Laser processing effects on Ti−45Nb alloy surface,corrosive and biocompatible properties

The Ti−45Nb(wt.%)alloy properties were investigated in relation to its potential biomedical use.Laser surface modification was utilized to improve its performance in biological systems.As a result of the laser treatment,(Ti,Nb)O scale was formed and various morphological features appeared on the alloy surface.The electrochemical behavior of Ti−45Nb alloy in simulated body conditions was evaluated and showed that the alloy was highly resistant to corrosion deterioration regardless of additional laser surface modification treatment.Nevertheless,the improved corrosion resistance after laser treatment was evident(the corrosion current density of the alloy before laser irradiation was 2.84×10^(−8)A/cm^(2),while that after laser treatment with 5 mJ was 0.65×10^(−8)A/cm^(2))and ascribed to the rapid formation of a complex and passivating bi-modal surface oxide layer.Alloy cytotoxicity and effects of the Ti−45Nb alloy laser surface modification on the MRC-5 cell viability,morphology,and proliferation were also investigated.The Ti−45Nb alloy showed no cytotoxic effect.Moreover,cells showed improved viability and adherence to the alloy surface after the laser irradiation treatment.The highest average cell viability of 115.37%was attained for the alloy laser-irradiated with 15 mJ.Results showed that the laser surface modification can be successfully utilized to significantly improve alloy performance in a biological environment.

HA01系列供电计量监测仪及其防窃电效果

窃电是供电系统线损大的重要原因之一，采样ＨＡ０１ 系列供电计量监测仪组成的监测管理系统，能够较好地监测窃电行为，追回经济损失。仅天津、北京和大连供电局近一年追回电量１７０．２３ 万ｋＷ ·ｈ。

AFM and XPS Study on the Surface and Interface States of CuPc and SiO_2 Films

A CuPc/SiO2 sample is fabricated. Its morphology is characterized by atomic force microscopy, and the electron states are investigated by X-ray photoelectron spectroscopy. In order to investigate these spectra in detail, all of these spectra are normalized to the height of the most intense peak,and each component is fitted with a single Gaussian function. Analysis shows that the O element has great bearing on the electron states and that SiO2 layers produced by spurting technology are better than those produced by oxidation technology.

Preserving scheme for user’s confidential information in smart grid based on digital watermark and asymmetric encryption

As an essential part of the industrial Internet of Things(IoT)in power systems,the development of advanced metering infrastructure(AMI)facilitates services such as energy monitoring,load forecasting,and demand response.However,there is a growing risk of privacy disclosure with the wide installation of smart meters,for they transmit readings and sensitive data simultaneously.To guarantee the confidentiality of the sensitive information and authenticity of smart meter readings,we proposed a privacy-preserving scheme based on digital watermarking and elliptic-curve cryptography(ECC)asymmetric encryption.The sensitive data are encrypted using the public key and are hidden in the collected readings using digital watermark.Only the authorized user can extract watermark and can decrypt the confidential data using its private key.The proposed method realizes secure end-to-end confidentiality of the sensitive information.It has faster computing speed and can verify the data source and ensure the authenticity of readings.The example results show that the proposed method has little influence on the original data and unauthorized access cannot be completed within a reasonable time.On embedded hardware,the processing speed of the proposed method is better than the existing methods.

Genetic Algorithm-Based Redundancy Optimization Method for Smart Grid Communication Network

This paper proposes a redundancy optimization method for smart grid Advanced Metering Infrastructure(AMI) to realize economy and reliability targets.AMI is a crucial part of the smart grid to measure,collect,and analyze data about energy usage and power quality from customer premises.From the communication perspective,the AMI consists of smart meters,Home Area Network(HAN) gateways and data concentrators;in particular,the redundancy optimization problem focus on deciding which data concentrator needs redundancy.In order to solve the problem,we first develop a quantitative analysis model for the network economic loss caused by the data concentrator failures.Then,we establish a complete redundancy optimization model,which comprehensively consider the factors of reliability and economy.Finally,an advanced redundancy deployment method based on genetic algorithm(GA) is developed to solve the proposed problem.The simulation results testify that the proposed redundancy optimization method is capable to build a reliable and economic smart grid communication network.

An Overview of the Smart Grid in Great Britain

This paper presents an overview of the current status of the development of the smart grid in Great Britain(GB).The definition,policy and technical drivers,incentive mechanisms,technological focus,and the industry's progress in developing the smart grid are described.In particular,the Low Carbon Networks Fund and Electricity Network Innovation Competition projects,together with the rollout of smart metering,are detailed.A more observable,controllable,automated,and integrated electricity network will be supported by these investments in conjunction with smart meter installation.It is found that the focus has mainly been on distribution networks as well as on real-time flows of information and interaction between suppliers and consumers facilitated by improved information and communications technology,active power flow management,demand management,and energy storage.The learning from the GB smart grid initiatives will provide valuable guidelines for future smart grid development in GB and other countries.

Effect of surface treatment for aluminum foils on discharge properties of lithium-ion battery

Aluminum foils having thicknesses of 10-20 μm are commonly employed as current collectors for cathode electrodes in Li-ion batteries. The effects of the surface morphology of the foil on battery performance were investigated by using a foil with roughened surface by chemical etching and a plain foil with smooth surface on both sides. For high-conductivity LiCoO2 active materials with large particle size, there are no significant differences in battery performance between the two types of foils. But for low-conductivity LiFePO4 active materials with small particle size, high-rate discharge properties are significantly different. The possibility shows that optimizing both the surface morphology of the aluminum foil and particle size of active material leads to improvement of the battery performance.

Next Generation Narrowband(Under 500 kHz) Power Line Communications(PLC) Standards

In the past decade,several efforts around the world were started with the goal of introducing "smart metering" capabilities into the power grid.These efforts have spurred renewed interest in the design of next generation Narrowband Power Line Communications(NB-PLC) transceivers.In the past few years,ITU-T and IEEE have standardized a family of next generation OFDM-based NB-PLC transceivers some of which are today being considered for massive deployments in Europe and Asia.This paper addresses the important role that PLC has not only for smart metering but also for many other Smart Grid applications,and also gives an overview of the main differences between these next generation NB-PLC standards.

Effects of Sintering Atmosphere on the Microstructure and Surface Properties of Symmetric TiO2 Membranes

The effects of sintering atmosphere on the properties of symmetric TiO2 membranes are studied with regard to sintering behavior, porosity, mean pore size, surface comPosition. and surface charge properties. The exerimental results show that the symmetric TiO2 membranes display better sintering activity in the air than in argon, and the mean pore diameters and porosities of the membrane sintered in argon are higher than those of the membrane sintered in the air at the same temperature. The surface compositions of the symmetric TiO2 membrane sintered in the air and in argon at different temperatures, as studied by X-ray photoelectron spectroscopy, are discussed in terms of their chemical composition, with particular emphasis on the valence state of the titanium ions. The correlation between the valence state of the titanium ions at the surface and the surface charge properties is examined.It is found that the presence of Ti^3＋, introduced at the surface of the symmetric TiO2 membranes by sintering in a lower partial pressure of oxygen, is related to a significant decrease in the isoelectric point. TiO2 with Ti^4＋ at the interface has an isoelectric point of 5.1, but the non-stoichiometric TiO2-x with Ti^3＋ at the interface has a lower isoelectric point of 3.6.

Smart Grid Cyber Security： An Overview of Threats and Countermeasures

The smart grid is the next generation of power and distribution systems. The integration of advanced network, communications, and computing techniques allows for the enhancement of efficiency and reliability. The smart grid interconnects the flow of information via the power line, intelligent metering, renewable and distributed energy systems, and a monitoring and controlling infrastructure. For all the advantages that these components come with, they remain at risk to a spectrum of physical and digital attacks. This paper will focus on digital vulnerabilities within the smart grid and how they may be exploited to form full fledged attacks on the system. A number of countermeasures and solutions from the literature will also be reported, to give an overview of the options for dealing with such problems. This paper serves as a triggering point for future research into smart grid cyber security.

IEC 62059 Standards' Application in Reliability Prediction and Verification of Smart Meters

This article introduces the current situation of the smart then describes the relationship of meter reliability characteristics meter＇s reliability and the failure mechanisms at first, and combined with its Bathtub Curve. It also introduces both the feasible failure tree model for meter lifecycle prediction based on actual experiences and meter reliability prediction methodology by SN 29500 norms based on this model. This article also brings forward that it is necessary that the ＂Learning Factor＂ shall be adopted in meter reliability prediction for new materials, new process, and customized parts by referring to GJB/Z299C. Thereafter, this article also tries to apply IEC 62059 and JB/T 50070 to introduce the feasible method for the lifecycle prediction result verification by accelerated lifecycle test. Furthermore, the article also explores ways to increase the firmware reliability in smart meter.

Chemical composition and surface charge properties of montmorillonite

The effects of the cell parameter and chemical composition on the surface charge properties of five kinds of different colour montmorillonites were studied. The results indicate that the surface isoelectric point（IEP） of the montmorillonite shows positive correlation with the mass fractions of Fe203 and K20, but it has little relation to the mass fractions of other chemical compositions. At around pH=6.8, the surface zeta potential of the montmorillonite shows the negative relationship with the mass fractions of Fe203 and MgO, but it does not linearly correlate to the mass fractions of other chemical compositions. Cell parameter（bo） of the montmorillonite expresses negative linear relationship with mass fractions of K2O and Na2O, so does cosinβ with mass fractions of SlOE and Fe2O3. And there is no specific relationship between bo and IEP of different montmorillonites, but there is positive correlation between cosinβ and IEP of different montmorillonite samples.

Effects of surface chemical properties of activated coke on selective catalytic reduction of NO with NH_3 over commercial coal-based activated coke

Surface chemical properties of typical commercial coal-based activated cokes were characterized by Xray photoelectron spectroscopy(XPS) and acid-base titration, and then the influence of surface chemical properties on catalytic performance of activated cokes of NO reduction with NH3 was investigated in a fixed-bed quartz micro reactor at 150 ℃. The results indicate that the selective catalytic reduction(SCR) activity of activated cokes with the increase of its surface acidic sites and oxygen content,obviously, a correlation between catalytic activity and surface acidic sites content by titration has higher linearity than catalytic activity and surface oxygen content by XPS. While basic sites content by acid-base titration have not correlation with SCR activity. It has been proposed that surface basic sites content measured by titration may not be on adjacent of acidic surface oxides and then cannot form of NO2-like species, thus the reaction of reduction of NO with NH3 have been retarded.

Research on the Recognition Method of Electric Energy Meter Lead Title based on the Fuzzy Image Processing

This article puts forward an automatic recognition algorithm of electric energy meter lead seals： firstly, the image will be histogram equalization, smoothing, binaryzation pretreatment, then according to the image characteristics of text changes, the system can quickly and accurately segment image from complex background, finally the system extract different dimension and the feature of English and Arabia using digital projection transform coefficient method and to identify the corresponding number by BP neural network, solves the problem of automatic recognition of electric energy meter lead sealing.

In situ studies of energy-related electrochemical reactions using Raman and X-ray absorption spectroscopy

Electrochemical energy conversion technologies involving processes such as water splitting and O_(2)/CO_(2) reduction,provide promising solutions for addressing global energy scarcity and minimizing adverse environmental impact.However,due to a lack of an in-depth understanding of the reaction mechanisms and the nature of the active sites,further advancement of these techniques has been limited by the development of efficient and robust catalysts.Therefore,in situ characterization of these electrocatalytic processes under working conditions is essential.In this review,recent applications of in situ Raman spectroscopy and X-ray absorption spectroscopy for various nano-and single-atom catalysts in energy-related reactions are summarized.Notable cases are highlighted,including the capture of oxygen-containing intermediate species formed during the reduction of oxygen and oxidation of hydrogen,and the detection of catalyst structural transformations occurring with the change in potential during the evolution of oxygen and reduction of CO_(2).Finally,the challenges and outlook for advancing in situ spectroscopic technologies to gain a deeper fundamental understanding of these energy-related electrocatalytic processes are discussed.

Event-Oriented Dynamic Security Service for Demand Response in Smart Grid Employing Mobile Networks

Equipped with millions of sensors and smart meters in smart gird,a reliable and resilient wireless communication technology is badly needed.Mobile networks are among the major energy communication networks which contribute to global energy consumption increase rapidly.As one of core technologies of smart grid employing mobile networks,Demand Response(DR) helps improving efficiency,reliability and security for electric power grid infrastructure.Security of DR events is one of the most important issues in DR.However,the security requirements of different DR events are dynamic for variousactual demands.To address this,an event-oriented dynamic security service mechanism is proposed for DR.Three kinds of security services including security access service,security communication service and security analysis service for DR event are composited dynamically by the fine-grained sub services.An experiment prototype of the network of State Grid Corporation of China(SGCC) is established.Experiment and evaluations shows the feasibility and effectiveness of the proposed scheme in smart grid employing mobile network.

Highly Active and Stable Ni_2P/SiO_2 Catalyst for Hydrogenation of C_9 Petroleum Resin

Catalytic hydrogenation is an appropriate method for the improvement of C9 petroleum resin（C9PR） quality. In this study, the Ni2P/SiO2（containing 10% of Ni） catalyst prepared by the temperature-programmed reduction（TPR） method was used for hydrogenation of C9 petroleum resins. The effect of reaction conditions on catalytic performance was studied, and the results showed that the optimum reaction temperature, pressure and liquid hourly space velocity（LHSV） was 250 ℃, 6.0 MPa, and 1.0 h-1, respectively. The bromine numbers of hydrogenated products were maintained at low values（250 mg Br/100g） within 300h, showing the high activity and stability of Ni2P/SiO2 catalyst. The fresh and spent catalysts were characterized by X-ray diffraction（XRD）, BET surface area（BET） analysis, scanning electron microscopy（SEM）, transmission electron microscopy（TEM）, Fourier transform infrared（FTIR） pyridine adsorption, and X-ray photoelectron spectroscopy（XPS）. Compared with the traditional sulfurated-Ni W catalysts, Ni2P possessed globe-like structure instead of layered structure like the active phase of Ni WS, thereof exposing more active sites, which were responsible for the high activity of Ni2P/SiO2 catalyst. The stability of Ni2P/SiO2 catalyst was probably attributed to its high sulfur tolerance, antisintering, anti-coking and carbon-resistance ability. These properties might be further ascribed to the special Ni-P-S surface phase, high thermal stability of Ni2P nanoparticles and weak surface acidity for the Ni2P/SiO2 catalyst.

Restructuring of well-defined Pt-based electrode surfaces under mild electrochemical conditions

Since the 1980s,single-crystal Pt electrodes with well-defined surface structures have been deemed stable under mild electrochemical conditions(e.g.,in the potential region of electric double layers,underpotential deposition of hydrogen,or mild hydrogen evolution/OH adsorption)and have served as model electrodes for unraveling the structure-performance relation in electrocatalysis.With the advancement of in situ electrochemical microscopy/spectroscopy techniques,subtle surface restructuring under mild electrochemical conditions has been achieved in the last decade.Surface restructuring can considerably modify electrocatalytic properties by generating/destroying highly active sites,thereby interfering with the deduction of the structure-performance relation.In this review,we summarize recent progress in the restructuring of well-defined Pt(-based)electrode surfaces under mild electrochemical conditions.The importance of the meticulous structural characterization of Pt electrodes before,during,and after electrochemical measurements is demonstrated using CO adsorption/oxidation,hydrogen adsorption/evolution,and oxygen reduction as examples.The implications of present findings for correctly identifying the reaction mechanisms and kinetics of other electrocatalytic systems are also briefly discussed.

The Design of Intelligent Watt-hour Meter based STM32 System

In view of limitalions function, cost and application in domestic meter at present, this paper was designed the low power consumption, low cost smart meters and PC system based on microprocessor MSP430F4794. It supports multi rate, step rate and power factor influence factor of electricity metering method, and can realize the real-time clock, timing backup data, monitoring the temperature and humidity of the environment and other functions, has the ability to forecast the next period of time energy consumption and carbon dioxide emissions of electrical appliances. Combined with the PC software, the backup data of smart meters to report, detailed list, and the data curve method is presented to the user, and facilitate to analysis of user. The whole embedded in smart meters and the host computer system provides a good human-computer interface, can realize the user personalized service configuration and software calibration function.

Calculation of Surface Excitation Parameters by a Monte Carlo Method

Electron inelastic mean free path （IMFP） is an important parameter for surface chemical quantification by surface electron spectroscopy techniques. It can be obtained from analysis of elastic peak electron spectroscopy （EPES） spectra measured on samples and a Monte Carlo simulation method. To obtain IMFP parameters with high accuracy, the surface excitation effect on the measured EPES spectra has to be quantified as a surface excitation parameter （SEP）, which can be calculated via a dielectric response theory. However, such calculated SEP does not include influence of elastic scattering of electrons inside samples during their incidence and emission processes, which should not be neglected simply in determining IMFP by an EPES method. In this work a Monte Carlo simulation method is employed to determine surface excitation parameter by taking account of the elastic scattering effect. The simulated SEPs for different primary energies are found to be in good agreement with the experiments particularly for larger incident or emission angles above 60° where the elastic scattering effect plays a more important role than those in smaller incident or emission angles. Based on these new SEPs, the IMFP measurement by EPES technique can provide more accurate data.