脂塑木复合材料制备协同处理废有机树脂工艺研究

本项目在生产脂塑木复合材料的同时,协同处理废弃线路板非金属有机树脂。生产工艺为:偶联剂(聚乙烯接枝马来酸酐)用量4 kg,润滑剂(PE蜡)添加量2 kg,HDPE用量20 kg,HDPE新旧料比m(新料):m(回收料)=1:1,树脂粉粒径0.180~0.250 mm,脂木比m(树脂粉):m(木粉)=2:5(树脂粉20 kg,木粉50 kg),造粒温度195℃,挤出温度185℃,生产出来的脂塑木复合性能板最小集中载荷保持在3400 N以上,满足木塑地板使用标准,处理废有机树脂的同时产生经济效益。

探讨炭纤维增强脂基复合材料热压罐成型模具设计知识管理框架

热压成型方法是塑料加工也中较为简单且普遍的一种加工方法，主要是利用加热加工模具之后，注入试料，以压力将模型固定于加热板，控制试料之熔融温度和时间，从而实现融化之后硬化、冷却，最后取出模型即可。这种方法凭借着自身的诸多优势在大尺寸高质量增强树脂复合材料制件的施工中得到了广泛的应用。本文通过对热压罐生产过程中应该注意的因素进行分析，结合主要工艺装备框架式模具设计的根本目标，从而制定出相应的脂基复合材料热压罐成型模具设计的知识管理框架。

泡沫铝复合材料的动态压缩试验研究和吸能分析

随着武器科技的发展,对吸能防护材料要求越来越高。采用分离式Hopkinson压杆(SHPB)试验技术对泡沫铝,铝-脂-胶复合材料,填充环氧树脂的泡沫铝冲击压缩性能进行研究,得到3种材料的应力-应变曲线,并对其进行吸能性能分析。结果表明,铝-脂-胶复合材料具有非常好的吸能特性。铝-脂-胶复合材料可作为一种新型的高性能吸能防护材料。

废线路板树脂粉末的无害化处理与资源化利用

废线路板是一类重要的电器电子废弃物,废线路板树脂粉末是废线路板拆卸分选处理后的主要产物,废线路板树脂粉末的无害化处理与资源化利用,符合环境保护和可持续发展的要求。本文介绍了废线路板树脂粉末的主要产生来源和产生量,对现阶段废线路板树脂粉末的处理和资源化技术作了简单评述,着重介绍了废线路板树脂粉末制备脂塑复合材料的主要机理和相关技术,指出了该技术在废线路板树脂粉末资源化方面的技术和产业优势。在此基础上,分析了未来废线路板树脂粉末资源化利用技术的发展趋势。

Research on High-Velocity Impact Damage Monitoring Method of CFRP Based on Guided Wave

Carbon fiber-reinforced polymer(CFRP)is widely used in aerospace applications.This kind of material may face the threat of high-velocity impact in the process of dedicated service,and the relevant research mainly considers the impact resistance of the material,and lacks the high-velocity impact damage monitoring research of CFRP.To solve this problem,a real high-velocity impact damage experiment and structural health monitoring(SHM)method of CFRP plate based on piezoelectric guided wave is proposed.The results show that CFRP has obvious perforation damage and fiber breakage when high-velocity impact occurs.It is also proved that guided wave SHM technology can be effectively used in the monitoring of such damage,and the damage can be reflected by quantifying the signal changes and damage index(DI).It provides a reference for further research on guided wave structure monitoring of high/hyper-velocity impact damage of CFRP.

Cardo poly (ether sulfone) toughened E51/DETDA epoxy resin and its carbon fiber composites

A toughener that can effectively improve the interlaminar toughness in carbon fiber composites is crucial for various applications.We investigated,the toughening effects of phenolphthalein-based cardo poly(ether sulfone)(PES-C)on E51/DETDA epoxy and its carbon fiber composites(CFCs).Scanning electron microscopy showed that the phase structures of PES-C/epoxy blends change from island(of dispersed phase)structures to bi-continuous structures(of the matrix)as the PES-C content increased,which is associated with reaction-induced phase separation.After adding 15 phr PES-C,the glass transition temperature(T_(g))of the blends increased by 51.5℃,and the flexural strength,impact strength and fracture toughness of the blends were improved by 41.1%,186.2%and 42.7%,respectively.These improvements could be attributed to the phase separation structure of the PES-C/epoxy sys-tem.A PES-C film was used to improve the mode-II fracture toughness(G_(IIC))of CFCs.The G_(IIC) value of the 7μm PES-C film toughened laminate was improved by 80.3%compared to that of the control laminate.The increase in G_(IIC) was attributed to cohesive failure and plastic deformation in the interleaving region.

城市规划中的井盖多样化及井盖出现的病害

当今城市建设中,井盖的多样化也随着社会的发展而增加。同时井盖的报废和破损率也日益增加,井盖的病害原因很多,井盖的分类多样化也更加复杂以及井盖材料包括新型材料的出现日益繁多。本文将从当今井盖出现病害现象和井盖的多样化进行说明。

RELAXATION BEHAVIOUR OF GFRP UNIDIRECTIONAL LAMINATES

In this paper two set of GFRP specimens are manufactured and tested to investigate the relaxation behaviour under cyclic loading in the longitudinal and transversel direction. The relaxation of GFRP unidirectional laminates is evident for both cyclic loadings. Under longitudinal cyclic loading the relaxation is dependent on the number of loading cycles. Under transverse loading the relaxation depends on the loading cycles as well as the time of loading. Two expressions are set up to describe the relaxation for the longitudinal and transverse loading, and the predictions agree well with the experimental data.

A Self-Referenced Fiber-Optic Refractive Index Sensor for Cure Monitoring of Epoxy Composites

A self referenced fiber optic refractive index sensor is developed to measure quantitative cure extent of epoxy. In case the sensor is applied to in situ cure monitoring of epoxy composites, each sensor embedded in different location within the structure is self referenced and can be normalized to a common scale. Therefore, the real time comparative of each sensor’s output becomes possible and variations in the extent of cure at different locations can be monitored. The developed sensor was used to monitor the isothermal cure of an epoxy system. The output of the sensor was compared with the results of the differential scanning calorimetry (DSC). The self referencing function of the sensor is confirmed.

Synthesis of magnetically modified palygorskite composite for immobilization of Candida sp. 99–125 lipase via adsorption

Magnetically modified palygorskite composites were synthesized with γ-Fe2O3 dispersing on the external surface of clay mineral. The magnetic clay was characterized with Fourier transform infrared, X-ray diffrac- tion, transmission electron microscopy, and vibrating sample magnetometer. Candida sp. 99-125 lipase was immobilized on magnetic palygorskite composites by physical adsorption with enzyme loading of 41.5 mg· g^-1 support and enzyme activity of 2631.6 U· （g support）^-1. The immobilized lipase exhibit better thermal and broader pH stability and excellent reusabilitV compared with free lipase.

Synergistic regulation of current-carrying wear performance of resin matrix carbon brush composites with tungsten copper composite powder

Resin matrix carbon brush composites(RMCBCs)are critical materials for high-powered electric tools.However,effectively improving their wear resistance and heat dissipation remains a challenge.RMCBCs prepared with flake graphite powders that were evenly loaded with tungsten copper composite powder(RMCBCs-W@Cu)exhibited a low wear rate of 1.63 mm^(3)/h,exhibiting 48.6%reduction in the wear rate relative to RCMBCs without additives(RMCBCs-0).In addition,RMCBCs-W@Cu achieved a low friction coefficient of 0.243 and low electric spark grade.These findings indicate that tungsten copper composite powders provide particle reinforcement and generate a gradation effect for the epoxy resin(i.e.,connecting phase)in RMCBCs,which weakens the wear of RMCBCs caused by fatigue under a cyclic current-carrying wear.

An Investigation of Stimulating the Autoclave Curing Process of Resin Matrix/Fiber Reinforced Composite Material, Ⅰ: Process model

A mathematical model is made which describes the curing process of composites constructed from continuous fiber-reinforced, thermosetting resin matrix prepreg materials, and the consolidation of the composite is developed. The model provides the variation of temperature distribution, the cure reaction process in the resin, the resin flow and fibers stress inside the composite, and the void variation and the residual stress distribution. It can be used to illustrate the mechanism of curing process and optimize the cure cycle of composite material in order to ensure the quality of a product.

New composite grouting materials:Modified urea-formaldehyde resin with cement

A new composite two component grout comprised of modified urea-formaldehyde resin and cement was formulated to take account of the advantages and disadvantages of both the cement grout and the chem- ical grout. The new grout is designed for water blocking by reinforcing as well as seepage control by bore grouting. The A component consists of a modified urea-formaldehyde resin A component, some cement, and some water. The B component is an alkaline coagulant. An orthogonal test of four factors at three lev- els showed that gel time increased with increased water content and with urea-formaldehyde resin con- tent. Gel time decreased at increased levels of alkaline coagulant. The A component of this new composite grout is stable over time. A mixed cross-over test showed that as the volume ratio of A to B increases the gel time falls at first but then increases. The solid strength decreases with increasing levels of the B com- ponent. The solid strength increases over time and becomes stable by the 28th day after mixing. The vis- cosity increases with increasing levels of resin A component. The increase is exponential and may be fit to： μ = 8.162e0.0286x.

Failure Analysis in Graphite Epoxy Composite Laminates

The present analysis was performed to obtain bearing strength for pinned joints in uni-directional graphite epoxy composite laminates using characteristic curve model. The characteristic dimensions used to determine the characteristic curve were evaluated using a two-dimensional finite element model that was developed in ANSYS14.5 Software. Also, two-dimensional finite element stress analysis was developed to determine the stress distribution needed to evaluate the failure. Tsai-Wu failure criterion was used in the analysis with the characteristic curve to predict bearing strength. The results of the analysis showed good agreement with experimental data.

Characteristics of Cyanate Ester and Fluorenyl Epoxy-Based Polymer-Ceramic Composites

In the field of highly integrated printed circuit board （PCB）, the heat resistant substrate with low water absorption is very important material. To get the resin composition for the high functional substrate material with low moisture absorption and high glass transition temperature （Tg） simultaneously, a fluorenyl ＂Cardo＂ epoxy was incorporated into novolac cyanate ester resin. As an optimum curing agent for the fiuorenyl epoxy, methyl nadic anhydride （MNA） was selected. Silica powders as fillers were added into the resin composition. The partial replacement of the cyanate ester resin with the fluorenyl epoxy could reduce the moisture absorption with keeping high glass transition temperature over 300 ℃. The laminate, which was fabricated from prepregs made with 40 wt% silica-filled resin composition and glass fabric, showed high Tg of 317 ℃ and low moisture absorption of 0.57%.

A comparison of soft magnetic composites designed from different ferromagnetic powders and phenolic resins

Soft magnetic composites （SMCs） were prepared from three different ferromagnetic powder particles： iron powder ASC 100.29, spherical FeSi particles and vitroperm （Fe73CulNb3Si16B7） flakes. Two types of hybrid organic-inorganic phenolic resins modified with either silica nanoparticles or boron were used to design a thin insulating layer perfect- ly covering the ferromagnetic particles. Fourier transform infrared （FTIR） spectrometry confirmed an incorporation of silica or boron into the polymer matrix, which manifested itself through an improved thermal stability of the hybrid resins verified by thermogravimetric-differential scanning calorimetry （TG-DSC） analysis. The core-shell particles prepared from the ferromagnetic powder particles and the modified hybrid resins were further compacted to the cylindrical and toroidal shapes for the mechanical, electrical and magnetic testing. A uniform distribution of the resin between the ferromagnetic particles was evidenced by scanning electron microscope （SEM） analysis, which was also reflected in a rather high value of the electrical resistivity. A low porosity and extraordinary high values of mechanical hardness and flexural strength were found in SMC consisting of the iron powder and phenolic resin modified with boron. The coercive fields of the prepared samples were comparable with the commercial SMCs.

Resin Matrix/Fiber Reinforced Composite Material, Ⅱ: Method of Solution and Computer Code

According to a mathematical model which describes the curing process of composites constructed from continuous fiber-reinforced, thermosetting resin matrix prepreg materials, and the consolidation of the composites, the solution method to the model is made and a computer code is developed, which for flat-plate composites cured by a specified cure cycle, provides the variation of temperature distribution, the cure reaction process in the resin, the resin flow and fibers stress inside the composite, the void variation and the residual stress distribution.

Natural Composite Material from Steelwool or Luffa cylindrica under Natural, Rigid and Flexible Resin

In a changing world with a high interest in new ecomaterials, natural fibers such as the steelwool or Luffa cylindriea appear in new presentations and mixing with other materials to develop better opportunities to replace synthetic fibers. This work presents a research on the use of steelwool fiber for composite materials, on the basis of the physical properties, that generate conditions of mixing with three binders （matrix） natural： the rosin, artificial hard： polyurethane resin and artificial flexible： flexible twin resin （epoxy） and finally a polyester resin to make a comparison with other major resins. A testing of compression and tension is carried out to the materials analyzed, obtaining three types of composite materials by the above mentioned binders and three proposed presentations of fiber （complete, tissue and ground）. The test tube in tension with polyester resin presented a high rigidity and a percentage of deformation of 14%, resulting in less distortion than the woven with resin polyurethane with 12% of deformation. The presentation with resin polyurethane presented greater resistance to compression, because the resin acts as a sponge absorbing the energy of charge and the join of particles is larger than the other presentations generating greater cohesion among them and avoiding its rupture easily for a load of 2,000 kg. The presentation that is least resisted was the woven in two resins in the stage of energy absorption of load where polyurethane is 800 kg and the flexible twin is 850 kg, because the form of woven fiber distribution creates spaces where there are more resin than fiber.

Melamine/Stearic Acid Composite Nanowires and Vesicles with an Intercalated Nanostructure Prepared through NCCM Method

A solvent-non-solvent method invented in our laboratory for preparing non-covalently con- nected micelles （NCCM） was used to intercalate melamine （MA） molecules into stearic acid （SA） bilayers to form tile composite nanoparticles with an intercalated nanostructure in which a melamine bilayer is sandwiched between two stearic acid bilayers, NCCM method helps to sufficiently mix the two components in nanospace and meanwhile inhibits the strong tendency of self-crystallization of MA, leading to the intercalation. Although the nanopar- ticles have a regular inner structure, the primary MA/SA nanoparticles have an irregular morphology. Regular nanoparticles were obtained through annealing the suspension of the primary nanoparticles. Through annealing at different temperatures, the MA/SA compos- ite nanowires and vesicles with an intercalated structure were prepared respectively. It is proposed that the morphological change results from the change in the intercalated structure.

Experimental Plans Method to Formulate a Resin Concrete

This work is an experimental approach based on the method of experimental plans to determine a specific formulation of a resin concrete. In this study, an unsaturated polyester resin （thermosetting resin） was used with two types of mineral fillers （dune sand and crushed sand）, and with the addition of a marble powder to ensure the continuity of the particle size mixing granular. The lack of the methods for developing this kind of composite materials, had led us to perform an initial experimental approach to define the experimental field, that is to say determine the mass proportions of the various compounds of mixture of our study. In the second approach, we have established and implemented fully experimental plans with three factors namely： factor （1）： sand, factor （2）： resin, factor （3）： marble powder. Test results being the density of polymer concrete and the mechanical resistances. Finally, multi-parameters regression allowed us to determine predictive mathematical models for the different responses of the study. Tests results showed that at three days we got a tensile strength of about 16 MPa with a resin concrete density of 1.9 g/cm3. This shows the advantages of this material.