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《分析化学》 SCIE EI CAS CSCD 北大核心 2014年第10期1549-1549,共1页
近年来,水溶性共轭聚合物( WSCPs)以其独特的光电性质,在核酸、蛋白质和离子检测方面的研究备受关注。相对于单个小分子而言,共轭聚合物具有多个吸收单元,因此具有很强的吸光能力,在参与能量转移的过程中,可大幅放大响应信号,... 近年来,水溶性共轭聚合物( WSCPs)以其独特的光电性质,在核酸、蛋白质和离子检测方面的研究备受关注。相对于单个小分子而言,共轭聚合物具有多个吸收单元,因此具有很强的吸光能力,在参与能量转移的过程中,可大幅放大响应信号,提高检测灵敏度。荧光共振能量转移( FRET)作为常用的技术手段,在生物大分子相互作用分析、细胞生理研究、免疫分析等方面有着广泛应用。 展开更多
关键词 水溶性共轭聚合物 光电性质 能量给体 分析化学
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Lagrangian view of time irreversibility of fluid turbulence
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作者 HaiTao Xu 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS CSCD 2016年第1期7-15,共9页
A turbulent flow is maintained by an external supply of kinetic gradients. The scale at which energy is supplied greatly differs energy, which is eventually dissipated into heat at steep velocity from the scale at whi... A turbulent flow is maintained by an external supply of kinetic gradients. The scale at which energy is supplied greatly differs energy, which is eventually dissipated into heat at steep velocity from the scale at which energy is dissipated, the more so as the turbulent intensity (the Reynolds number) is larger. The resulting energy flux over the range of scales, intermediate between energy injection and dissipation, acts as a source of time irreversibility. As it is now possible to follow accurately fluid particles in a turbulent flow field, both from laboratory experiments and from numerical simulations, a natural question arises: how do we detect time irreversibility from these Lagrangian data? Here we discuss recent results concerning this problem. For Lagrangian statistics involving more than one fluid particle, the distance between fluid particles introduces an intrinsic length scale into the problem. The evolution of quantities dependent on the relative motion between these fluid particles, including the kinetic energy in the relative motion, or the configuration of an initially isotropic structure can be related to the equal-time correlation functions of the velocity field, and is therefore sensitive to the energy flux through scales, hence to the irreversibility of the flow. In contrast, for single- particle Lagrangian statistics, the most often studied velocity structure functions cannot distinguish the "arrow of time". Recent observations from experimental and numerical simulation data, however, show that the change of kinetic energy following the particle motion, is sensitive to time-reversal. We end the survey with a brief discussion of the implication of this line of work. 展开更多
关键词 fluid turbulence time irreversibility energy cascade Lagrangian description
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