In this work,the regeneration mechanism of potassium carbonate solution after absorption of CO2 using ion-exchange membrane electrolysis was presented.The solutions of potassium carbonate(K2CO3) and potassium bicarbon...In this work,the regeneration mechanism of potassium carbonate solution after absorption of CO2 using ion-exchange membrane electrolysis was presented.The solutions of potassium carbonate(K2CO3) and potassium bicarbonate(KHCO3) were used to simulate the solution after absorbing CO2.Experiments were carried out at various electrodes,temperatures and current densities.The results indicate that the membrane electrolysis can in-crease concentration ratio of K2CO3 and KHCO3,and achieve 100%conversion.In this process,not only CO2 is desorbed from carbonate solution,but also hydrogen,as a byproduct,is generated at the cathode,which is the main contributor to reduce energy consumption.Thus,the membrane electrolysis is valuable in the regeneration of the K2CO3 absorbent.展开更多
基金Supported by the Specialized Research Fund for Doctoral Programme of Higher Education of MOE（200700033154 200800030095） the National Natural Science Foundation of China（20836008）
文摘In this work,the regeneration mechanism of potassium carbonate solution after absorption of CO2 using ion-exchange membrane electrolysis was presented.The solutions of potassium carbonate(K2CO3) and potassium bicarbonate(KHCO3) were used to simulate the solution after absorbing CO2.Experiments were carried out at various electrodes,temperatures and current densities.The results indicate that the membrane electrolysis can in-crease concentration ratio of K2CO3 and KHCO3,and achieve 100%conversion.In this process,not only CO2 is desorbed from carbonate solution,but also hydrogen,as a byproduct,is generated at the cathode,which is the main contributor to reduce energy consumption.Thus,the membrane electrolysis is valuable in the regeneration of the K2CO3 absorbent.
