The NiAl alloys modified by reactive element(RE),dysprosium(Dy),were produced by arc melting.The microstructures of the modified alloys were investigated by field emission-scanning electron microscope(FE-SEM)equipped ...The NiAl alloys modified by reactive element(RE),dysprosium(Dy),were produced by arc melting.The microstructures of the modified alloys were investigated by field emission-scanning electron microscope(FE-SEM)equipped with energy dispersive spectroscope(EDS)and back scatter detector.Cyclic oxidation tests at 1 200℃were conducted to assess the cyclic oxidation performance of the alloys.The Dy dopant prevents the surface rumpling of the oxide scale and the formation of cavities beneath the oxide scale.The pegs consisting of Dy-rich oxide inclusion core and an outer alumina sheath develop deeply in the alloy and improve the oxide scale adhesion.0.05%-0.1%(molar fraction)Dy dramatically improves the cyclic oxidation resistance of the NiAl alloy. Too high concentration of Dy is deleterious because of the fast oxidation rate caused by severe internal oxidation.展开更多
Laboratory tests were conducted to study the effects of curing time, cement ratio and seawater pressure on cement soil deterioration formed at simulative marine soft clay sites. Deterioration depth was determined on t...Laboratory tests were conducted to study the effects of curing time, cement ratio and seawater pressure on cement soil deterioration formed at simulative marine soft clay sites. Deterioration depth was determined on the basis of characteristics of penetration resistance and penetration depth curves, and the deterioration depth of cement soil with the cement ratio of 7%, reached 31.8 mm after 720 d. Results of research indicated that deterioration extended quickly under seawater environment and the deterioration depth increased with the prolonging curing time. In addition, the water pressure could speed up deterioration. With the increase of cement content, the strength of cement soil increased obviously. At the same time, the deterioration depth decreased significantly. The concentration of calcium ion in the cement stabilized soil increased with the increase of depth, while that of magnesium ion gradually decreased. The variations were consistent with energy dispersive spectrometer(EDS)analysis results, and the calcium concentration with depth was in a good consistency with strength distribution at long term. The results showed that the deterioration became more serious with the curing time, and it was related to calcium leaching.展开更多
Tribological characteristics and self-repairing effect of hydroxy-magnesium silicate (HMS) dispersed in lubricant oil on steel-to-steel friction pairs with various surface roughness were analyzed.The friction-reductio...Tribological characteristics and self-repairing effect of hydroxy-magnesium silicate (HMS) dispersed in lubricant oil on steel-to-steel friction pairs with various surface roughness were analyzed.The friction-reduction,anti-wear and self-repairing performance of various surface roughness friction pairs were examined by friction testing machine.An operation comparison was made between SJ10W-40 lubricant with and without HMS.The surface morphology and elementary composition of the grinding cracks were analyzed by scanning electron microscope (SEM) and energy dispersive spectrometer (EDS).The results show that the lubrication state changes from boundary lubrication into mixed lubrication after operation in lubricant with HMS.The friction-reduction,anti-wear and self-repairing performance of the friction pairs with various surface roughness are distinctly different.There is a repairing film whose material is different from substrate material on the grinding cracks.In addition,Si,Mg,O,Al and other elements are deposited on the repairing film which contains nanocrystals of these elements.And HMS self-repairing material possesses superior performance of friction-reduction,anti-wear and self-repairing effects.展开更多
The ignition-proof mechanism of ZM5 magnesium alloy added with 0.1% （mass fraction） rare earth （RE） was investigated. The oxide scales and substrates were characterized by scanning electronic microscope （SEM）, X...The ignition-proof mechanism of ZM5 magnesium alloy added with 0.1% （mass fraction） rare earth （RE） was investigated. The oxide scales and substrates were characterized by scanning electronic microscope （SEM）, X-ray diffraction （XRD）, energy dispersive spectrometer （EDS） and tensile test. And an oxidation model of ZM5 alloy with RE was established. The results show that the ignition temperature of ZM5 alloy is particularly elevated from 654 to 823 ℃, the microstructure is refined, and the tensile strength is slightly improved from 168.2 to 174.6 MPa by adding 0.1% RE. A double-layer oxidation film formed on the alloy surface under high temperature mainly consists of MgO, RE203 and A1203, which is 2.5-3.5 μm in thickness. It is found that the forming of protective oxidation film on the thermodynamics is attributed to RE elements congregating on the surface of molten Mg alloy.展开更多
基金Projects(50731001,50771009)supported by the National Natural Science Foundation of ChinaProject(PCSIRT/IRT 0512)supported bythe Program for Changjiang Scholars and Innovative Research Team in Chinese University
文摘The NiAl alloys modified by reactive element(RE),dysprosium(Dy),were produced by arc melting.The microstructures of the modified alloys were investigated by field emission-scanning electron microscope(FE-SEM)equipped with energy dispersive spectroscope(EDS)and back scatter detector.Cyclic oxidation tests at 1 200℃were conducted to assess the cyclic oxidation performance of the alloys.The Dy dopant prevents the surface rumpling of the oxide scale and the formation of cavities beneath the oxide scale.The pegs consisting of Dy-rich oxide inclusion core and an outer alumina sheath develop deeply in the alloy and improve the oxide scale adhesion.0.05%-0.1%(molar fraction)Dy dramatically improves the cyclic oxidation resistance of the NiAl alloy. Too high concentration of Dy is deleterious because of the fast oxidation rate caused by severe internal oxidation.
基金Supported by the National Natural Science Foundation of China(No.50779062)
文摘Laboratory tests were conducted to study the effects of curing time, cement ratio and seawater pressure on cement soil deterioration formed at simulative marine soft clay sites. Deterioration depth was determined on the basis of characteristics of penetration resistance and penetration depth curves, and the deterioration depth of cement soil with the cement ratio of 7%, reached 31.8 mm after 720 d. Results of research indicated that deterioration extended quickly under seawater environment and the deterioration depth increased with the prolonging curing time. In addition, the water pressure could speed up deterioration. With the increase of cement content, the strength of cement soil increased obviously. At the same time, the deterioration depth decreased significantly. The concentration of calcium ion in the cement stabilized soil increased with the increase of depth, while that of magnesium ion gradually decreased. The variations were consistent with energy dispersive spectrometer(EDS)analysis results, and the calcium concentration with depth was in a good consistency with strength distribution at long term. The results showed that the deterioration became more serious with the curing time, and it was related to calcium leaching.
基金Projects(50735006,50904072) supported by the National Natural Science Foundation of ChinaProject(2007CB607601) supported by the National Basic Research Program of China
文摘Tribological characteristics and self-repairing effect of hydroxy-magnesium silicate (HMS) dispersed in lubricant oil on steel-to-steel friction pairs with various surface roughness were analyzed.The friction-reduction,anti-wear and self-repairing performance of various surface roughness friction pairs were examined by friction testing machine.An operation comparison was made between SJ10W-40 lubricant with and without HMS.The surface morphology and elementary composition of the grinding cracks were analyzed by scanning electron microscope (SEM) and energy dispersive spectrometer (EDS).The results show that the lubrication state changes from boundary lubrication into mixed lubrication after operation in lubricant with HMS.The friction-reduction,anti-wear and self-repairing performance of the friction pairs with various surface roughness are distinctly different.There is a repairing film whose material is different from substrate material on the grinding cracks.In addition,Si,Mg,O,Al and other elements are deposited on the repairing film which contains nanocrystals of these elements.And HMS self-repairing material possesses superior performance of friction-reduction,anti-wear and self-repairing effects.
基金Project(2004BB8429) supported by Chongqing Municipal Science and Technology Commission, China
文摘The ignition-proof mechanism of ZM5 magnesium alloy added with 0.1% （mass fraction） rare earth （RE） was investigated. The oxide scales and substrates were characterized by scanning electronic microscope （SEM）, X-ray diffraction （XRD）, energy dispersive spectrometer （EDS） and tensile test. And an oxidation model of ZM5 alloy with RE was established. The results show that the ignition temperature of ZM5 alloy is particularly elevated from 654 to 823 ℃, the microstructure is refined, and the tensile strength is slightly improved from 168.2 to 174.6 MPa by adding 0.1% RE. A double-layer oxidation film formed on the alloy surface under high temperature mainly consists of MgO, RE203 and A1203, which is 2.5-3.5 μm in thickness. It is found that the forming of protective oxidation film on the thermodynamics is attributed to RE elements congregating on the surface of molten Mg alloy.
