Room temperature and high temperature microstructural and mechanical properties of arc melted Ni Al-28Cr-6Mo eutectic alloys doped with 0.1% Fe, 0.2% Fe and 0.5% Fe(mole fraction) were investigated. The homogenization...Room temperature and high temperature microstructural and mechanical properties of arc melted Ni Al-28Cr-6Mo eutectic alloys doped with 0.1% Fe, 0.2% Fe and 0.5% Fe(mole fraction) were investigated. The homogenization heat treatment of the alloys was conducted at 1300℃ in Ar atmosphere. Microscopic analyses, hardness measurements, XRD measurements and compression tests were used to characterize the alloys. As-cast and homogenized alloys exhibit fine cellular eutectic structures with coarse intercellular eutectic structure. The increase in the content of Fe results in coarsening eutectic layers and the decrease in eutectic cells. All alloys have very high compressive stress and strain at room temperature. The addition of Fe has small negative impact on the strength and ductility of the alloys at room temperature. However, the addition of Fe increases the high temperature strength of the alloy. High temperature XRD patterns show that peaks shift to lower Bragg angles. This indicates that the lattice parameter of the alloys increases.展开更多
Morphology,distribution,composition,forming ability,structural stability and intrinsic mechanical properties of the intermetallic compounds(IMCs)formed in steel/aluminum laser welding were determined through scanning ...Morphology,distribution,composition,forming ability,structural stability and intrinsic mechanical properties of the intermetallic compounds(IMCs)formed in steel/aluminum laser welding were determined through scanning electron microscope,energy dispersive spectrometer,X-ray diffractometer and first-principles calculation.It was found that the mechanical properties of the joint are limited by the Fe−Al IMCs,whose brittleness is attributed to the orbital hybridization between Al(s),Al(p)and Fe(d).However,the joint properties are improved by adding interlayer,which is ascribed to some changes of electronic structure of the generated IMCs.The transition mechanism of IMCs changing from brittle to ductile is mainly due to the weak ability of interlayer elements to attract electrons.The mechanical properties of the joint are closely related to the ductility or brittleness of the IMCs.Moreover,the addition of Ti foil interlayer effectively improves the mechanical properties of the joints,which means that the experimental verification is in good agreement with the theoretical calculation predictions.展开更多
Metallic glasses(MGs)constitute an emerging class of advanced structural materials due to their excellent mechanical properties.However,brittle failure at room temperature and the resultant complicated fracture behavi...Metallic glasses(MGs)constitute an emerging class of advanced structural materials due to their excellent mechanical properties.However,brittle failure at room temperature and the resultant complicated fracture behavior greatly limit their wide engineering applications.Over the past decades,the deformation and fracture in ductile or brittle mode referring to material compositions,load conditions,sample size,etc.,have been widely studied,and significant progress has been made in understanding the failure behavior of MGs.Micromechanisms of fracture have been revealed involving shear banding,cavitation and the nature of the crack tip field.The ductile-to-brittle transition and inherent governing parameters have been found.To well describe and predict the failure behavior of MGs,failure criteria for ductile and brittle MGs have been established empirically or based on atomic interactions.In this paper,we provide a detailed review of the above advances and identify outstanding issues in the failure of MGs that need to be further clarified.展开更多
基金Project(RCJC20210706091948015) supported by the Science Fund for Distinguished Young Scholars in Shenzhen,ChinaProject(U2013603) supported by the National Natural Science Foundation of China。
基金Tubitak for their financial support under Contract No. 213M247
文摘Room temperature and high temperature microstructural and mechanical properties of arc melted Ni Al-28Cr-6Mo eutectic alloys doped with 0.1% Fe, 0.2% Fe and 0.5% Fe(mole fraction) were investigated. The homogenization heat treatment of the alloys was conducted at 1300℃ in Ar atmosphere. Microscopic analyses, hardness measurements, XRD measurements and compression tests were used to characterize the alloys. As-cast and homogenized alloys exhibit fine cellular eutectic structures with coarse intercellular eutectic structure. The increase in the content of Fe results in coarsening eutectic layers and the decrease in eutectic cells. All alloys have very high compressive stress and strain at room temperature. The addition of Fe has small negative impact on the strength and ductility of the alloys at room temperature. However, the addition of Fe increases the high temperature strength of the alloy. High temperature XRD patterns show that peaks shift to lower Bragg angles. This indicates that the lattice parameter of the alloys increases.
基金the National Natural Science Foundation of China(Nos.51674112,51774125).
文摘Morphology,distribution,composition,forming ability,structural stability and intrinsic mechanical properties of the intermetallic compounds(IMCs)formed in steel/aluminum laser welding were determined through scanning electron microscope,energy dispersive spectrometer,X-ray diffractometer and first-principles calculation.It was found that the mechanical properties of the joint are limited by the Fe−Al IMCs,whose brittleness is attributed to the orbital hybridization between Al(s),Al(p)and Fe(d).However,the joint properties are improved by adding interlayer,which is ascribed to some changes of electronic structure of the generated IMCs.The transition mechanism of IMCs changing from brittle to ductile is mainly due to the weak ability of interlayer elements to attract electrons.The mechanical properties of the joint are closely related to the ductility or brittleness of the IMCs.Moreover,the addition of Ti foil interlayer effectively improves the mechanical properties of the joints,which means that the experimental verification is in good agreement with the theoretical calculation predictions.
基金supported by the National Natural Science Foundation Basic Science Center Program for"Multiscale Problems in Nonlinear Mechanics"(Grant No.11988102)the National Natural Science Foundation of China(Grant Nos.11972346 and 11790292)+3 种基金the National Key Research and Development Program of China(Grant No.2017YFB0702003)the Strategic Priority Research Program(Grant Nos.XDB22040302 and XDB22040303)the Key Research Program of Frontier Sciences(Grant No.QYZDJSSW-JSC011)the Science Challenge Project(Grant No.TZ2018001).
文摘Metallic glasses(MGs)constitute an emerging class of advanced structural materials due to their excellent mechanical properties.However,brittle failure at room temperature and the resultant complicated fracture behavior greatly limit their wide engineering applications.Over the past decades,the deformation and fracture in ductile or brittle mode referring to material compositions,load conditions,sample size,etc.,have been widely studied,and significant progress has been made in understanding the failure behavior of MGs.Micromechanisms of fracture have been revealed involving shear banding,cavitation and the nature of the crack tip field.The ductile-to-brittle transition and inherent governing parameters have been found.To well describe and predict the failure behavior of MGs,failure criteria for ductile and brittle MGs have been established empirically or based on atomic interactions.In this paper,we provide a detailed review of the above advances and identify outstanding issues in the failure of MGs that need to be further clarified.
