The study was conducted in a plastic tunnel in which the heat storage system was installed in the stone accumulator. The system consists of a suction pipe warm air fan and perforated pipes placed in the stone＇s accum...The study was conducted in a plastic tunnel in which the heat storage system was installed in the stone accumulator. The system consists of a suction pipe warm air fan and perforated pipes placed in the stone＇s accumulator. The accumulator used a bed of stone （porphyry-type stones of dimension in the range 37 mm to 65 ram）. In the accumulator, there are four sections with dimensions of 1.7 m × 11 m, each of which contains a perforated pipe for hot air distribution within the battery, and separate conduits for supplying air to the interior of the tunnel. The paper presents the results of analysis related to performance （as a result of heat and mass transfer） in cycles of charging and discharging of the accumulator.展开更多
Developing efficient,stable,and low-cost novel electron-cocatalysts is crucial for photocatalytic hydrogen evolution reaction.Herein,amorphous Ni-P alloy particles were successfully modified onto g-C3N4 to construct t...Developing efficient,stable,and low-cost novel electron-cocatalysts is crucial for photocatalytic hydrogen evolution reaction.Herein,amorphous Ni-P alloy particles were successfully modified onto g-C3N4 to construct the Ni-P/g-C3N4 photocatalyst through a simple and green triethanolamine(TEOA)-mediated photodeposition method.It was found that the TEOA could serve as an excellent complexing agent to coordinate with Ni2+to form[Ni(TEOA)]^2+complex,which can promote the rapid and effective deposition of amorphous Ni-P alloy on the g-C3N4 surface.Photocatalytic tests suggest that the hydrogen-evolution performance of gC3N4 can be greatly promoted through integrating amorphous Ni-P alloy.Especially,the Ni-P/g-C3N4(5 wt%)exhibits the superior H2-generation activity(118.2μmol h^-1g^-1),which is almost 35.8 times that of bare g-C3N4.Furthermore,the amorphous Ni-P alloy cocatalyst can also serve as the general hydrogen-production cocatalyst to greatly enhance the photocatalytic performance of traditional semiconductor materials such as Ti O2 and Cd S.Based on the present results,the mechanism of the amorphous Ni-P alloy as the high-efficiency electron transfer medium was proposed for the boosted H2-generation rate.The present facile route may broaden the horizons for the efficient development of highly active cocatalysts in photocatalytic field.展开更多
文摘The study was conducted in a plastic tunnel in which the heat storage system was installed in the stone accumulator. The system consists of a suction pipe warm air fan and perforated pipes placed in the stone＇s accumulator. The accumulator used a bed of stone （porphyry-type stones of dimension in the range 37 mm to 65 ram）. In the accumulator, there are four sections with dimensions of 1.7 m × 11 m, each of which contains a perforated pipe for hot air distribution within the battery, and separate conduits for supplying air to the interior of the tunnel. The paper presents the results of analysis related to performance （as a result of heat and mass transfer） in cycles of charging and discharging of the accumulator.
基金supported by the National Natural Science Foundation of China(21771142 and 51672203)the Fun-damental Research Funds for the Central Universities(WUT 2019IB002)。
文摘Developing efficient,stable,and low-cost novel electron-cocatalysts is crucial for photocatalytic hydrogen evolution reaction.Herein,amorphous Ni-P alloy particles were successfully modified onto g-C3N4 to construct the Ni-P/g-C3N4 photocatalyst through a simple and green triethanolamine(TEOA)-mediated photodeposition method.It was found that the TEOA could serve as an excellent complexing agent to coordinate with Ni2+to form[Ni(TEOA)]^2+complex,which can promote the rapid and effective deposition of amorphous Ni-P alloy on the g-C3N4 surface.Photocatalytic tests suggest that the hydrogen-evolution performance of gC3N4 can be greatly promoted through integrating amorphous Ni-P alloy.Especially,the Ni-P/g-C3N4(5 wt%)exhibits the superior H2-generation activity(118.2μmol h^-1g^-1),which is almost 35.8 times that of bare g-C3N4.Furthermore,the amorphous Ni-P alloy cocatalyst can also serve as the general hydrogen-production cocatalyst to greatly enhance the photocatalytic performance of traditional semiconductor materials such as Ti O2 and Cd S.Based on the present results,the mechanism of the amorphous Ni-P alloy as the high-efficiency electron transfer medium was proposed for the boosted H2-generation rate.The present facile route may broaden the horizons for the efficient development of highly active cocatalysts in photocatalytic field.
