“拒腐防变”需谨小慎微

湖南是个水利大省,水利建设项目大大小小很多,山塘整治、除险加固、续建配套、人饮安全、堤防建设等,投资也不小,资金管理难度大,如何保证工程质量、资金安全、干部安全值得探讨,文章分析"腐变"的发展变化过程,提出领导要注意嗜好、戒贪欲、慎用权、防微杜渐、慎独自律、善待人生、勤于学习等方面来加强修养,拒腐防变,对水利系统各级执政领导具有积极的警戒意义。

新疆五堡墓地出土干燥皮革文物的劣变与保护

皮革很容易劣化腐变,因此我国出土皮革文物数量很少。新疆、甘肃等北方地区出土的一些皮革文物,是研究古代人们生产生活的重要实物资料。为此,本研究探讨了出土干燥皮革文物发掘前和发掘后的劣变因素,并以新疆五堡墓地出土皮革文物的保护修复过程作为实例,对出土干燥皮革的保护方法和过程进行了阐述。在显微镜观察评估病害基础上,对皮革文物采取杀虫、加湿整形等处理。结果表明:干燥皮革劣变的内因主要是皮革本身的组成结构和鞣制方法,外因则主要是皮革出土前所处的土壤埋藏环境和出土后的大气保存环境,保护处理后的皮革恢复形状,可满足展览要求。本研究结果可为出土干燥皮革文物的保护研究提供参考。

反腐:以文学的名义——评张力反腐倡廉题材小说

张力是一位持续关注现实的作家,对社会的腐败现象多有揭示和批判。他以笔为剑,为民担当,剖写底层、基层、官场与腐败的隐秘关联,呼唤公平、正义与良知。

新时代下如何加强基层企业反腐廉政工作建设研究

反腐廉政是我党长期以来的一贯作风,各个不同时期有着不同的时代特色。特别是党的十八大以来,反腐廉政得到了空前的发展,依法治国得到明显加强。本文从反腐廉政的现状、所存在的问题及其建议和对策等方面在经验和学术之间进行了一些探讨和研究。最后,提出了一般性的结论,反腐廉政是一项长期而艰苦的斗争,它贯穿于社会主义整个过程。高举反腐廉政的伟大旗帜,才能最终实现中华民族的伟大复兴,实现美丽的"中国梦"!

可食性果蔬保鲜膜研究现状与发展趋势

综述了可食性果蔬保鲜膜的研究现状,提出了可食性保鲜膜的发展趋势。

Effect of TiO_2 content on properties of Al_2O_3 thermal barrier coatings by plasma spraying

Al2O3 thermal barrier coatings with different TiO2 contents were deposited on 6061 aluminum alloy by plasma spraying. The corrosion resistance, thermal insulation property and phase composition of these coatings were investigated. The results indicate that all the feedstock powders exhibit phase transformation during the spray process. With the increase of the TiO2 content in the powder, the corrosion resistance of the coating is enhanced but the thermal insulation property is decreased. This can be attributed to the higher thermal conductivity but lower melting point and brittleness of TiO2 than those of Al2O3, so it is easy for TiO2 to disperse in the brittle Al2O3 substrate during spraying, in which these dispersively distributed TiO2 play the role of hole sealing, releasing stress and reducing cracks.

Effect of pre-deformation of rolling combined with stretching on stress corrosion of aluminum alloy 2519A plate

The effect of the pre-deformation of rolling combined with stretching on the stress corrosion cracking resistance of aluminum alloy 2519A was studied by means of the slow strain rate technique at 10-6 s-1. The tensile strength and stress corrosion index of the alloy plate with 7% rolling plus 3% perpendicular stretching were 481 MPa and 0.0429, respectively, showing better mechanical property and stress corrosion cracking resistance than those with 4% rolling plus 3% parallel stretching or 7% rolling plus 3% parallel stretching, which is due to its finer and denser precipitates within the grains, discontinuous grain boundary precipitates, as well as more narrow precipitate-free zone width. Such microstructure is attributing to the denser and more homogeneously distributed dislocations which are produced by the pre-deformation.

Stress corrosion cracking behaviour of 7xxx aluminum alloys: A literature review

Stress corrosion cracking （SCC） is degradation of mechanical properties under the combined action of stress and corrosive environment of the susceptible material. Out of eight series of aluminium alloys, 2xxx, 5xxx and 7xxx aluminium alloys are susceptible to SCC. Among them, 7xxx series aluminium alloys have specific application in aerospace, military and structural industries due to superior mechanical properties. In these high strength 7xxx aluminium alloys, SCC plays a vital factor of consideration, as these failures are catastrophic during the service. The understanding of SCC behaviour possesses critical challenge for this alloy. The main aim of this review paper is to understand the effect of constituent alloying elements on the response of microstructural variation in various heat-treated conditions on SCC behavior. Further, review was made for improving the SCC resistance using thermomechanical treatments and by surface modifications of 7xxx alloys. Apart from a brief review on SCC of 7xxx alloys, this paper presents the effect of stress and pre-strain, effect of constituent alloying elements in the alloy, and the effect of environments on SCC behaviour. In addition, the SCC behaviours of weldments, 7xxx metal matrix composites and also laser surface modifications were also reviewed.

Corrosion behaviour of thixoformed and heat-treated ZA27 alloys in NaCl solution

The influence of corrosion on the microstructure of thixoformed and heat-treated ZA27 alloys was investigated. The microstructure of ZA27 alloy was affected by heat treatment. The process of electrochemical corrosion occurs in both ZA27 alloys through the area of r/phase. According to the results of immersion test and electrochemical measurements, the corrosion rate of the thixoformed ZA27 alloy is at least 50% lower than that of the thixoformed and thermally processed alloy. This indicates the unfavourable influence of applied heat treatment （T4 regime） on the corrosion resistance of the thixoformed ZA27 alloy.

Transformation mechanism of secondary phase and its effect on intergranular corrosion in laser wire filling welding Ni-based alloy/304 stainless steel

To clarify the transformation mechanism of secondary phase and the mechanism of intergranular corrosion in laser welding Ni-based alloy (Hastelloy C-276)/304 stainless steel with filler wire,the secondary phase was analyzed by electron probe micro-analysis (EPMA) and transmission electron microscopy (TEM).The evaluation of intergranular corrosion resistance of the welded joints was conducted by double-loop electrochemical potentiokinetic reactivation(DL-EPR) method,and at the same time the chemical compositions of the corrosion surface were analyzed by energy-dispersive spectrometry (EDS).The results show that p phase has complete coherence relationship withμphase,and the coherent relationship is described as[001]p//■and[430]p//[0001]μ.Theμphase is rapidly transformed from p phase,which is the inhomogeneous phase transformation.The transformation of secondary phase will increase the susceptibility to intergranular corrosion.Therefore,the transformation of secondary phase should be avoided in the welding process.

In-situ formation characteristic, tribological characterization and anti-corrosion properties of quaternary composites films

Improvements of wear and corrosion properties are essential characteristic in engineering application. A study was made on the structure, electro-oxidation and properties of fabricated Zn-Al-SnO 2-Ti O2（Zn-Al-Sn-Ti） thin films using electrodeposition technique from chloride bath. The microstructural studies were performed by scanning electron microscopy with attached energy dispersive spectrometer（SEM-EDS）, optical microscopy（OPM） and X-ray diffractogram（XRD）. The electrochemical oxidation and erosion behavior in 3.65% Na Cl medium were studied by potentiodynamic polarization technique and characterized by atomic force microscopy（AFM）. The hardness and wear behavior of the electrodeposited film were performed by high diamond dura scan microhardness tester and CERT UMT-2 reciprocating sliding machine. It was found that a successful co-deposition of composite and particle were attained. Homogeneous imbedded grain structure distribution and fine refinement of crystal with improved micromechanical behavior was achieved. The corrosion resistance, hardness and wear stability resistance of the fabricated quaternary films improved significantly in all varied process parameter.

Influence of multipass high rotating speed friction stir processing on microstructure evolution,corrosion behavior and mechanical properties of stirred zone on AZ31 alloy

The influence of multipass high rotating speed friction stir processing(FSP)on the microstructure evolution,corrosion behavior,and tensile properties of the stirred zone(SZ)was investigated by EBSD,TEM,SEM,electrochemical workstation and electronic universal testing machine.The mean grain size of the SZ is significantly refined,and it increases with the increase of the processing pass.In addition to an obvious increase in the number,the distribution ofβ-Al12Mg17 precipitates also becomes more uniform and dispersed with increasing the processing pass.Compared with the as-received AZ31 alloy,the tensile properties of the SZ are hardly improved,but the corrosion resistances are significantly enhanced.The corrosion potential of the SZ prepared by 4-pass FSP is increased from−1.56 V for the unprocessed AZ31 alloy to−1.19 V,while the corrosion current is decreased from 1.55×10^−4 to 5.47×10^−5 A.

Effects of Composted and Thermally Dried Sewage Sludges on Soil and Soil Humic Acid Properties

The effect of annual additions of composted sewage sludge (CS) and thermally dried sewage sludge (TS) at 80 t ha-1 on soil chemical properties was investigated for three years in a field experiment under semiarid conditions. Humic acids (HAs) isolated by conventional procedures from CS, TS, and unamended (SO) and sludge amended soils were analysed for elemental (C, H, N, S and O) and acidic functional groups (carboxylic and phenolic) and by ultraviolet-visible, Fourier transform infrared and fluorescence spectroscopies. With respect to CS, TS had similar pH and total P and K contents, larger dry matter, total organic C, total N and C/N ratio and smaller ash content and electrical conductivity. Amendment with both CS and TS induced a number of modifications in soil properties, including an increase of pH, electrical conductivity, total organic C, total N, and available P. The CS-HA had greater O, total acidity, carboxyl, and phenolic OH group contents and smaller C and H contents than TS-HA. The CS-HA and TS-HA had larger N and S contents, smaller C, O and acidic functional group contents, and lower aromatic polycondensation and humification degrees than SO-HA. Amended soil-HAs showed C, H, N and S contents larger than SO-HA, suggesting that sludge HAs were partially incorporated into soil HAs. These effects were more evident with increasing number of sludge applications.

Tensile creep and corrosion properties of Mg-2%Ca based cast alloys

The relative effect of Zn addition to Mg-2%Ca based alloy on the creep and corrosion characteristics was compared with Al addition. The creep resistance of Mg-2%Ca based alloy at 175 ℃was improved by Zn addition more significantly than by Al addition. However, the Al addition showed more effective in enhancing corrosion resistance. Since the solidification range for Zn-added alloy was considerably wide, the cautious casting design may be necessary to produce high-quality castings.

Corrosion properties of plastically deformed AZ80 magnesium alloy

AZ80 magnesium alloys were deformed at 200,250,300,350 and 400℃ with different deformation degree of 50%,75%, 83%,87%and 90%,respectively.The corrosion properties of different deformed AZ80 samples were studied by galvanic test in 3.5%NaCl solution.The results show that plastic deformation could improve the corrosion resistance of AZ80 alloy;and the corrosion rate of AZ80 deformed at 250℃ with the deformation degree of 83%was the lowest,which was 33%of the as-cast AZ80 alloy.Further studies of the microstructure show that the refined grain size and continuously distribution ofβphase around the grain boundary did have a positive effect on the improvement of corrosion resistance of AZ80 alloys.For AZ80 alloys,the smaller the grain size is,the more homogeneous the structure is,and the better the corrosion resistance is.

SCC evaluation of ultra-high strength steel in acidic chloride solution

The stress corrosion crack （SCC） susceptibility of ultra-high strength steel AerMet 100 was investigated by slow strain rate technique （SSRT）, tensile with polarization and surface analysis technique. The curves of tf^Cl/tf^W -strain rate are divided into three regions： stress-dominated region, SCC-dominated region, and corrosion-dominated region, so as the curves of εf^Cl/εf^W - strain rate and tm/tf-strain rate. The results of tensile tests with polarization show that the main SCC mechanism of AerMet 100 is anodic dissolution, which controls the corrosion process. The three regions have been discussed according to the relationship between the rate of slip-step formation and the rate of dissolution. Fracture appearances in different environments were analyzed by scanning electron microscopy （SEM）. SCC fracture appears as a mixture of intergranular and dimples, while it is totally dimples in the inert environment. The εf becomes the parameter to predict tf because the relationship between εf^Cl/εf^W and tf^Cl/tf^w is a straight line for AerMet 100.

Filiform corrosion behaviour on machined AA7150 aluminium alloy

The microstructure and the filiform corrosion behaviour of machined AA7150 aluminium alloy were investigated using scanning and transmission electron microscopies combined with potentiodynamic polarization and filiform corrosion testing,respectively.It is found that the grain refinement,redistribution of alloying elements,and elements segregation at grain boundaries are evident within the near-surface region on the machined AA7150 aluminium alloy.The corrosion susceptibility of machining introduced near-surface deformed layer is significantly improved caused by the modified microstructure associated with severe deformation.Filiform corrosion resistance on the machined surface is obviously decreased,due to the surface roughness associated with machining tracks and the presence of the electrochemically more active near-surface deformed layer introduced by machining.

Heat treatment of 7xxx series aluminium alloys—Some recent developments

The 7xxx series alloys are heat treatable wrought aluminium alloys based on the Al-Zn-Mg（-Cu） system. They are widely used in high-performance structural aerospace and transportation applications. Apart from compositional, casting and thermo-mechanical processing effects, the balance of properties is also significantly influenced by the way in which the materials are heat-treated. This paper describes the effects of homogenisation, solution treatment, quenching and ageing treatments on the evolution of the microstructure and properties of some important medium to high-strength 7xxx alloys. With a focus on recent work at Monash University, where the whole processing route from homogenisation to final ageing has been studied for thick plate products, it is reported how microstructural features such as dispersoids, coarse constituent particles, fine-scale precipitates, grain structure and grain boundary characteristics can be controlled by heat treatment to achieve improved microstructure-property combinations. In particular, the paper presents methods for dissolving unwanted coarse constituent particles by controlled high- temperature treatments, quench sensitivity evaluations based on a systematic study of continuous cooling precipitation behaviour, and ageing investigations of one-, two- and three-step ageing treatments using experimental and modelling approaches, in each case, the effects on both the microstructure and the resulting properties are discussed.

A damage constitutive model of rock-like materials containing a single crack under the action of chemical corrosion and uniaxial compression

To describe the deformation and strength characteristics of the corroded rock-like specimens containing a single crack under uniaxial compression,a damage constitutive model combining hydro-chemical damage with coupling damage of micro-flaws and macro-cracks is proposed.Firstly,based on phenomenological theory,the damage variable of the rock-like specimens subjected to water environment erosion and chemical corrosion is obtained.Secondly,a coupled damage variable for cracked rock-like specimens is derived based on the Lemaitre strain equivalence hypothesis,which combines the Weibull statistical damage model for micro-flaws and the fracture mechanics model for a macro single crack.Then,considering the residual strength characteristics of the rock-like materials,the damage variable is modified by introducing the correction coefficient,and the damage constitutive model of the corroded rock-like specimens with a single crack under uniaxial compression is established.The model is verified by comparing the experimental stress−strain curves,and the results are in good agreement with those provided in the literature.Finally,the correction coefficient of the damage variable proposed in this paper is discussed.The damage constitutive model developed in this paper provides an effective method to describe the stress−strain relationship and residual strength characteristics of the corroded rock-like specimens with a single crack under uniaxial compression.