光谱的测试结果显示,MZO/Al_(2)O_(3)/CdTe的少子寿命远大于MZO/CdTe的少子寿命,表明Al_... 采用磁控溅射法分别生长Al_(2)O_(3)和SnO_(2),将其作为MgxZn_(1-x)O(MZO)/CdTe薄膜太阳能电池前电极钝化层进行了相关研究.时间分辨光致发光(TRPL)光谱的测试结果显示,MZO/Al_(2)O_(3)/CdTe的少子寿命远大于MZO/CdTe的少子寿命,表明Al_(2)O_(3)对CdTe太阳能电池具有较好的钝化作用.实验发现,以Al_(2)O_(3)为钝化层的电池亮态电流密度-电压曲线出现了严重的“S-kink”现象.通过X射线光电子能谱(XPS)分析不同钝化层电池界面的能带匹配,发现Al_(2)O_(3)和CdTe界面较高的导带带阶是造成亮态电流密度-电压曲线出现“S-kink”的主要原因之一.SnO_(2)和CdTe界面处具有较小的导带带阶,通过控制SnO_(2)薄膜厚度,可以利用量子尺寸效应调整SnO_(2)和CdTe界面处的导带带阶,减弱电流密度-电压曲线的“S-kink”现象,提升电池填充因子和短路电流密度,使得电池转化效率提升至9.7%.研究结果表明,较大的导带带阶是导致“S-kink”产生的主要原因,适当降低导带带阶,能有效改善“S-kink”现象,进而有效地提升电池转化效率. 展开更多
关键词 碲化镉 薄膜太阳能电池 钝化 能带调制
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Electronic Energy Band and Transport Properties in Monolayer Graphene with Periodically Modulated Magnetic Vector Potential and Electrostatic Potential
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作者 刘正方 伍清萍 刘念华 《Communications in Theoretical Physics》 SCIE CAS CSCD 2012年第2期315-319,共5页
We investigated the electronic energy band and transport features of graphene superlattice with periodically modulated magnetic vector potential and electrostatic potential. It is found that both parallel magnetic vec... We investigated the electronic energy band and transport features of graphene superlattice with periodically modulated magnetic vector potential and electrostatic potential. It is found that both parallel magnetic vector potential and electrostatic potential can decisively shift Dirac point in a different way, which may be an efficient way to achieve electron or hole filter. We a/so find that applying modulated parallel and anti-parallel magnetic vector potential to the electrons can efficiently change electronic states between pass and stop states, which can be useful in designing electron or hole switches and lead to large magneto-resistance. 展开更多
关键词 GRAPHENE energy band and transport properties magnetic vector potential and electrostatic potential
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Modulation of land-sea thermal contrast on the energy source and sink of tropical cyclone activity and its annual cycle 被引量:1
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作者 YING Ming WU GuoXiong +1 位作者 LIU YiMin SUN ShuQing 《Science China Earth Sciences》 SCIE EI CAS 2012年第11期1855-1871,共17页
In general,the tropical cyclone(TC) activity is considered to be influenced by the heat content of underlying ocean,vertical shear of horizontal wind,vorticity in the low troposphere,moisture in the troposphere,and fa... In general,the tropical cyclone(TC) activity is considered to be influenced by the heat content of underlying ocean,vertical shear of horizontal wind,vorticity in the low troposphere,moisture in the troposphere,and favorable condition for deep convection development.However,these factors by nature merely present the internal factors of either atmosphere or ocean which influence the TC activity.In fact,the energy budget of the Earth system and its variation,modulated by the land-sea thermal contrast,are the intrinsic reasons responsible for the variation of TC activity.Here we investigate the modulation of diabatic heating distribution associated with the land-sea thermal contrast on the distribution of TC activity energy source and sink as well as the seasonality.An accumulated energy increment index(AEI) is defined using the TC best track data,and the energy sources and sinks of TC activity are then diagnosed effectively and practically according to the distribution of AEI.Results show that the thermal contrast of land and ocean is the primary reason for asymmetric distribution of TC activity about the Equator as well as the zonally asymmetric distribution of TC activity.The energy sources of TC activity are dominated by condensation heating of deep convection or double-dominant heating,which includes the condensation heating and cooling of longwave radiation(LO),while the sink areas are dominated by LO.The large scale diabatic heating associated with land-sea thermal contrast results in more favorable conditions for TC activity over the west part of oceans than those over the east parts.Moreover,the intensity of interaction of different diabatic heating over the west and east parts of ocean is also affected by the zonal scale of the oceans,which induces the difference of TC activity over the western North Pacific(WNP) and North Atlantic(ATL).The favorable westerlies and anticyclonic vertical shear associated with the tropical zonally asymmetric diabatic heating also contribute to the most intense TC activity over the WNP.The variation of large scale diabatic heating modulates the annual cycle of TC energy sources and sinks.In particular,the annual cycle over the WNP is the most typical one among the three basins(the WNP,the south Indian Ocean,and western South Pacific) that are characterized by the meridional shift of the energy sources and sinks.However,sources over the eastern North Pacific tend to extend westward and withdraw eastward associated with the variation of LO,while over the ATL,sources always merge from small pieces into a big one as the different diabatic heating over its west and east parts interacts with each other.Over the boreal Indian Ocean,the subcontinental scale land-sea heating contrast modifies the large scale circulation,and consequently contributes to the bimodal annual cycle of TC activity.In summary,TC activities are closely related to the interaction among various components of the climate system more than the atmosphere and ocean. 展开更多
关键词 land-sea thermal contrast tropical cyclone energy sources and sinks SEASONALITY
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