Methanol/TiO2(110) is a model system in the surface science study of photocatalysis where methanol is taken as a hole capture. However, the highest occupied molecular orbital of adsorbed methanol lies below the vale...Methanol/TiO2(110) is a model system in the surface science study of photocatalysis where methanol is taken as a hole capture. However, the highest occupied molecular orbital of adsorbed methanol lies below the valence band maximum of TiO2, preventing the hole transfer. To study the level alignment of this system, electronic structure of methanol covered TiO2(110) surface has been measured by ultraviolet photoelectron spectroscopy and the molecular orbitals of adsorbed methanol have been clearly identified. The results indicate the weak interaction between methanol and TiO2 substrate. The static electronic structure also suggests the mismatch of the energy levels. These static experiments have been performed without band gap excitation which is the prerequisite of a photocatalytie process. Future study of the transient electronic structure using time-resolved UPS has also been discussed.展开更多
Quantum dot gain spectra based on harmonic oscillator model are calculated including and excluding excitons. The effects of non-equilibrium distributions are considered at low temperatures. The variations of threshold...Quantum dot gain spectra based on harmonic oscillator model are calculated including and excluding excitons. The effects of non-equilibrium distributions are considered at low temperatures. The variations of threshold current density in a wide temperature range are analyzed and the negative characteristic temperature and oscillatory characteristic temperature appearing in that temperature range are discussed. Also,the improvement of quantum dot lasers' performance is investigated through vertical stacking and p-type doping and the optimal dot density, which corresponds to minimal threshold current density,is calculated.展开更多
Potential energies of LiS(^2∏), LiS-(^1E+) and LiS+ (^3E-) are calculated by using the multi- reference configuration interaction method including Davidson correction and the augmented correlation-consistent ...Potential energies of LiS(^2∏), LiS-(^1E+) and LiS+ (^3E-) are calculated by using the multi- reference configuration interaction method including Davidson correction and the augmented correlation-consistent basis sets aug-cc-PV(X+d)Z (X=T, Q). Such obtained potential energies are subsequently extrapolated to the complete basis set limit. Both the core-valence correction and the relativistic effect are also considered. The analytical potential energy functions are then obtained by fitting such accurate energies utilizing a least-squares fitting procedure. By using such analytical potential energy functions, we obtain the accurate spectroscopic parameters, complete set of vibrational levels and classical turning points. The present results are compared well with the experimental and other theoretical work.展开更多
The cavity field spectrum of a cascade three-level atom interacting with single-mode field with Kerr-like medium in the cavity is investigated. The numerical results for the initial field in pure number state, coheren...The cavity field spectrum of a cascade three-level atom interacting with single-mode field with Kerr-like medium in the cavity is investigated. The numerical results for the initial field in pure number state, coherent state and squeezed vacuum state are calculated, respectively. It is found that the Kerr-like medium affects the spectral structure even though the initial field is in vacuum when the atom is in upper level. In the case of strong input field, the number state spectrum shows two peaks with different heights; and the superposition state spectrum shows a multipeak structure with an equal distance of two neighboring peaks. The spectral "central frequency" shifts away from the resonant frequency with the increasing of average photon number.展开更多
Y and inverted Y-type four-level schemes for optical quantum coherence systems,which may be intuitivelyconsidered to be very simple,have not been studied intensively till now.In this paper,we present the multiformity ...Y and inverted Y-type four-level schemes for optical quantum coherence systems,which may be intuitivelyconsidered to be very simple,have not been studied intensively till now.In this paper,we present the multiformity ofthese two types of schemes by considering that they can be classified into nine possible level styles as the second-ordersub-schemes using laser fields.Further we point out the complexity of their more than one hundred realistic configurationsas the third-order four-level sub-schemes that may appear in the optical quantum coherence experiments.Throughoutthis paper we review which configurations have been studied in some research aspects and which ones not,accordingto our knowledge,in order to be propitious to next steps of theoretical and experimental investigations,especially forapplications in the fields of quantum optics,quantum information science,laser spectroscopy,and so on.展开更多
We have measured the deep energy level of the InP: Fe which is semi -insulator through the method of OTCS. The effect of light intensity on OTCS measurement is mainly discussed. There are electron trap of E_T =0.34 eV...We have measured the deep energy level of the InP: Fe which is semi -insulator through the method of OTCS. The effect of light intensity on OTCS measurement is mainly discussed. There are electron trap of E_T =0.34 eV and hole trap of E_T = 1.13 eV in InP: Fe under the strong light and low temperature. The location of the OTCS peak of electron trap (E_T = 0.34 eV) moves towards the direction of high temperaturer, when the light intensity was increased, E_T is different under different light intensity. It is corrected in terms of theory that the stuff ratio of the deep energy level is affected by the light intensity. The experiments show that the error is decreased greatly with the correction.展开更多
1.5at% Eu-doped GaN powders were prepared by a co-precipitation method.Powder X-ray diffraction(XRD)results shows that there is only the wurtzite phase.Cathodoluminescence spectra were measured at room temperature and...1.5at% Eu-doped GaN powders were prepared by a co-precipitation method.Powder X-ray diffraction(XRD)results shows that there is only the wurtzite phase.Cathodoluminescence spectra were measured at room temperature and liquid nitrogen temperature,respectively.The band-to-band luminescence of GaN was shifted from 373 nm to 368 nm with the temperature decreasing from room temperature to liquid nitrogen temperature.The luminescence peaks at 537,557,579,590,597,614,653 and 701 nm are attributed to the Eu ions related transitions in the host of GaN powders and the peak positions were not influenced by the variation of temperature.With the increase of accelerating voltage,the intensity of all luminescence peaks was increased.The strongest luminescence peak at 614 nm shows non-symmetrical shape and is composed of 612,615 and 621 nm through Lorentzian fitting,which indicates there are oxygen and nitrogen environments of the Eu3+ions in the Eu-doped GaN powders.展开更多
Photoluminescence properties of highly p+-doped GaASl_ySby are investigated. Band gap narrowing (BGN) effect is considered for heavily doped GaAs1_ySby epilayers. Band-gap Eg(GaAsl_ySby)=l.25y2-1.95y+1.519 is ob...Photoluminescence properties of highly p+-doped GaASl_ySby are investigated. Band gap narrowing (BGN) effect is considered for heavily doped GaAs1_ySby epilayers. Band-gap Eg(GaAsl_ySby)=l.25y2-1.95y+1.519 is obtained through fitting band-gap energy obtained by PL spectra from 35 to 300 K. Fermi level (El) and full width at half maximum (FWHM) of photolumines- cence increase with antimony mole fraction. The increase of Fermi level is attributed to hole mass of GaAsl_ySby decrease which is resulted from antimony composition increase. The increase of Fermi level means that more electrons participate in in- direct transition to result in FWHM increases.展开更多
We obtain the energy spectrum and all the corresponding eigenfunctions of N-body Bose and Fermi systems with Quadratic Pair Potentials in one dimension. The original first excited state or energy level is disappeared ...We obtain the energy spectrum and all the corresponding eigenfunctions of N-body Bose and Fermi systems with Quadratic Pair Potentials in one dimension. The original first excited state or energy level is disappeared in one dimension, which results from the operation of symmetry or antisymmetry of identical particles. In two and higher dimensions, we give the energy spectrum and the analytical ground state wave [unctions and the degree of degeneracy. By comparison, we refine A vinash Khare's results by making some items in his article precisely.展开更多
We investigate the features of the spontaneous emission spectra in a cold five-level atomic system coupled by a single elliptically polarized control field. We use wave function approach to derive the explicit and ana...We investigate the features of the spontaneous emission spectra in a cold five-level atomic system coupled by a single elliptically polarized control field. We use wave function approach to derive the explicit and analytical expressions of atomic spontaneous emission spectra. It is shown that some interesting phenomena such as spectralline enhancement, spectral-line suppression, spectral-line narrowing, spectral-line splitting and dark fluorescence can be observed in the spectra by appropriately modulating the phase difference between the right-hand circularly (LHC) and left-hand circularly (RHC) polarized components of the elliptically polarized control field and the intensity of external magnetic field. The number of emission peaks, the positions of fluorescence-quenching points can be also controlled. Furthermore, we propose an ultracold 87Rb atomic system for experimental observation. These investigations may find applications in high-precision spectroscopy.展开更多
文摘Methanol/TiO2(110) is a model system in the surface science study of photocatalysis where methanol is taken as a hole capture. However, the highest occupied molecular orbital of adsorbed methanol lies below the valence band maximum of TiO2, preventing the hole transfer. To study the level alignment of this system, electronic structure of methanol covered TiO2(110) surface has been measured by ultraviolet photoelectron spectroscopy and the molecular orbitals of adsorbed methanol have been clearly identified. The results indicate the weak interaction between methanol and TiO2 substrate. The static electronic structure also suggests the mismatch of the energy levels. These static experiments have been performed without band gap excitation which is the prerequisite of a photocatalytie process. Future study of the transient electronic structure using time-resolved UPS has also been discussed.
文摘Quantum dot gain spectra based on harmonic oscillator model are calculated including and excluding excitons. The effects of non-equilibrium distributions are considered at low temperatures. The variations of threshold current density in a wide temperature range are analyzed and the negative characteristic temperature and oscillatory characteristic temperature appearing in that temperature range are discussed. Also,the improvement of quantum dot lasers' performance is investigated through vertical stacking and p-type doping and the optimal dot density, which corresponds to minimal threshold current density,is calculated.
基金This work was supported by the National Natural Science Foundation of China (No.11304185), Taishan scholar project of Shandong Province, China Postdoctoral Science Foundation (No.2014M561957), and Post-doctoral Innovation Project of Shandong Province (No.201402013), Shandong Provincial Natural Science Foundation (No.ZR2014AM022). The authors gratefully acknowledge Dr. S. Li for useful discussion in this work.
文摘Potential energies of LiS(^2∏), LiS-(^1E+) and LiS+ (^3E-) are calculated by using the multi- reference configuration interaction method including Davidson correction and the augmented correlation-consistent basis sets aug-cc-PV(X+d)Z (X=T, Q). Such obtained potential energies are subsequently extrapolated to the complete basis set limit. Both the core-valence correction and the relativistic effect are also considered. The analytical potential energy functions are then obtained by fitting such accurate energies utilizing a least-squares fitting procedure. By using such analytical potential energy functions, we obtain the accurate spectroscopic parameters, complete set of vibrational levels and classical turning points. The present results are compared well with the experimental and other theoretical work.
基金The project supported by the Natural Science Foundation of Shandong Province under Grant No. Y2004A09
文摘The cavity field spectrum of a cascade three-level atom interacting with single-mode field with Kerr-like medium in the cavity is investigated. The numerical results for the initial field in pure number state, coherent state and squeezed vacuum state are calculated, respectively. It is found that the Kerr-like medium affects the spectral structure even though the initial field is in vacuum when the atom is in upper level. In the case of strong input field, the number state spectrum shows two peaks with different heights; and the superposition state spectrum shows a multipeak structure with an equal distance of two neighboring peaks. The spectral "central frequency" shifts away from the resonant frequency with the increasing of average photon number.
基金Supported by the Research Starting Funds of Tianjin Polytechnic University under Grant Nos.20080033 and 20070010
文摘Y and inverted Y-type four-level schemes for optical quantum coherence systems,which may be intuitivelyconsidered to be very simple,have not been studied intensively till now.In this paper,we present the multiformity ofthese two types of schemes by considering that they can be classified into nine possible level styles as the second-ordersub-schemes using laser fields.Further we point out the complexity of their more than one hundred realistic configurationsas the third-order four-level sub-schemes that may appear in the optical quantum coherence experiments.Throughoutthis paper we review which configurations have been studied in some research aspects and which ones not,accordingto our knowledge,in order to be propitious to next steps of theoretical and experimental investigations,especially forapplications in the fields of quantum optics,quantum information science,laser spectroscopy,and so on.
文摘We have measured the deep energy level of the InP: Fe which is semi -insulator through the method of OTCS. The effect of light intensity on OTCS measurement is mainly discussed. There are electron trap of E_T =0.34 eV and hole trap of E_T = 1.13 eV in InP: Fe under the strong light and low temperature. The location of the OTCS peak of electron trap (E_T = 0.34 eV) moves towards the direction of high temperaturer, when the light intensity was increased, E_T is different under different light intensity. It is corrected in terms of theory that the stuff ratio of the deep energy level is affected by the light intensity. The experiments show that the error is decreased greatly with the correction.
基金supported by the National Natural Science Foundation of China(Grant Nos.51002179 and 61306004)the Natural Science Fund of Jiangsu Province(Grant No.BK20130263)the Instruments Function Innovation of Chinese Academy of Sciences(Grant No.yg2012093)
文摘1.5at% Eu-doped GaN powders were prepared by a co-precipitation method.Powder X-ray diffraction(XRD)results shows that there is only the wurtzite phase.Cathodoluminescence spectra were measured at room temperature and liquid nitrogen temperature,respectively.The band-to-band luminescence of GaN was shifted from 373 nm to 368 nm with the temperature decreasing from room temperature to liquid nitrogen temperature.The luminescence peaks at 537,557,579,590,597,614,653 and 701 nm are attributed to the Eu ions related transitions in the host of GaN powders and the peak positions were not influenced by the variation of temperature.With the increase of accelerating voltage,the intensity of all luminescence peaks was increased.The strongest luminescence peak at 614 nm shows non-symmetrical shape and is composed of 612,615 and 621 nm through Lorentzian fitting,which indicates there are oxygen and nitrogen environments of the Eu3+ions in the Eu-doped GaN powders.
文摘Photoluminescence properties of highly p+-doped GaASl_ySby are investigated. Band gap narrowing (BGN) effect is considered for heavily doped GaAs1_ySby epilayers. Band-gap Eg(GaAsl_ySby)=l.25y2-1.95y+1.519 is obtained through fitting band-gap energy obtained by PL spectra from 35 to 300 K. Fermi level (El) and full width at half maximum (FWHM) of photolumines- cence increase with antimony mole fraction. The increase of Fermi level is attributed to hole mass of GaAsl_ySby decrease which is resulted from antimony composition increase. The increase of Fermi level means that more electrons participate in in- direct transition to result in FWHM increases.
基金Supported by the National Natural Science Foundation of China under Grant No.10975125
文摘We obtain the energy spectrum and all the corresponding eigenfunctions of N-body Bose and Fermi systems with Quadratic Pair Potentials in one dimension. The original first excited state or energy level is disappeared in one dimension, which results from the operation of symmetry or antisymmetry of identical particles. In two and higher dimensions, we give the energy spectrum and the analytical ground state wave [unctions and the degree of degeneracy. By comparison, we refine A vinash Khare's results by making some items in his article precisely.
基金Supported by the National Natural Science Foundation of China under Grant Nos.11275047, 11004069 and 91021011the Doctoral Foundation of the Ministry of Education of China under Grant No.20100142120081the National Basic Research Program of China under Grant No.2012CB922103
文摘We investigate the features of the spontaneous emission spectra in a cold five-level atomic system coupled by a single elliptically polarized control field. We use wave function approach to derive the explicit and analytical expressions of atomic spontaneous emission spectra. It is shown that some interesting phenomena such as spectralline enhancement, spectral-line suppression, spectral-line narrowing, spectral-line splitting and dark fluorescence can be observed in the spectra by appropriately modulating the phase difference between the right-hand circularly (LHC) and left-hand circularly (RHC) polarized components of the elliptically polarized control field and the intensity of external magnetic field. The number of emission peaks, the positions of fluorescence-quenching points can be also controlled. Furthermore, we propose an ultracold 87Rb atomic system for experimental observation. These investigations may find applications in high-precision spectroscopy.