In this study,the microstructure and mechanical properties of a multi-layered 316L-TiC composite material produced by selective laser melting(SLM)additive manufacturing process are investigated.Three different layers,...In this study,the microstructure and mechanical properties of a multi-layered 316L-TiC composite material produced by selective laser melting(SLM)additive manufacturing process are investigated.Three different layers,consisting of 316L stainless steel,316L-5 wt%TiC and 316L-10 wt%TiC,were additively manufactured.The microstructure of these layers was characterized by optical microscopy(OM)and scanning electron microscopy(SEM).X-ray diffraction(XRD)was used for phase analysis,and the mechanical properties were evaluated by tensile and nanoindentation tests.The microstructural observations show epitaxial grain growth within the composite layers,with the elongated grains growing predominantly in the build direction.XRD analysis confirms the successful incorporation of the TiC particles into the 316L matrix,with no unwanted phases present.Nanoindentation results indicate a significant increase in the hardness and modulus of elasticity of the composite layers compared to pure 316L stainless steel,suggesting improved mechanical properties.Tensile tests show remarkable strength values for the 316L-TiC composite samples,which can be attributed to the embedded TiC particles.These results highlight the potential of SLM in the production of multi-layer metal-ceramic composites for applications that require high strength and ductility of metallic components in addition to the exceptional hardness of the ceramic particles.展开更多
The effect of realistic topology configuration of intercellular connections on the response ability in coupled cell system is numerically investigated by using the Hindmarsh-Rose model. For the proper coupling intensi...The effect of realistic topology configuration of intercellular connections on the response ability in coupled cell system is numerically investigated by using the Hindmarsh-Rose model. For the proper coupling intensity, we set the control parameter to be near the critical value, and the external stimulus is introduced to the first cell in coupled system. It is found that, on one hand, when the cells are coupled with some proper topological structures, the external stimulus could transmit through the system, and shows better response ability and higher sensitivity. On the other hand, the influence of topological configuration on the synchronous ability and selection effect of neural system are also discussed. Our results display that the topology of coupled system may play an important role in the process of signal propagation, which could help us to understand the coordinated performance of cells in tissue.展开更多
Combining the characteristics of peer-to-peer (P2P) and grid, a super-peer selection algorithm--SSABC is presented in the distributed network merging P2P and grid. The algorithm computes nodes capacities using their...Combining the characteristics of peer-to-peer (P2P) and grid, a super-peer selection algorithm--SSABC is presented in the distributed network merging P2P and grid. The algorithm computes nodes capacities using their resource properties provided by a grid monitoring and discovery system, such as available bandwidth, free CPU and idle memory, as well as the number of current connections and online time. when a new node joins the network and the super-peers are all saturated, it should select a new super-peer from the new node or joined nodes with the highest capacity. By theoretical analyses and simulation experiments, it is shown that super-peers selected by capacity can achieve higher query success rates and shorten the average hop count when compared with super-peers selected randomly, and they can also balance the network load when all super-peers are saturated. When the number of total nodes changes, the conclusion is still valid, which explains that the algorithm SSABC is feasible and stable.展开更多
The knowledge representation mode and inference control strategy were analyzed according to the specialties of air-conditioning cooling/heating sources selection. The constructing idea and working procedure for knowle...The knowledge representation mode and inference control strategy were analyzed according to the specialties of air-conditioning cooling/heating sources selection. The constructing idea and working procedure for knowledge base and inference engine were proposed while the realization technique of the C language was discussed. An intelligent decision support system (IDSS) model based on such knowledge representation and inference mechanism was developed by domain engineers. The model was verified to have a small kernel and powerful capability in list processing and data driving, which was successfully used in the design of a cooling/heating sources system for a large-sized office building.展开更多
Two series of Mn/beta and Mn/ZSM‐5catalysts were prepared to study the influence of how different Mn precursors,introduced to the respective parent zeolites by wet impregnation,affected the selective catalytic reduct...Two series of Mn/beta and Mn/ZSM‐5catalysts were prepared to study the influence of how different Mn precursors,introduced to the respective parent zeolites by wet impregnation,affected the selective catalytic reduction(SCR)of NO by NH3across a low reaction temperature window of50–350°C.In this study,the catalysts were characterized using N2adsorption/desorption,X‐ray diffraction,X‐ray fluorescence,H2temperature‐programmed reduction,NH3temperature‐programmed desorption and X‐ray photoelectron spectroscopy.As the manganese chloride precursor only partially decomposed this primarily resulted in the formation of MnCl2in addition to the presence of low levels of crystalline Mn3O4,which resulted in poor catalytic performance.However,the manganese nitrate precursor formed crystalline MnO2as the major phase in addition to a minor presence of unconverted Mn‐nitrate.Furthermore,manganese acetate resulted principally in a mixture of amorphous Mn2O3and MnO2,and crystalline Mn3O4.From all the catalysts screened,the test performance data showed Mn/beta‐Ac to exhibit the highest NO conversion(97.5%)at240°C,which remained>90%across a temperature window of220–350°C.The excellent catalytic performance was ascribed to the enrichment of highly dispersed MnOx(Mn2O3and MnO2)species that act as the active phase in the NH3‐SCR process.Furthermore,together with a suitable amount of weakly acidic centers,higher concentration of surface manganese and a greater presence of surface labile oxygen groups,SCR performance was collectively enhanced at low temperature.?2018,Dalian Institute of Chemical Physics,Chinese Academy of Sciences.Published by Elsevier B.V.All rights reserved.展开更多
The V/O5-WO3-MoOy'TiO2 honeycomb catalyst was prepared with industrial grade chemicals. The structural and physico-chemical properties were analyzed with X-ray diffraction (XRD), scanning electron micrograph (SEM...The V/O5-WO3-MoOy'TiO2 honeycomb catalyst was prepared with industrial grade chemicals. The structural and physico-chemical properties were analyzed with X-ray diffraction (XRD), scanning electron micrograph (SEM) and mercury porosimetry. The NOx conversion and durability were investigated on a pilot plant test set under the actual operational conditions of a coal fired boiler. The catalyst monolith had good formability with mass per- centage of V : W : Mo : TiO2 : fiber glass = 1 : 4.5 : 4.5 : 72 : 18. Vanadium, tungsten and molybdenum species were highly dispersed on anatase TiO2 without causing the transformation of anatase TiO2 to ruffle by calcining under a current of air at 450℃ for 4.5 h, but there were some degrees of crystal distortion. The catalyst particle sizes were almost uniform with close pile-up and the pore structure was regular with complete macro-pore formation and large specific surface area. The NOx conversion was sensitive to temperature but nearly insensitive to NH3. The catalyst showed strong adaptability to NOx concentration with activity above 80% in the range of 615 1640 mg.m-3. Within the range of 720-8640 h continuous operation, the NOx conversion dropped at a rate of about 1% reduction per 600 h.展开更多
We investigated the structural evolution and elecfronic properties of ConC3-/0 and ConC4-/0 (n=1-4) clusters by using mass-selected photoelectron spectroscopy and density functional theory calculations. The adiabati...We investigated the structural evolution and elecfronic properties of ConC3-/0 and ConC4-/0 (n=1-4) clusters by using mass-selected photoelectron spectroscopy and density functional theory calculations. The adiabatic and vertical detachment energies of CO1-4C3- and COl-4C4- were obtained from their photoelectron spectra. By comparing the theoretical results with the experimental data, the global minimum structures were determined. The results indicate that the carbon atoms of ConC3-/0 and ConC4-/0 (n=1-4) are separated from each other gradually with increasing number of cobalt atoms but a C2 unit still remains at n=4. It is interesting that the Co2C3- and Co2C4- anions have planar structures whereas the neutral Co2C3 and Co2C4 have linear structures with the Co atoms at two ends. The Co3C3- anion has a planar structure with a Co2C2 four-membered ring and a Co3C four-membered ring sharing a Co-Co bond, while the neutral Co3C3 is a three-dimensional structure with a C2 unit and a C atom connecting to two faces of the Co3 triangle.展开更多
Fixed carrier membrane exhibits attractive CO2 permeance and selectivity due to its transport mechanism of reaction selectivity (facilitated transport). However, its performance needs improvement to meet cost target...Fixed carrier membrane exhibits attractive CO2 permeance and selectivity due to its transport mechanism of reaction selectivity (facilitated transport). However, its performance needs improvement to meet cost targets for CO2 capture. This study attempts to develop membranes with multiple permselective mechanisms in order to enhance CO2 separation performance of fixed carder membrane. In this study, a novel membrane with multiplepermselective mechanisms of solubility selectivity and reaction selectivity was developed by incorporating CO2-selective adsorptive silica nanoparticles in situ into the tertiary amine containing polyamide membrane formed by interfacial polymerization (IP). Various techniques were employed to characterize the polyamide and polyam-ide-silica composite membranes. The TGA result shows that nanocomposite membranes exhlbit superior-thermal stability than pure polyamide membranes. In addition, gas permeation experiments show that both nanocomposite membranes have larger CO2 permeance than pure polyamide membranes. The enhanced CO2/N2 separation performance for nanocomposite membranes is mainly due to the thin film thickness, and multiple permselective mechanisms of solubility selectivity and reaction selectivity.展开更多
Multi-target tracking(MTT) is a research hotspot of wireless sensor networks at present.A self-organized dynamic cluster task allocation scheme is used to implement collaborative task allocation for MTT in WSN and a s...Multi-target tracking(MTT) is a research hotspot of wireless sensor networks at present.A self-organized dynamic cluster task allocation scheme is used to implement collaborative task allocation for MTT in WSN and a special cluster member(CM) node selection method is put forward in the scheme.An energy efficiency model was proposed under consideration of both energy consumption and remaining energy balance in the network.A tracking accuracy model based on area-sum principle was also presented through analyzing the localization accuracy of triangulation.Then,the two models mentioned above were combined to establish dynamic cluster member selection model for MTT where a comprehensive performance index function was designed to guide the CM node selection.This selection was fulfilled using genetic algorithm.Simulation results show that this method keeps both energy efficiency and tracking quality in optimal state,and also indicate the validity of genetic algorithm in implementing CM node selection.展开更多
C1 chemistry is the essence of coal chemistry and natural gas chemistry. Catalytic methods to efficiently convert C1 molecules into fuels and chemicals have been extensively studied. Syngas(CO +H_2) conversion is t...C1 chemistry is the essence of coal chemistry and natural gas chemistry. Catalytic methods to efficiently convert C1 molecules into fuels and chemicals have been extensively studied. Syngas(CO +H_2) conversion is the most important industrial reaction system in C1 chemistry, and Fe and Co catalysts, two major industrial catalysts, have been the focus of fundamental research and industrial application. In the last decade, considerable research efforts have been devoted to discoveries concerning catalyst structure and increasing market demands for olefins and oxygenates. Since the development of efficient catalysts would strongly benefit from catalyst design and the establishment of a new reaction system, this review comprehensively overviews syngas conversion in three main reactions, highlights the advances recently made and the challenges that remain open, and will stimulate future research activities. The first part of the review summarizes the breakthroughs in Fischer-Tropsch synthesis regarding the optimization of activity and stability, determination of the active phase, and mechanistic studies. The second part overviews the modulation of catalytic structure and product selectivity for Fischer-Tropsch to olefins(FTO). Catalysts designed to produce higher alcohols, as well as to tune product selectivity in C1 chemistry, are described in the third section. Finally, present challenges in syngas conversion are proposed, and the solutions and prospects are discussed from the viewpoint of fundamental research and practical application. This review summarizes the latest advances in the design, preparation, and application of Fe/Co-based catalysts toward syngas conversion and presents the challenges and future directions in producing value-added fuels.展开更多
In order to resolve the relay selection problem in wireless mobile relay networks (WMRNs), a novel balanced energy-efficient mobile relay selection scheme is proposed in this paper. Compared with traditional counter...In order to resolve the relay selection problem in wireless mobile relay networks (WMRNs), a novel balanced energy-efficient mobile relay selection scheme is proposed in this paper. Compared with traditional counter-based algorithm, distance and energy consumption are considered from network respect to provide a better network lifetime performance in the proposed scheme. Also, it performs well when nodes move freely at high speed. A random assessment delay (RAD) mechanism is added to avoid collisions and improve transmission efficiency. Simulation results reveal that, the proposed scheme has advantages in prolonging network lifetime, balancing energy compared with existing counter-based scheme. consumption and reducing the total energy consumption展开更多
A method to select solvent for extractive distillation is proposed by UNIFAC group contribution. Solventselectivity can be divided into two parts: the partial combinatorial solvent selectivity and the partial residual...A method to select solvent for extractive distillation is proposed by UNIFAC group contribution. Solventselectivity can be divided into two parts: the partial combinatorial solvent selectivity and the partial residual solventselectivity. The properties of partial combinatorial and residual solvent selectivity are demonstrated. In most cases,the partial residual solvent selectivity is predominant. The candidate groups of solvent can be selected by groupinteraction parameter using UNIFAC group interaction parameter table as a guide.展开更多
Graphene/Inconel 718 composites were innovatively synthesized through selective laser melting,and the mechanical and tribological performances of the grapheme-reinforced Inconel 718 matrix composites were evaluated.Th...Graphene/Inconel 718 composites were innovatively synthesized through selective laser melting,and the mechanical and tribological performances of the grapheme-reinforced Inconel 718 matrix composites were evaluated.The composite microstructures were characterized by XRD,SEM and Raman spectroscopy.The results show that selective laser melting is a viable method to fabricate Inconel 718 matrix composite and the addition of graphene nanoplatelets leads to a significant strengthening of Inconel 718 alloy,as well as the improvement of tribological performance.The yield strength and ultimate tensile strength of 1.0%graphene/Inconel 718 composites(mass fraction)are 42%and 53%higher than those of pure material,and the friction coefficient and wear rate are 22.4%and 66.8%lower than those of pure material.The decrease of fraction coefficient and wear rate is attributed to the improved hardness of composites and the formation of graphene nanoplatelet protective layer on the worn surfaces.展开更多
To investigate how the physicochemical properties and NH3‐selective catalytic reduction(NH3‐SCR)performance of supported ceria‐based catalysts are influenced as a function of support type,a series of CeO2/SiO2,CeO2...To investigate how the physicochemical properties and NH3‐selective catalytic reduction(NH3‐SCR)performance of supported ceria‐based catalysts are influenced as a function of support type,a series of CeO2/SiO2,CeO2/γ‐Al2O3,CeO2/ZrO2,and CeO2/TiO2catalysts were prepared.The physicochemical properties were probed by means of X‐ray diffraction,Raman spectroscopy,Brunauer‐Emmett‐Teller surface area measurements,X‐ray photoelectron spectroscopy,H2‐temperature programmed reduction,and NH3‐temperature programmed desorption.Furthermore,the supported ceria‐based catalysts'catalytic performance and H2O+SO2tolerance were evaluated by the NH3‐SCR model reaction.The results indicate that out of the supported ceria‐based catalysts studied,the CeO2/γ‐Al2O3catalyst exhibits the highest catalytic activity as a result of having a high relative Ce3+/Ce4+ratio,optimum reduction behavior,and the largest total acid site concentration.Finally,the CeO2/γ‐Al2O3catalyst also presents excellent H2O+SO2tolerance during the NH3‐SCR process.展开更多
With the explosive growth and need for high-speed wireless communications, more and more energy is consumed to support the required quality of service. Therefore, energy efficient or green communication has become a v...With the explosive growth and need for high-speed wireless communications, more and more energy is consumed to support the required quality of service. Therefore, energy efficient or green communication has become a very hot topic under the ground of limited energy resource and environmentally friendly transmission schemes. MIMO technique is capable of reducing the transmission power thanks to its diversity and multiplexing gain. Moreover, antenna selection(AS) is an alternative to extract many of the benefits in MIMO systems with a reduced cost of complexity and power. Although many works including several survey papers have investigated AS in MIMO systems, the goal of these works is only the capacity maximization or error rate minimization, which fails to guarantee the optimality of the energy efficiency in MIMO systems. In this paper, we overview the state of the art in the AS schemes in energy efficient MIMO systems, the goal of which is to optimize the energy efficiency of the whole system. Specifically, we introduce energy efficient AS in point-to-point MIMO, cooperative MIMO, multiuser MIMO and largescale MIMO systems, respectively. Several challenging and practical issues in this area are also addressed.展开更多
Opportunistic networks are random networks and do not communicate with each other among respective communication areas.This situation leads to great difficulty in message transfer.This paper proposes a reducing energy...Opportunistic networks are random networks and do not communicate with each other among respective communication areas.This situation leads to great difficulty in message transfer.This paper proposes a reducing energy consumption optimal selection of path transmission(OSPT) routing algorithm in opportunistic networks.This algorithm designs a dynamic random network topology,creates a dynamic link,and realizes an optimized selected path.This algorithm solves a problem that nodes are unable to deliver messages for a long time in opportunistic networks.According to the simulation experiment,OSPT improves deliver ratio,and reduces energy consumption,cache time and transmission delay compared with the Epidemic Algorithm and Spray and Wait Algorithm in opportunistic networks.展开更多
In this paper, we proposed a new approach for face recognition with robust to illumination variation. The improved performance to various lights in recognition is obtained by a novel combination of multicondition reli...In this paper, we proposed a new approach for face recognition with robust to illumination variation. The improved performance to various lights in recognition is obtained by a novel combination of multicondition relighting and optimal feature selection. Multi-condition relighting provides a "coarse" compensation for the variable illumination, and then the optimal feature selection further refines the compensation, and additionally offers the robustness to shadow and highlight, by deemphasizing the local mismatches caused by imprecise lighting compensation, shadow or highlight on recognition. For evaluation, two databases with various illumination mismatches have been used. The results have demonstrated the improved robustness of the new methods.展开更多
The primary goal of this work is to characterize the impact of weighting selection strategy and multistatic geometry on the multistatic radar performance. With the relationship between the multistatic ambiguity functi...The primary goal of this work is to characterize the impact of weighting selection strategy and multistatic geometry on the multistatic radar performance. With the relationship between the multistatic ambiguity function (AF) and the multistatie Cram6r-Rao lower bound (CRLB), the problem of calculating the multistatic AF and the multistatic CRLB as a performance metric for multistatic radar system is studied. Exactly, based on the proper selection of the system parameters, the multistatic radar performance can be significantly improved. The simulation results illustrate that the multistatic AF and the multistatic CRLB can serve as guidelines for future multistatic fusion rule development and multistatic radars deployment.展开更多
文摘In this study,the microstructure and mechanical properties of a multi-layered 316L-TiC composite material produced by selective laser melting(SLM)additive manufacturing process are investigated.Three different layers,consisting of 316L stainless steel,316L-5 wt%TiC and 316L-10 wt%TiC,were additively manufactured.The microstructure of these layers was characterized by optical microscopy(OM)and scanning electron microscopy(SEM).X-ray diffraction(XRD)was used for phase analysis,and the mechanical properties were evaluated by tensile and nanoindentation tests.The microstructural observations show epitaxial grain growth within the composite layers,with the elongated grains growing predominantly in the build direction.XRD analysis confirms the successful incorporation of the TiC particles into the 316L matrix,with no unwanted phases present.Nanoindentation results indicate a significant increase in the hardness and modulus of elasticity of the composite layers compared to pure 316L stainless steel,suggesting improved mechanical properties.Tensile tests show remarkable strength values for the 316L-TiC composite samples,which can be attributed to the embedded TiC particles.These results highlight the potential of SLM in the production of multi-layer metal-ceramic composites for applications that require high strength and ductility of metallic components in addition to the exceptional hardness of the ceramic particles.
文摘The effect of realistic topology configuration of intercellular connections on the response ability in coupled cell system is numerically investigated by using the Hindmarsh-Rose model. For the proper coupling intensity, we set the control parameter to be near the critical value, and the external stimulus is introduced to the first cell in coupled system. It is found that, on one hand, when the cells are coupled with some proper topological structures, the external stimulus could transmit through the system, and shows better response ability and higher sensitivity. On the other hand, the influence of topological configuration on the synchronous ability and selection effect of neural system are also discussed. Our results display that the topology of coupled system may play an important role in the process of signal propagation, which could help us to understand the coordinated performance of cells in tissue.
基金The National High Technology Research and Development Program of China (863 Program) (No.2007AA01Z422)the NaturalFoundation of Anhui Provincial Education Department (No.2006KJ041B,KJ2007B073)
文摘Combining the characteristics of peer-to-peer (P2P) and grid, a super-peer selection algorithm--SSABC is presented in the distributed network merging P2P and grid. The algorithm computes nodes capacities using their resource properties provided by a grid monitoring and discovery system, such as available bandwidth, free CPU and idle memory, as well as the number of current connections and online time. when a new node joins the network and the super-peers are all saturated, it should select a new super-peer from the new node or joined nodes with the highest capacity. By theoretical analyses and simulation experiments, it is shown that super-peers selected by capacity can achieve higher query success rates and shorten the average hop count when compared with super-peers selected randomly, and they can also balance the network load when all super-peers are saturated. When the number of total nodes changes, the conclusion is still valid, which explains that the algorithm SSABC is feasible and stable.
文摘The knowledge representation mode and inference control strategy were analyzed according to the specialties of air-conditioning cooling/heating sources selection. The constructing idea and working procedure for knowledge base and inference engine were proposed while the realization technique of the C language was discussed. An intelligent decision support system (IDSS) model based on such knowledge representation and inference mechanism was developed by domain engineers. The model was verified to have a small kernel and powerful capability in list processing and data driving, which was successfully used in the design of a cooling/heating sources system for a large-sized office building.
基金supported by the National Science and Technology Program of China(CDGC01-KT16)~~
文摘Two series of Mn/beta and Mn/ZSM‐5catalysts were prepared to study the influence of how different Mn precursors,introduced to the respective parent zeolites by wet impregnation,affected the selective catalytic reduction(SCR)of NO by NH3across a low reaction temperature window of50–350°C.In this study,the catalysts were characterized using N2adsorption/desorption,X‐ray diffraction,X‐ray fluorescence,H2temperature‐programmed reduction,NH3temperature‐programmed desorption and X‐ray photoelectron spectroscopy.As the manganese chloride precursor only partially decomposed this primarily resulted in the formation of MnCl2in addition to the presence of low levels of crystalline Mn3O4,which resulted in poor catalytic performance.However,the manganese nitrate precursor formed crystalline MnO2as the major phase in addition to a minor presence of unconverted Mn‐nitrate.Furthermore,manganese acetate resulted principally in a mixture of amorphous Mn2O3and MnO2,and crystalline Mn3O4.From all the catalysts screened,the test performance data showed Mn/beta‐Ac to exhibit the highest NO conversion(97.5%)at240°C,which remained>90%across a temperature window of220–350°C.The excellent catalytic performance was ascribed to the enrichment of highly dispersed MnOx(Mn2O3and MnO2)species that act as the active phase in the NH3‐SCR process.Furthermore,together with a suitable amount of weakly acidic centers,higher concentration of surface manganese and a greater presence of surface labile oxygen groups,SCR performance was collectively enhanced at low temperature.?2018,Dalian Institute of Chemical Physics,Chinese Academy of Sciences.Published by Elsevier B.V.All rights reserved.
基金Supported by the Science and Technology Development Planning of Shandong Province(2011GSF11716)China Scholarship Council for Researching in University of Birmingham
文摘The V/O5-WO3-MoOy'TiO2 honeycomb catalyst was prepared with industrial grade chemicals. The structural and physico-chemical properties were analyzed with X-ray diffraction (XRD), scanning electron micrograph (SEM) and mercury porosimetry. The NOx conversion and durability were investigated on a pilot plant test set under the actual operational conditions of a coal fired boiler. The catalyst monolith had good formability with mass per- centage of V : W : Mo : TiO2 : fiber glass = 1 : 4.5 : 4.5 : 72 : 18. Vanadium, tungsten and molybdenum species were highly dispersed on anatase TiO2 without causing the transformation of anatase TiO2 to ruffle by calcining under a current of air at 450℃ for 4.5 h, but there were some degrees of crystal distortion. The catalyst particle sizes were almost uniform with close pile-up and the pore structure was regular with complete macro-pore formation and large specific surface area. The NOx conversion was sensitive to temperature but nearly insensitive to NH3. The catalyst showed strong adaptability to NOx concentration with activity above 80% in the range of 615 1640 mg.m-3. Within the range of 720-8640 h continuous operation, the NOx conversion dropped at a rate of about 1% reduction per 600 h.
文摘We investigated the structural evolution and elecfronic properties of ConC3-/0 and ConC4-/0 (n=1-4) clusters by using mass-selected photoelectron spectroscopy and density functional theory calculations. The adiabatic and vertical detachment energies of CO1-4C3- and COl-4C4- were obtained from their photoelectron spectra. By comparing the theoretical results with the experimental data, the global minimum structures were determined. The results indicate that the carbon atoms of ConC3-/0 and ConC4-/0 (n=1-4) are separated from each other gradually with increasing number of cobalt atoms but a C2 unit still remains at n=4. It is interesting that the Co2C3- and Co2C4- anions have planar structures whereas the neutral Co2C3 and Co2C4 have linear structures with the Co atoms at two ends. The Co3C3- anion has a planar structure with a Co2C2 four-membered ring and a Co3C four-membered ring sharing a Co-Co bond, while the neutral Co3C3 is a three-dimensional structure with a C2 unit and a C atom connecting to two faces of the Co3 triangle.
基金Supported by the National Natural Science Foundation of China (20836006), the National Basic Research Program (2009CB623405), the Science & Technology Pillar Program of Tianjin (10ZCKFSH01700), the Programme of Introducing Talents of Discipline to Universities (B06006), and the Cheung Kong Scholar Program for Innovative Teams of the Ministry of Education (IRT0641).
文摘Fixed carrier membrane exhibits attractive CO2 permeance and selectivity due to its transport mechanism of reaction selectivity (facilitated transport). However, its performance needs improvement to meet cost targets for CO2 capture. This study attempts to develop membranes with multiple permselective mechanisms in order to enhance CO2 separation performance of fixed carder membrane. In this study, a novel membrane with multiplepermselective mechanisms of solubility selectivity and reaction selectivity was developed by incorporating CO2-selective adsorptive silica nanoparticles in situ into the tertiary amine containing polyamide membrane formed by interfacial polymerization (IP). Various techniques were employed to characterize the polyamide and polyam-ide-silica composite membranes. The TGA result shows that nanocomposite membranes exhlbit superior-thermal stability than pure polyamide membranes. In addition, gas permeation experiments show that both nanocomposite membranes have larger CO2 permeance than pure polyamide membranes. The enhanced CO2/N2 separation performance for nanocomposite membranes is mainly due to the thin film thickness, and multiple permselective mechanisms of solubility selectivity and reaction selectivity.
基金Projects(90820302,60805027)supported by the National Natural Science Foundation of ChinaProject(200805330005)supported by the Research Fund for the Doctoral Program of Higher Education,ChinaProject(2009FJ4030)supported by Academician Foundation of Hunan Province,China
文摘Multi-target tracking(MTT) is a research hotspot of wireless sensor networks at present.A self-organized dynamic cluster task allocation scheme is used to implement collaborative task allocation for MTT in WSN and a special cluster member(CM) node selection method is put forward in the scheme.An energy efficiency model was proposed under consideration of both energy consumption and remaining energy balance in the network.A tracking accuracy model based on area-sum principle was also presented through analyzing the localization accuracy of triangulation.Then,the two models mentioned above were combined to establish dynamic cluster member selection model for MTT where a comprehensive performance index function was designed to guide the CM node selection.This selection was fulfilled using genetic algorithm.Simulation results show that this method keeps both energy efficiency and tracking quality in optimal state,and also indicate the validity of genetic algorithm in implementing CM node selection.
文摘C1 chemistry is the essence of coal chemistry and natural gas chemistry. Catalytic methods to efficiently convert C1 molecules into fuels and chemicals have been extensively studied. Syngas(CO +H_2) conversion is the most important industrial reaction system in C1 chemistry, and Fe and Co catalysts, two major industrial catalysts, have been the focus of fundamental research and industrial application. In the last decade, considerable research efforts have been devoted to discoveries concerning catalyst structure and increasing market demands for olefins and oxygenates. Since the development of efficient catalysts would strongly benefit from catalyst design and the establishment of a new reaction system, this review comprehensively overviews syngas conversion in three main reactions, highlights the advances recently made and the challenges that remain open, and will stimulate future research activities. The first part of the review summarizes the breakthroughs in Fischer-Tropsch synthesis regarding the optimization of activity and stability, determination of the active phase, and mechanistic studies. The second part overviews the modulation of catalytic structure and product selectivity for Fischer-Tropsch to olefins(FTO). Catalysts designed to produce higher alcohols, as well as to tune product selectivity in C1 chemistry, are described in the third section. Finally, present challenges in syngas conversion are proposed, and the solutions and prospects are discussed from the viewpoint of fundamental research and practical application. This review summarizes the latest advances in the design, preparation, and application of Fe/Co-based catalysts toward syngas conversion and presents the challenges and future directions in producing value-added fuels.
基金Supported by the National High Technology Research and Development Programme of China (No. 2007AA01Z221, 2009AA01Z246) and the National Natural Science Foundation of China (No. 60832009).
文摘In order to resolve the relay selection problem in wireless mobile relay networks (WMRNs), a novel balanced energy-efficient mobile relay selection scheme is proposed in this paper. Compared with traditional counter-based algorithm, distance and energy consumption are considered from network respect to provide a better network lifetime performance in the proposed scheme. Also, it performs well when nodes move freely at high speed. A random assessment delay (RAD) mechanism is added to avoid collisions and improve transmission efficiency. Simulation results reveal that, the proposed scheme has advantages in prolonging network lifetime, balancing energy compared with existing counter-based scheme. consumption and reducing the total energy consumption
文摘A method to select solvent for extractive distillation is proposed by UNIFAC group contribution. Solventselectivity can be divided into two parts: the partial combinatorial solvent selectivity and the partial residual solventselectivity. The properties of partial combinatorial and residual solvent selectivity are demonstrated. In most cases,the partial residual solvent selectivity is predominant. The candidate groups of solvent can be selected by groupinteraction parameter using UNIFAC group interaction parameter table as a guide.
基金Project supported by the Ganpo 555 Program for Leading Talents of Jiangxi Province,China
文摘Graphene/Inconel 718 composites were innovatively synthesized through selective laser melting,and the mechanical and tribological performances of the grapheme-reinforced Inconel 718 matrix composites were evaluated.The composite microstructures were characterized by XRD,SEM and Raman spectroscopy.The results show that selective laser melting is a viable method to fabricate Inconel 718 matrix composite and the addition of graphene nanoplatelets leads to a significant strengthening of Inconel 718 alloy,as well as the improvement of tribological performance.The yield strength and ultimate tensile strength of 1.0%graphene/Inconel 718 composites(mass fraction)are 42%and 53%higher than those of pure material,and the friction coefficient and wear rate are 22.4%and 66.8%lower than those of pure material.The decrease of fraction coefficient and wear rate is attributed to the improved hardness of composites and the formation of graphene nanoplatelet protective layer on the worn surfaces.
基金supported by the National Natural Science Foundation of China (21507130)the Chongqing Science and Technology Commission (cstc2016jcyjA 0070,cstc2014pt-gc20002,cstc2014yykfC 20003,cstckjcxljrc13)the Open Project Program of Chongqing Key Laboratory of Ca-talysis and Functional Organic Molecules from Chongqing Technology and Business University (1456029)~~
文摘To investigate how the physicochemical properties and NH3‐selective catalytic reduction(NH3‐SCR)performance of supported ceria‐based catalysts are influenced as a function of support type,a series of CeO2/SiO2,CeO2/γ‐Al2O3,CeO2/ZrO2,and CeO2/TiO2catalysts were prepared.The physicochemical properties were probed by means of X‐ray diffraction,Raman spectroscopy,Brunauer‐Emmett‐Teller surface area measurements,X‐ray photoelectron spectroscopy,H2‐temperature programmed reduction,and NH3‐temperature programmed desorption.Furthermore,the supported ceria‐based catalysts'catalytic performance and H2O+SO2tolerance were evaluated by the NH3‐SCR model reaction.The results indicate that out of the supported ceria‐based catalysts studied,the CeO2/γ‐Al2O3catalyst exhibits the highest catalytic activity as a result of having a high relative Ce3+/Ce4+ratio,optimum reduction behavior,and the largest total acid site concentration.Finally,the CeO2/γ‐Al2O3catalyst also presents excellent H2O+SO2tolerance during the NH3‐SCR process.
基金supported by NSFC under grant No. 61322111 and No. 61401249the National Basic Research Program of China (973 Program) No. 2013CB336600+1 种基金Specialized Research Fund for the Doctoral Program of Higher Education (SRFDP) under Grant No. 20130002120001Chuanxin Funding, and Beijing nova program No.Z121101002512051
文摘With the explosive growth and need for high-speed wireless communications, more and more energy is consumed to support the required quality of service. Therefore, energy efficient or green communication has become a very hot topic under the ground of limited energy resource and environmentally friendly transmission schemes. MIMO technique is capable of reducing the transmission power thanks to its diversity and multiplexing gain. Moreover, antenna selection(AS) is an alternative to extract many of the benefits in MIMO systems with a reduced cost of complexity and power. Although many works including several survey papers have investigated AS in MIMO systems, the goal of these works is only the capacity maximization or error rate minimization, which fails to guarantee the optimality of the energy efficiency in MIMO systems. In this paper, we overview the state of the art in the AS schemes in energy efficient MIMO systems, the goal of which is to optimize the energy efficiency of the whole system. Specifically, we introduce energy efficient AS in point-to-point MIMO, cooperative MIMO, multiuser MIMO and largescale MIMO systems, respectively. Several challenging and practical issues in this area are also addressed.
基金Supported by the National Natural Science Foundation of China(No.61379057,61073186,61309001,61379110,61103202)Doctoral Fund of Ministry of Education of China(No.20120162130008)the National Basic Research Program of China(973 Program)(No.2014CB046305)
文摘Opportunistic networks are random networks and do not communicate with each other among respective communication areas.This situation leads to great difficulty in message transfer.This paper proposes a reducing energy consumption optimal selection of path transmission(OSPT) routing algorithm in opportunistic networks.This algorithm designs a dynamic random network topology,creates a dynamic link,and realizes an optimized selected path.This algorithm solves a problem that nodes are unable to deliver messages for a long time in opportunistic networks.According to the simulation experiment,OSPT improves deliver ratio,and reduces energy consumption,cache time and transmission delay compared with the Epidemic Algorithm and Spray and Wait Algorithm in opportunistic networks.
文摘In this paper, we proposed a new approach for face recognition with robust to illumination variation. The improved performance to various lights in recognition is obtained by a novel combination of multicondition relighting and optimal feature selection. Multi-condition relighting provides a "coarse" compensation for the variable illumination, and then the optimal feature selection further refines the compensation, and additionally offers the robustness to shadow and highlight, by deemphasizing the local mismatches caused by imprecise lighting compensation, shadow or highlight on recognition. For evaluation, two databases with various illumination mismatches have been used. The results have demonstrated the improved robustness of the new methods.
基金Project(61271441)supported by the National Natural Science Foundation of ChinaProject(NCET-10-0895)supported by the Program for New Century Excellent Talents in Universities of China
文摘The primary goal of this work is to characterize the impact of weighting selection strategy and multistatic geometry on the multistatic radar performance. With the relationship between the multistatic ambiguity function (AF) and the multistatie Cram6r-Rao lower bound (CRLB), the problem of calculating the multistatic AF and the multistatic CRLB as a performance metric for multistatic radar system is studied. Exactly, based on the proper selection of the system parameters, the multistatic radar performance can be significantly improved. The simulation results illustrate that the multistatic AF and the multistatic CRLB can serve as guidelines for future multistatic fusion rule development and multistatic radars deployment.