本文由氧化石墨烯通过水热法制备直接获得石墨烯。采用热重-差热分析方法检测了石墨烯受热过程中的质量变化和氧化温度。利用热分析-质谱联用技术在400-650°C温度区间得到了水和二氧化碳正离子质谱峰,这说明石墨烯氧化过程中的质...本文由氧化石墨烯通过水热法制备直接获得石墨烯。采用热重-差热分析方法检测了石墨烯受热过程中的质量变化和氧化温度。利用热分析-质谱联用技术在400-650°C温度区间得到了水和二氧化碳正离子质谱峰,这说明石墨烯氧化过程中的质量损失是由羟基水和二氧化碳脱除造成的。同时,还采用非等温热分析动力学方法,利用5、10、15°C?min^(-1)三种不同升温速率获得了石墨烯材料在空气气氛下的热分析动力学参数。通过Kissinger方法计算出石墨烯氧化过程中的活化能(Ea)和指前因子的对数(lg(A/s-1))分别为155.11 k J?mol^(-1)和6.90。利用Ozawa-Flynn-Wall(FWO)方法还建立了活化能和指前因子与反应转化率之间的关系。基于以上研究结果,本工作将对石墨烯在热界面、导热和先进复合材料等领域的应用提供参考价值。展开更多
Performance of a pulse tube cooler significantly depends on the efficient operation of its regenerator. Influence of input acoustic power on regenerator's performance is simulated and analyzed with simple harmonic...Performance of a pulse tube cooler significantly depends on the efficient operation of its regenerator. Influence of input acoustic power on regenerator's performance is simulated and analyzed with simple harmonic analysis method. Given regenera-tor's dimensions and pressure ratio,there is an optimal input acoustic power for achieving a highest coefficient of performance,due to a compromise between relative time-averaged total energy flux in regenerator and relative acoustic power at regenerator's cold end. Additionally,optimal dimensions of regenerator are also estimated and presented for different input acoustic powers. The computed optimal diameter obviously increases with increase of input acoustic power,while the optimal length decreases slightly,and as a result,a larger input acoustic power requires a smaller aspect ratio (length over diameter).展开更多
Boiling heat transfer condition has significance for pool-type research reactors cooled by natural circulation.It has important effect on the fuel element safety of reactor.On the basis of heat transfer characteristic...Boiling heat transfer condition has significance for pool-type research reactors cooled by natural circulation.It has important effect on the fuel element safety of reactor.On the basis of heat transfer characteristics of the Xi'an pulsed reactor(XAPR),fuel conduction,single-phase convection and boiling heat transfer,and void fraction models of the core are constructed.To validate the correctness of the physical models presented in the paper,numerical calculation based on a subchannel analysis method of XAPR is carried out,and the temperature fields are measured in some reactor coolant channels.The comparison between the calculated and experimental results verifies the effectiveness of the models.These physical models are used to calculate the thermal-hydraulic parameters of XAPR at the rated power(for XAPR the rated power is 2.0 MW in steady-state operation).The results indicate that subcooled boiling occurs in the XAPR core but it exhibits a subcooling degree which is considerably higher than that of saturation boiling.Subcooled boiling improves the efficiency of heat transfer between the fuel element surface and coolant,as well as effectively protects fuel elements.This research is also a beneficial reference in thermal-hydraulic analysis for other natural circulation reactors.展开更多
基金supported by the National Natural Science Foundation of China(51325203,51472263)Shanghai Materials Genome Project,China(14DZ2261200)+2 种基金Shanghai Technical Platform for Testing and Characterization on Inorganic Materials,China(14DZ2292900)Shanghai Sailing Program,China(16YF1413100)Program of the Innovative Fund of Shanghai Institute of Ceramics,Chinese Academy of Science(Y37ZC4143G)~~
文摘本文由氧化石墨烯通过水热法制备直接获得石墨烯。采用热重-差热分析方法检测了石墨烯受热过程中的质量变化和氧化温度。利用热分析-质谱联用技术在400-650°C温度区间得到了水和二氧化碳正离子质谱峰,这说明石墨烯氧化过程中的质量损失是由羟基水和二氧化碳脱除造成的。同时,还采用非等温热分析动力学方法,利用5、10、15°C?min^(-1)三种不同升温速率获得了石墨烯材料在空气气氛下的热分析动力学参数。通过Kissinger方法计算出石墨烯氧化过程中的活化能(Ea)和指前因子的对数(lg(A/s-1))分别为155.11 k J?mol^(-1)和6.90。利用Ozawa-Flynn-Wall(FWO)方法还建立了活化能和指前因子与反应转化率之间的关系。基于以上研究结果,本工作将对石墨烯在热界面、导热和先进复合材料等领域的应用提供参考价值。
基金Project supported by the National Natural Sciences Foundation of China (No. 50536040)the University Doctoral Subject Special Foundation of China (No. 20050335047)the Postdoctoral Sci-ence Foundation of Zhejiang Province (No. 2006-bsh-21),China
文摘Performance of a pulse tube cooler significantly depends on the efficient operation of its regenerator. Influence of input acoustic power on regenerator's performance is simulated and analyzed with simple harmonic analysis method. Given regenera-tor's dimensions and pressure ratio,there is an optimal input acoustic power for achieving a highest coefficient of performance,due to a compromise between relative time-averaged total energy flux in regenerator and relative acoustic power at regenerator's cold end. Additionally,optimal dimensions of regenerator are also estimated and presented for different input acoustic powers. The computed optimal diameter obviously increases with increase of input acoustic power,while the optimal length decreases slightly,and as a result,a larger input acoustic power requires a smaller aspect ratio (length over diameter).
文摘Boiling heat transfer condition has significance for pool-type research reactors cooled by natural circulation.It has important effect on the fuel element safety of reactor.On the basis of heat transfer characteristics of the Xi'an pulsed reactor(XAPR),fuel conduction,single-phase convection and boiling heat transfer,and void fraction models of the core are constructed.To validate the correctness of the physical models presented in the paper,numerical calculation based on a subchannel analysis method of XAPR is carried out,and the temperature fields are measured in some reactor coolant channels.The comparison between the calculated and experimental results verifies the effectiveness of the models.These physical models are used to calculate the thermal-hydraulic parameters of XAPR at the rated power(for XAPR the rated power is 2.0 MW in steady-state operation).The results indicate that subcooled boiling occurs in the XAPR core but it exhibits a subcooling degree which is considerably higher than that of saturation boiling.Subcooled boiling improves the efficiency of heat transfer between the fuel element surface and coolant,as well as effectively protects fuel elements.This research is also a beneficial reference in thermal-hydraulic analysis for other natural circulation reactors.
