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B2型Y基金属间化合物YX(X=Ag,Cu,In,Rh)延性预测 被引量:5
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作者 庄厚龙 彭平 +1 位作者 周惦武 刘金水 《稀有金属材料与工程》 SCIE EI CAS CSCD 北大核心 2006年第2期247-252,共6页
采用第一原理赝势平面波方法——CASTEP程序计算了4种B2型Y基金属间化合物YX(X=Ag,Cu,In,Rh)的部分弹性性质,计算结果与文献报道值基本一致。通过Pugh定律、Cauchy压力和泊松比等经验判据,分析并预测了它们的脆性/延性,其延性高低次序为... 采用第一原理赝势平面波方法——CASTEP程序计算了4种B2型Y基金属间化合物YX(X=Ag,Cu,In,Rh)的部分弹性性质,计算结果与文献报道值基本一致。通过Pugh定律、Cauchy压力和泊松比等经验判据,分析并预测了它们的脆性/延性,其延性高低次序为:YRh>YAg>YCu>YIn。电子结构分析表明:这4种金属间化合物良好的延性源于其较强的金属键,而不同程度的Y(d)-X(p)电子杂化则导致了其延性的差异。YIn中因In的p电子较多,杂化程度高,共价键方向性强,因而延展性最低,而YRh则由于存在Y(d)-Rh(d)电子间强的相互作用,增强了其金属键作用,因而延性最好。 展开更多
关键词 Y基金属间化合物 脆性/延性 第一原理 电子结构
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几种工程陶瓷的延性域磨削 被引量:3
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作者 纳米尔 林滨 +2 位作者 关强 于思远 董向红 《天津大学学报》 EI CAS CSCD 1999年第4期486-491,共6页
在几种磨削条件下,采用不同粒度金刚石砂轮对工程陶瓷材料进行了延性域磨削,着重研究了磨粒尺寸和各磨削参数对陶瓷材料磨削过程中脆性/延性转换的影响,并用微粉金刚石砂轮(W2.5)进行ZrO2、Sialon和Si3N4陶瓷... 在几种磨削条件下,采用不同粒度金刚石砂轮对工程陶瓷材料进行了延性域磨削,着重研究了磨粒尺寸和各磨削参数对陶瓷材料磨削过程中脆性/延性转换的影响,并用微粉金刚石砂轮(W2.5)进行ZrO2、Sialon和Si3N4陶瓷的超精密磨削,获得表面粗糙度Ra3,4,8nm的超光滑镜面.最后采用STM对上述精密镜面的形貌和细节进行了观测。 展开更多
关键词 脆性/延性转换 磨削参数 延性域磨削 工程陶瓷
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Microstructure and mechanical properties of Fe-doped NiAl-28Cr-6Mo eutectic alloys 被引量:2
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作者 A.GUNGOR H.DEMIRTAS 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2016年第4期1025-1031,共7页
Room temperature and high temperature microstructural and mechanical properties of arc melted Ni Al-28Cr-6Mo eutectic alloys doped with 0.1% Fe, 0.2% Fe and 0.5% Fe(mole fraction) were investigated. The homogenization... Room temperature and high temperature microstructural and mechanical properties of arc melted Ni Al-28Cr-6Mo eutectic alloys doped with 0.1% Fe, 0.2% Fe and 0.5% Fe(mole fraction) were investigated. The homogenization heat treatment of the alloys was conducted at 1300℃ in Ar atmosphere. Microscopic analyses, hardness measurements, XRD measurements and compression tests were used to characterize the alloys. As-cast and homogenized alloys exhibit fine cellular eutectic structures with coarse intercellular eutectic structure. The increase in the content of Fe results in coarsening eutectic layers and the decrease in eutectic cells. All alloys have very high compressive stress and strain at room temperature. The addition of Fe has small negative impact on the strength and ductility of the alloys at room temperature. However, the addition of Fe increases the high temperature strength of the alloy. High temperature XRD patterns show that peaks shift to lower Bragg angles. This indicates that the lattice parameter of the alloys increases. 展开更多
关键词 aluminium alloy MICROALLOYING solid-solution hardening BRITTLENESS DUCTILITY microstructure mechanical properties
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First-principles and experimental investigations on ductility/brittleness of intermetallic compounds and joint properties in steel/aluminum laser welding 被引量:3
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作者 Tian LI Dian-wu ZHOU +2 位作者 You-rui-ling YAN Ping PENG Jin-shui LIU 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2021年第10期2962-2977,共16页
Morphology,distribution,composition,forming ability,structural stability and intrinsic mechanical properties of the intermetallic compounds(IMCs)formed in steel/aluminum laser welding were determined through scanning ... Morphology,distribution,composition,forming ability,structural stability and intrinsic mechanical properties of the intermetallic compounds(IMCs)formed in steel/aluminum laser welding were determined through scanning electron microscope,energy dispersive spectrometer,X-ray diffractometer and first-principles calculation.It was found that the mechanical properties of the joint are limited by the Fe−Al IMCs,whose brittleness is attributed to the orbital hybridization between Al(s),Al(p)and Fe(d).However,the joint properties are improved by adding interlayer,which is ascribed to some changes of electronic structure of the generated IMCs.The transition mechanism of IMCs changing from brittle to ductile is mainly due to the weak ability of interlayer elements to attract electrons.The mechanical properties of the joint are closely related to the ductility or brittleness of the IMCs.Moreover,the addition of Ti foil interlayer effectively improves the mechanical properties of the joints,which means that the experimental verification is in good agreement with the theoretical calculation predictions. 展开更多
关键词 first-principles calculation elastic constant DUCTILITY BRITTLENESS laser welding mechanical properties
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