Based on experimental data,machine learning(ML) models for Young's modulus,hardness,and hot-working ability of Ti-based alloys were constructed.In the models,the interdiffusion and mechanical property data were hi...Based on experimental data,machine learning(ML) models for Young's modulus,hardness,and hot-working ability of Ti-based alloys were constructed.In the models,the interdiffusion and mechanical property data were high-throughput re-evaluated from composition variations and nanoindentation data of diffusion couples.Then,the Ti-(22±0.5)at.%Nb-(30±0.5)at.%Zr-(4±0.5)at.%Cr(TNZC) alloy with a single body-centered cubic(BCC) phase was screened in an interactive loop.The experimental results exhibited a relatively low Young's modulus of(58±4) GPa,high nanohardness of(3.4±0.2) GPa,high microhardness of HV(520±5),high compressive yield strength of(1220±18) MPa,large plastic strain greater than 30%,and superior dry-and wet-wear resistance.This work demonstrates that ML combined with high-throughput analytic approaches can offer a powerful tool to accelerate the design of multicomponent Ti alloys with desired properties.Moreover,it is indicated that TNZC alloy is an attractive candidate for biomedical applications.展开更多
The effects of interrupted aging on mechanical properties and corrosion resistance of 7A75 aluminum alloy extruded bar were investigated through various analyses,including electrical conductivity,mechanical properties...The effects of interrupted aging on mechanical properties and corrosion resistance of 7A75 aluminum alloy extruded bar were investigated through various analyses,including electrical conductivity,mechanical properties,local corrosion properties,and slow strain rate tensile stress corrosion tests.Microstructure characterization techniques such as metallographic microscopy,scanning electron microscopy(SEM),and transmission electron microscopy(TEM)were also employed.The results indicate that the tensile strength of the alloy produced by T6I6 aging is similar to that produced by T6I4 aging,and it even exceeds 700 MPa.Furthermore,the yield strength increases by 52.7 MPa,reaching 654.8 MPa after T6I6 aging treatment.The maximum depths of intergranular corrosion(IGC)and exfoliation corrosion(EXCO)decrease from 116.3 and 468.5μm to 89.5 and 324.3μm,respectively.The stress corrosion factor also decreases from 2.1%to 1.6%.These findings suggest that the alloy treated with T6I6 aging exhibits both high strength and excellent stress corrosion cracking resistance.Similarly,when the alloy is treated with T6I4,T6I6 and T6I7 aging,the sizes of grain boundary precipitates(GBPs)are found to be 5.2,18.4,and 32.8 nm,respectively.The sizes of matrix precipitates are 4.8,5.7 and 15.7 nm,respectively.The atomic fractions of Zn in GBPs are 9.92 at.%,8.23 at.%and 6.87 at.%,respectively,while the atomic fractions of Mg are 12.66 at.%,8.43 at.%and 7.00 at.%,respectively.Additionally,the atomic fractions of Cu are 1.83 at.%,2.47 at.%and 3.41 at.%,respectively.展开更多
To investigate the feasibility and seismic performance of the horizontal joints in an innovative precast shear wall system, two test walls were fabricated, and the monotonic and cyclic loading tests were performed on ...To investigate the feasibility and seismic performance of the horizontal joints in an innovative precast shear wall system, two test walls were fabricated, and the monotonic and cyclic loading tests were performed on the two test walls, respectively. Then, the lateral load-top displacement curves, load beating capacity, ductility, lateral stiffness, strains of steel bars, strain distribution on the connecting steel frame (CSF), and relative slippages between the CSF and embedded limbic steel frame (ELSF) were discussed in detail. The test results show that the load bearing capacity and ductility of the test wall are both favorable with a displacement ductility factor of more than 3.7. The normal and shear stresses in the CSF except for the compression end are far smaller than the yield stresses throughout the test procedure. Certain slippages of about 1.13 mm occurs between the CSF and ELSF on the compression side of the test wall, while almost no slippages occurs on the tension side. The seismic performance of the test wall is favorable and the new-type scheme of the horizontal joints is both feasible and reliable.展开更多
Butt welding of 0.2 mm-thick TiNi shape memory alloy sheet (SMA) was carried out using impulse laser, and tensile strength, fracture morphology, microstructure and phase change behaviour of welded joint were studied...Butt welding of 0.2 mm-thick TiNi shape memory alloy sheet (SMA) was carried out using impulse laser, and tensile strength, fracture morphology, microstructure and phase change behaviour of welded joint were studied. The results show that using impulse laser can realize good butt welding of TiNi SMA sheet, tensile strength of welded joint is 683 MPa, which achieves 97% of that of cold rolled base metal, and the fracture mode of welded joint is ductile type as well as base metal. The welded joint can be divided into four zones according to grain size and microstructure. The microstructures of welded seam center zone are fine equiaxed crystals and the microstructures of both lower surface and upper surface edge zones are columnar crystals. When welded joint is vacuum annealed after welding, the phase transformation process is basically similar to the annealed base metal.展开更多
A series of electrochemical and long-term corrosion tests were carried out in a neutral saline (5%NaCl) vapor of 35 °C on thermal sprayed WC cermet coatings containing different kinds of metallic binders in ord...A series of electrochemical and long-term corrosion tests were carried out in a neutral saline (5%NaCl) vapor of 35 °C on thermal sprayed WC cermet coatings containing different kinds of metallic binders in order to examine the effect of composition of binder materials on the corrosion behavior. The experimental results revealed that the overall corrosion resistance of WC-Co coating was inferior to that of WC-Co-Cr coating. For the coatings without Cr, WC-Co, general corrosion occurred in binder materials in addition to galvanic corrosion between WC particles and metallic binders in the neutral environment. By contrast, the formation of passive film in the form of surface oxide in the coatings containing Cr, WC-Co-Cr, suppressed the binder and metallic binders to be eroded. It is found that the chemical composition of metallic binder materials is one of the important factors influencing the corrosion resistance of HVOF sprayed WC cermet coatings in the neutral vapor.展开更多
The effect of heat treatment on microstructure and mechanical properties of the Ti-steel explosive-rolling clad plate was elaborated by optical microscopy (OM), scanning electron microscopy (SEM), X-ray diffracti...The effect of heat treatment on microstructure and mechanical properties of the Ti-steel explosive-rolling clad plate was elaborated by optical microscopy (OM), scanning electron microscopy (SEM), X-ray diffraction (XRD), transmission electron microscopy (TEM), micro-hardness test and shear test. The composites were subjected to heat treatment at temperature of 650-950 ~C for 60 min. The results show that the heat treatment process results in a great enhancement of diffusion and microstructural transformation. The shear strength decreases as the treatment temperature increases. Heated at 850 ℃ or below, their shear strength decreases slowly as a result of the formation of TiC in the diffusion interaction layer; while at the temperature of 850 ℃ or above, the shear strength decreases obviously, which is the consequence of a large amount of Ti-Fe intermetaUics (Fe2Ti/FeTi) along with some TiC distributing continuously at diffusion reaction layer.展开更多
In order to evaluate the electrochemical properties of aluminum alloy anode under high current densities in alkaline electrolyte, the galvanostatic discharge, potentiodynamic polarization and hydrogen evolution tests ...In order to evaluate the electrochemical properties of aluminum alloy anode under high current densities in alkaline electrolyte, the galvanostatic discharge, potentiodynamic polarization and hydrogen evolution tests of three experimental Al?Mg?Sn?In?(Ga) alloys were performed. The results show that the alloying element gallium improves the working potentials of experimental Al?Mg?Sn?In alloys under different discharge current densities. The average working potentials of the alloys containing gallium can reach?1.3 V under current density ranging from 650 to 900 mA/cm2, while those of alloy without Ga are only?1.0 V. Such phenomenon is attributed to the solid solution which can form amalgam with aluminum matrix. Such an amalgam can form the hydrolyzed species during the discharge process and lead to the corrosion infiltrating into aluminum matrix.展开更多
The effects of plastic deformation on precipitation behavior and tensile fracture behavior of Mg-10Gd-3Y-0.6Zr alloy were investigated.The results indicate that more precipitation cores can be provided by the crystal ...The effects of plastic deformation on precipitation behavior and tensile fracture behavior of Mg-10Gd-3Y-0.6Zr alloy were investigated.The results indicate that more precipitation cores can be provided by the crystal defects caused by the plastic deformation,as well as increasing the amount of β' phases,and the formation of precipitations at grain boundaries and interfaces between the twins and matrix.Because of an increase in precipitations,the dislocation slipping during deformation process is effectively hindered and the matrix is strengthened,especially for the 2% deformed alloy which can achieve a good combination of strength and ductility.With increasing the plastic deformation,the microcracks occur at the interface between grain boundary precipitations and matrix,and then propagate intergranularly.When intergranular fracture combines with the formation of smoothing facets on the fracture surface,the tensile properties decrease.展开更多
The influence of Li addition on mechanical property and aging precipitation behavior of Al-3.5Cu-1.5Mg alloy was investigated by tensile test,scanning electron microscopy(SEM),transmission electron microscopy(TEM)...The influence of Li addition on mechanical property and aging precipitation behavior of Al-3.5Cu-1.5Mg alloy was investigated by tensile test,scanning electron microscopy(SEM),transmission electron microscopy(TEM) and high resolution transmission electron microscopy(HRTEM).The results show that the tensile strength can be significantly improved with the slightly decreased ductility and the form of fracture morphology is converted from ductile fracture into ductile/britde mixed fracture by adding 1.0%Li.Besides,the peak aging time at 185 ℃ is delayed from 12 to 24 h and the main precipitation phase S(Al2CuMg) is converted into S'(Al2CuMg)+δ(Al3Li),while the formation of S'(Al2CuMg) is delayed.展开更多
Porous titanium has been shown to exhibit desirable properties as biomedical materials. In view of the load-bearing situation, the mechanical properties and pore structure deformation behaviour of porous titanium were...Porous titanium has been shown to exhibit desirable properties as biomedical materials. In view of the load-bearing situation, the mechanical properties and pore structure deformation behaviour of porous titanium were studied. Porous titanium with porosities varying from 36%-66% and average pore size of 230 μm was fabricated by powder sintering. Microstructural features were characterized using scanning electron microscopy. Uniaxial compression tests were used to probe the mechanical response in terms of elastic modulus and compressive strength. The mechanical properties of porous titanium were found to be close to the those of human bone, with stiffness values ranging from 1.86 to 14.7 GPa and compressive strength values of 85.16-461.94 MPa. The relationships between mechanical properties and relative densities were established, and the increase in relative density showed significant effects on mechanical properties and deformations of porous titanium. In a lower relative density, the microscopic deformation mechanism of porous titanium was yielding, bending and buckling of cell walls, while the deformation of yielding and bending of cell walls was observed in the porous titanium with higher relative density.展开更多
Surface mechanical attrition treatment (SMAT) was performed on biomedicalβ-type TiNbZrFe alloy for 60 min at room temperature to study the effect of surface nanocrystallization on the corrosion resistance of TiNbZrFe...Surface mechanical attrition treatment (SMAT) was performed on biomedicalβ-type TiNbZrFe alloy for 60 min at room temperature to study the effect of surface nanocrystallization on the corrosion resistance of TiNbZrFe alloy in physiological environment. The surface nanostructure was characterized by TEM, and the electrochemical behaviors of the samples with nanocrystalline layer and coarse grain were comparatively investigated in 0.9% NaCl and 0.2% NaF solutions, respectively. The results indicate that nanocrystallines with the size of 10-30 nm are formed within the surface layer of 30 μm in depth. The nanocrystallized surface behaves higher impedance, more positive corrosion potential and lower corrosion current density in 0.9%NaCl and 0.2%NaF solutions as compared with the coarse grain surface. The improvement of the corrosion resistance is attributed to the rapid formation of stable and dense passive film on the nanocrystallized surface of TiNbZrFe alloy.展开更多
Mg-2.7Nd-0.2Zn-0.4Zr (mass fraction, %) alloy was designed for degradable biomedical material. The ingots of the alloy were solution treated and then hot extruded. The extruded rods were heat treated with aging trea...Mg-2.7Nd-0.2Zn-0.4Zr (mass fraction, %) alloy was designed for degradable biomedical material. The ingots of the alloy were solution treated and then hot extruded. The extruded rods were heat treated with aging treatment, solution treatment and solution+aging treatment, respectively. Microstructures of the alloy were observed by optical microscopy (OM) and scanning electron microscopy (SEM). Mechanical properties at room temperature were tested. In vitro degradation behavior of the alloy immersed in simulated body fluid was measured by hydrogen evolution and mass loss tests. The degradation morphologies of the alloy with and without degradation products were observed by SEM. The results show that the grains grow apparently after solution treatment. Solution treatment improves the elongation of as-extruded alloy significantly and decreases the strength, while aging treatment improves the strength and reduces the elongation of the alloy. The yield ratio is reduced by heat treatment. The in vitro degradation results of the alloy show that solution treatment on the as-extruded alloy results in a little higher degradation rate and aging treatment on the alloy can reduce degradation rate slightly.展开更多
The functional bamboos are defined as the ones artificially selected, cultivated and produced in the special functions. Based on the principles to broaden market and maximize benefits, the directional cultivation of t...The functional bamboos are defined as the ones artificially selected, cultivated and produced in the special functions. Based on the principles to broaden market and maximize benefits, the directional cultivation of the functional bamboos has effectively been used bio-techniques and directionally to breed and cultivate bamboo cultivars to meet human's needs. The functional bamboos should feature stability, excellent quality and convenient production as well as easy duplication. The functional bamboo cultivars should also enhance the scientization, standardization industrialization and mass production. Given no negative environmental impact, ou purpose is to select, cultivate and develop one or more functional bamboos cultivars to meet the consumers' material and spiritual needs and bring more economic ben efits for the producers. The authors believe that directionally breeding functiona bamboo cultivars is not only feasible in techniques, resources and policies, but also in economy and market development. This implicates great significance for the green economic development given the features of China's natural resources.展开更多
In the performance based navigation(PBN),the flight technical error(FTE)and the navigation system error(NSE)are two main parts of total system error(TSE).The implementation of PBN requires pre-flight predictio...In the performance based navigation(PBN),the flight technical error(FTE)and the navigation system error(NSE)are two main parts of total system error(TSE).The implementation of PBN requires pre-flight prediction and en-route short-term dynamical prediction of TSE.Once the sum of predicted FTE and NSE is greater than the specified PBN value,PBN cannot operate.Thus,it requires accurate modeling and thorough analysis of the two main contributors.Multiple-input multiple-output(MIMO)longitudinal flight control system of ARIC model is designed using the linear quadratic Gaussian and loop transfer recovery(LQG/LTR)method,and FTE in symmetrical plane of aircraft is analyzed during the turbulence disturbed approach.The error estimation mapping function of FTE in symmetrical plane and its bound estimation model are proposed based on the singular value theory.The model provides an approach based on the forming mechanism of FTE,rather than the costly flight test and the data fitting.Real-data based simulation validates the theoretical analysis of FTE in symmetrical plane.It also shows that FTE is partially caused by the turbulence fluctuation disturbance when the automatic flight control system(AFCS)is engaged and increases with escalating the environmental turbulence intensity.展开更多
Using an optical microscope and scanning electron microscope (SEM), the variation of eutectic Si morphology of Al-Si alloy in solution treatment was observed to study its influence on mechanical properties and fractur...Using an optical microscope and scanning electron microscope (SEM), the variation of eutectic Si morphology of Al-Si alloy in solution treatment was observed to study its influence on mechanical properties and fracture behavior. The results show that eutectic Si undergoes stubbing, necking, fragmentation, and growth in the initial stage (250 min); in the middle solution stage (250 to 400 min), the eutectic Si morphology has no significant change, only the degree of spheroidizing becomes higher; after 600 min, the growth of eutectic Si is a coarsening process controlled by diffusion and follows the Liftshitz-Slyozov-Wangner (LSW) model, and the eutectic Si morphology deteriorates due to the occurrence of facets and lap. Based on the quantitative measure and regression analysis, the eutectic Si morphology has a remarkable influence on mechanical properties and fracture behavior.展开更多
In order to investigate the alternate operation characteristics of a solar-ground source heat pump system(SGSHPS),various alternate operation modes are put forward and defined.A two-dimensional mathematical model wi...In order to investigate the alternate operation characteristics of a solar-ground source heat pump system(SGSHPS),various alternate operation modes are put forward and defined.A two-dimensional mathematical model with freezing/melting phase changes is developed for the heat transfer analysis of the soil.Based on the numerical solution of the model,the variation trends of underground soil temperature of the SGSHPS operated in various alternate operation modes are discussed.The results indicate that,for the day-night and short-time interval alternate operation modes without solar energy,the operation time fraction of a solar heat source should be confined to from 50% to 58% when operated in an alternate period of 24 h.Meanwhile,the disadvantages of a natural resumption of soil temperature can be overcome effectively by solar energy filling,and an optimal operation effect can be achieved by integrating the mode of solar energy filling with other alternate modes.In addition,the accuracy of the presented model is verified by the experimental data of borehole wall temperatures.The conclusions can provide a reference for the optimization operation of the SGSHPS.展开更多
In order to reflect the influence of the drivers' characteristic differences on intersection capacity under a mixed traffic flow, a driver correction coefficient for the intersection capacity calculation according to...In order to reflect the influence of the drivers' characteristic differences on intersection capacity under a mixed traffic flow, a driver correction coefficient for the intersection capacity calculation according to the driver's visual characteristics is proposed. First, the parameters of the driver's visual characteristics at some real roads, including gaze fixation distribution, mean fixation duration, visual angle distribution and some other parameters at intersections, are collected. Then, the relationship between the traffic flow rate at intersections and the parameters of driver eye movements are established. The analytical results indicate that when the traffic flow is unsaturated, the parameters of driver eye movements change relatively little; however, when the traffic flow is saturated, the parameters of driver eye movements change drastically. Finally, the saturation-flow-rate model is modified according to the parameters of driver eye movements; thus, a capacity model of intersections considering the driver's visual characteristics is obtained.展开更多
基金the financial supports from the National Key Research and Development Program of China (No. 2022YFB3707501)the National Natural Science Foundation of China (No. 51701083)+1 种基金the GDAS Project of Science and Technology Development, China (No. 2022GDASZH2022010107)the Guangzhou Basic and Applied Basic Research Foundation, China (No. 202201010686)。
文摘Based on experimental data,machine learning(ML) models for Young's modulus,hardness,and hot-working ability of Ti-based alloys were constructed.In the models,the interdiffusion and mechanical property data were high-throughput re-evaluated from composition variations and nanoindentation data of diffusion couples.Then,the Ti-(22±0.5)at.%Nb-(30±0.5)at.%Zr-(4±0.5)at.%Cr(TNZC) alloy with a single body-centered cubic(BCC) phase was screened in an interactive loop.The experimental results exhibited a relatively low Young's modulus of(58±4) GPa,high nanohardness of(3.4±0.2) GPa,high microhardness of HV(520±5),high compressive yield strength of(1220±18) MPa,large plastic strain greater than 30%,and superior dry-and wet-wear resistance.This work demonstrates that ML combined with high-throughput analytic approaches can offer a powerful tool to accelerate the design of multicomponent Ti alloys with desired properties.Moreover,it is indicated that TNZC alloy is an attractive candidate for biomedical applications.
基金the Tianjin Key Laboratory of Fastening and Connection Technology Enterprises 2022—2023,China(No.TKLF2022-02-C-02)the technical support from the School of Materials Science and Engineering,Central South University,China.
文摘The effects of interrupted aging on mechanical properties and corrosion resistance of 7A75 aluminum alloy extruded bar were investigated through various analyses,including electrical conductivity,mechanical properties,local corrosion properties,and slow strain rate tensile stress corrosion tests.Microstructure characterization techniques such as metallographic microscopy,scanning electron microscopy(SEM),and transmission electron microscopy(TEM)were also employed.The results indicate that the tensile strength of the alloy produced by T6I6 aging is similar to that produced by T6I4 aging,and it even exceeds 700 MPa.Furthermore,the yield strength increases by 52.7 MPa,reaching 654.8 MPa after T6I6 aging treatment.The maximum depths of intergranular corrosion(IGC)and exfoliation corrosion(EXCO)decrease from 116.3 and 468.5μm to 89.5 and 324.3μm,respectively.The stress corrosion factor also decreases from 2.1%to 1.6%.These findings suggest that the alloy treated with T6I6 aging exhibits both high strength and excellent stress corrosion cracking resistance.Similarly,when the alloy is treated with T6I4,T6I6 and T6I7 aging,the sizes of grain boundary precipitates(GBPs)are found to be 5.2,18.4,and 32.8 nm,respectively.The sizes of matrix precipitates are 4.8,5.7 and 15.7 nm,respectively.The atomic fractions of Zn in GBPs are 9.92 at.%,8.23 at.%and 6.87 at.%,respectively,while the atomic fractions of Mg are 12.66 at.%,8.43 at.%and 7.00 at.%,respectively.Additionally,the atomic fractions of Cu are 1.83 at.%,2.47 at.%and 3.41 at.%,respectively.
文摘To investigate the feasibility and seismic performance of the horizontal joints in an innovative precast shear wall system, two test walls were fabricated, and the monotonic and cyclic loading tests were performed on the two test walls, respectively. Then, the lateral load-top displacement curves, load beating capacity, ductility, lateral stiffness, strains of steel bars, strain distribution on the connecting steel frame (CSF), and relative slippages between the CSF and embedded limbic steel frame (ELSF) were discussed in detail. The test results show that the load bearing capacity and ductility of the test wall are both favorable with a displacement ductility factor of more than 3.7. The normal and shear stresses in the CSF except for the compression end are far smaller than the yield stresses throughout the test procedure. Certain slippages of about 1.13 mm occurs between the CSF and ELSF on the compression side of the test wall, while almost no slippages occurs on the tension side. The seismic performance of the test wall is favorable and the new-type scheme of the horizontal joints is both feasible and reliable.
基金Project(200804)supported by State Key Laboratory of Advanced Welding and Joining,Harbin Institute of Technology,China
文摘Butt welding of 0.2 mm-thick TiNi shape memory alloy sheet (SMA) was carried out using impulse laser, and tensile strength, fracture morphology, microstructure and phase change behaviour of welded joint were studied. The results show that using impulse laser can realize good butt welding of TiNi SMA sheet, tensile strength of welded joint is 683 MPa, which achieves 97% of that of cold rolled base metal, and the fracture mode of welded joint is ductile type as well as base metal. The welded joint can be divided into four zones according to grain size and microstructure. The microstructures of welded seam center zone are fine equiaxed crystals and the microstructures of both lower surface and upper surface edge zones are columnar crystals. When welded joint is vacuum annealed after welding, the phase transformation process is basically similar to the annealed base metal.
文摘A series of electrochemical and long-term corrosion tests were carried out in a neutral saline (5%NaCl) vapor of 35 °C on thermal sprayed WC cermet coatings containing different kinds of metallic binders in order to examine the effect of composition of binder materials on the corrosion behavior. The experimental results revealed that the overall corrosion resistance of WC-Co coating was inferior to that of WC-Co-Cr coating. For the coatings without Cr, WC-Co, general corrosion occurred in binder materials in addition to galvanic corrosion between WC particles and metallic binders in the neutral environment. By contrast, the formation of passive film in the form of surface oxide in the coatings containing Cr, WC-Co-Cr, suppressed the binder and metallic binders to be eroded. It is found that the chemical composition of metallic binder materials is one of the important factors influencing the corrosion resistance of HVOF sprayed WC cermet coatings in the neutral vapor.
文摘The effect of heat treatment on microstructure and mechanical properties of the Ti-steel explosive-rolling clad plate was elaborated by optical microscopy (OM), scanning electron microscopy (SEM), X-ray diffraction (XRD), transmission electron microscopy (TEM), micro-hardness test and shear test. The composites were subjected to heat treatment at temperature of 650-950 ~C for 60 min. The results show that the heat treatment process results in a great enhancement of diffusion and microstructural transformation. The shear strength decreases as the treatment temperature increases. Heated at 850 ℃ or below, their shear strength decreases slowly as a result of the formation of TiC in the diffusion interaction layer; while at the temperature of 850 ℃ or above, the shear strength decreases obviously, which is the consequence of a large amount of Ti-Fe intermetaUics (Fe2Ti/FeTi) along with some TiC distributing continuously at diffusion reaction layer.
基金Project supported by the Open Fund of the State Key Laboratory of Powder Metallurgy,China
文摘In order to evaluate the electrochemical properties of aluminum alloy anode under high current densities in alkaline electrolyte, the galvanostatic discharge, potentiodynamic polarization and hydrogen evolution tests of three experimental Al?Mg?Sn?In?(Ga) alloys were performed. The results show that the alloying element gallium improves the working potentials of experimental Al?Mg?Sn?In alloys under different discharge current densities. The average working potentials of the alloys containing gallium can reach?1.3 V under current density ranging from 650 to 900 mA/cm2, while those of alloy without Ga are only?1.0 V. Such phenomenon is attributed to the solid solution which can form amalgam with aluminum matrix. Such an amalgam can form the hydrolyzed species during the discharge process and lead to the corrosion infiltrating into aluminum matrix.
基金Project(IRT0713) supported by the Program for Changjiang Scholars and Innovative Research Team in Chinese UniversityProjects(2007CB613701,2007CB613702) supported by the National Basic Research Program of China
文摘The effects of plastic deformation on precipitation behavior and tensile fracture behavior of Mg-10Gd-3Y-0.6Zr alloy were investigated.The results indicate that more precipitation cores can be provided by the crystal defects caused by the plastic deformation,as well as increasing the amount of β' phases,and the formation of precipitations at grain boundaries and interfaces between the twins and matrix.Because of an increase in precipitations,the dislocation slipping during deformation process is effectively hindered and the matrix is strengthened,especially for the 2% deformed alloy which can achieve a good combination of strength and ductility.With increasing the plastic deformation,the microcracks occur at the interface between grain boundary precipitations and matrix,and then propagate intergranularly.When intergranular fracture combines with the formation of smoothing facets on the fracture surface,the tensile properties decrease.
基金Projects (2010CB731700,2012CB619500) supported by the National Basic Research Program of China
文摘The influence of Li addition on mechanical property and aging precipitation behavior of Al-3.5Cu-1.5Mg alloy was investigated by tensile test,scanning electron microscopy(SEM),transmission electron microscopy(TEM) and high resolution transmission electron microscopy(HRTEM).The results show that the tensile strength can be significantly improved with the slightly decreased ductility and the form of fracture morphology is converted from ductile fracture into ductile/britde mixed fracture by adding 1.0%Li.Besides,the peak aging time at 185 ℃ is delayed from 12 to 24 h and the main precipitation phase S(Al2CuMg) is converted into S'(Al2CuMg)+δ(Al3Li),while the formation of S'(Al2CuMg) is delayed.
基金Project(2012CB619101)supported by the National Basic Research Program of China
文摘Porous titanium has been shown to exhibit desirable properties as biomedical materials. In view of the load-bearing situation, the mechanical properties and pore structure deformation behaviour of porous titanium were studied. Porous titanium with porosities varying from 36%-66% and average pore size of 230 μm was fabricated by powder sintering. Microstructural features were characterized using scanning electron microscopy. Uniaxial compression tests were used to probe the mechanical response in terms of elastic modulus and compressive strength. The mechanical properties of porous titanium were found to be close to the those of human bone, with stiffness values ranging from 1.86 to 14.7 GPa and compressive strength values of 85.16-461.94 MPa. The relationships between mechanical properties and relative densities were established, and the increase in relative density showed significant effects on mechanical properties and deformations of porous titanium. In a lower relative density, the microscopic deformation mechanism of porous titanium was yielding, bending and buckling of cell walls, while the deformation of yielding and bending of cell walls was observed in the porous titanium with higher relative density.
基金Projects(N100702001,N120310001)supported by the Fundamental Research Funds for the Central Universities,ChinaProject(20131036)supported by Doctoral Fund of Liaoning Province,ChinaProject(51301037)supported by the National Natural Science Foundation of China
文摘Surface mechanical attrition treatment (SMAT) was performed on biomedicalβ-type TiNbZrFe alloy for 60 min at room temperature to study the effect of surface nanocrystallization on the corrosion resistance of TiNbZrFe alloy in physiological environment. The surface nanostructure was characterized by TEM, and the electrochemical behaviors of the samples with nanocrystalline layer and coarse grain were comparatively investigated in 0.9% NaCl and 0.2% NaF solutions, respectively. The results indicate that nanocrystallines with the size of 10-30 nm are formed within the surface layer of 30 μm in depth. The nanocrystallized surface behaves higher impedance, more positive corrosion potential and lower corrosion current density in 0.9%NaCl and 0.2%NaF solutions as compared with the coarse grain surface. The improvement of the corrosion resistance is attributed to the rapid formation of stable and dense passive film on the nanocrystallized surface of TiNbZrFe alloy.
基金supported by the Introducing Talents Funds of Nanjing Institute of Technology,ChinaProject(20100470030) supported by the China Postdoctoral Science Foundation
文摘Mg-2.7Nd-0.2Zn-0.4Zr (mass fraction, %) alloy was designed for degradable biomedical material. The ingots of the alloy were solution treated and then hot extruded. The extruded rods were heat treated with aging treatment, solution treatment and solution+aging treatment, respectively. Microstructures of the alloy were observed by optical microscopy (OM) and scanning electron microscopy (SEM). Mechanical properties at room temperature were tested. In vitro degradation behavior of the alloy immersed in simulated body fluid was measured by hydrogen evolution and mass loss tests. The degradation morphologies of the alloy with and without degradation products were observed by SEM. The results show that the grains grow apparently after solution treatment. Solution treatment improves the elongation of as-extruded alloy significantly and decreases the strength, while aging treatment improves the strength and reduces the elongation of the alloy. The yield ratio is reduced by heat treatment. The in vitro degradation results of the alloy show that solution treatment on the as-extruded alloy results in a little higher degradation rate and aging treatment on the alloy can reduce degradation rate slightly.
基金Supported by Special International Bamboo Research Cooperation Program of Southwest Flower InstituteResearch Institute of Forestry Chinese Academy of Forestry(ICPB-2014-006)~~
文摘The functional bamboos are defined as the ones artificially selected, cultivated and produced in the special functions. Based on the principles to broaden market and maximize benefits, the directional cultivation of the functional bamboos has effectively been used bio-techniques and directionally to breed and cultivate bamboo cultivars to meet human's needs. The functional bamboos should feature stability, excellent quality and convenient production as well as easy duplication. The functional bamboo cultivars should also enhance the scientization, standardization industrialization and mass production. Given no negative environmental impact, ou purpose is to select, cultivate and develop one or more functional bamboos cultivars to meet the consumers' material and spiritual needs and bring more economic ben efits for the producers. The authors believe that directionally breeding functiona bamboo cultivars is not only feasible in techniques, resources and policies, but also in economy and market development. This implicates great significance for the green economic development given the features of China's natural resources.
基金Supported by the National Basic Research Program of China("973"Program)(2010CB731805)theFoundation for Innovative Research Groups of the National Natural Science Foundation of China(60921001)+1 种基金the National Key Technologies R&D Program of China(2011BAH24B02)the Basic Scientific Research Fundation of Central Institutions of Higher Education(ZXH2009D006)~~
文摘In the performance based navigation(PBN),the flight technical error(FTE)and the navigation system error(NSE)are two main parts of total system error(TSE).The implementation of PBN requires pre-flight prediction and en-route short-term dynamical prediction of TSE.Once the sum of predicted FTE and NSE is greater than the specified PBN value,PBN cannot operate.Thus,it requires accurate modeling and thorough analysis of the two main contributors.Multiple-input multiple-output(MIMO)longitudinal flight control system of ARIC model is designed using the linear quadratic Gaussian and loop transfer recovery(LQG/LTR)method,and FTE in symmetrical plane of aircraft is analyzed during the turbulence disturbed approach.The error estimation mapping function of FTE in symmetrical plane and its bound estimation model are proposed based on the singular value theory.The model provides an approach based on the forming mechanism of FTE,rather than the costly flight test and the data fitting.Real-data based simulation validates the theoretical analysis of FTE in symmetrical plane.It also shows that FTE is partially caused by the turbulence fluctuation disturbance when the automatic flight control system(AFCS)is engaged and increases with escalating the environmental turbulence intensity.
文摘Using an optical microscope and scanning electron microscope (SEM), the variation of eutectic Si morphology of Al-Si alloy in solution treatment was observed to study its influence on mechanical properties and fracture behavior. The results show that eutectic Si undergoes stubbing, necking, fragmentation, and growth in the initial stage (250 min); in the middle solution stage (250 to 400 min), the eutectic Si morphology has no significant change, only the degree of spheroidizing becomes higher; after 600 min, the growth of eutectic Si is a coarsening process controlled by diffusion and follows the Liftshitz-Slyozov-Wangner (LSW) model, and the eutectic Si morphology deteriorates due to the occurrence of facets and lap. Based on the quantitative measure and regression analysis, the eutectic Si morphology has a remarkable influence on mechanical properties and fracture behavior.
基金The National Key Technology R&D Program of Chinaduring the 11th Five-Year Plan Period(No.2008BAJ12B04)China Postdoctoral Science Foundation(No.20090461050)+1 种基金the Project of Researchand Development of Ministry of Housing and Urban-Rural Development ofChina(No.2008-K1-26)the New Century Talent Project of Yangzhou University for Excellent Young Backbone Teacher(2008)
文摘In order to investigate the alternate operation characteristics of a solar-ground source heat pump system(SGSHPS),various alternate operation modes are put forward and defined.A two-dimensional mathematical model with freezing/melting phase changes is developed for the heat transfer analysis of the soil.Based on the numerical solution of the model,the variation trends of underground soil temperature of the SGSHPS operated in various alternate operation modes are discussed.The results indicate that,for the day-night and short-time interval alternate operation modes without solar energy,the operation time fraction of a solar heat source should be confined to from 50% to 58% when operated in an alternate period of 24 h.Meanwhile,the disadvantages of a natural resumption of soil temperature can be overcome effectively by solar energy filling,and an optimal operation effect can be achieved by integrating the mode of solar energy filling with other alternate modes.In addition,the accuracy of the presented model is verified by the experimental data of borehole wall temperatures.The conclusions can provide a reference for the optimization operation of the SGSHPS.
基金The National Natural Science Foundation of China (No.50708019)Huo Yingdong Education Foundation(No.104010)Jiangsu Qing Lan Project
文摘In order to reflect the influence of the drivers' characteristic differences on intersection capacity under a mixed traffic flow, a driver correction coefficient for the intersection capacity calculation according to the driver's visual characteristics is proposed. First, the parameters of the driver's visual characteristics at some real roads, including gaze fixation distribution, mean fixation duration, visual angle distribution and some other parameters at intersections, are collected. Then, the relationship between the traffic flow rate at intersections and the parameters of driver eye movements are established. The analytical results indicate that when the traffic flow is unsaturated, the parameters of driver eye movements change relatively little; however, when the traffic flow is saturated, the parameters of driver eye movements change drastically. Finally, the saturation-flow-rate model is modified according to the parameters of driver eye movements; thus, a capacity model of intersections considering the driver's visual characteristics is obtained.