One new ent-pimarane diterpenoid ent-16-nor-3-oxo-pimar-8(14)-en-15-al (1) together with four known diterpenoids kirenol (2), ent-2-oxo-15,16,19-trihydroxypimar-8(14)-ene (3), darutigenol (4) and darutosi...One new ent-pimarane diterpenoid ent-16-nor-3-oxo-pimar-8(14)-en-15-al (1) together with four known diterpenoids kirenol (2), ent-2-oxo-15,16,19-trihydroxypimar-8(14)-ene (3), darutigenol (4) and darutoside (5) were isolated from the ethanol extract of Siegesbeckia pubescens. The planar structures and relative configurations of these compounds were elucidated by comprehensive spectroscopic analysis.展开更多
基金supported by the National Natural Science Foundation of China(Grant No.30973628)the National Science and Technology Project of China(Grant No.2012ZX09103201-022)
文摘One new ent-pimarane diterpenoid ent-16-nor-3-oxo-pimar-8(14)-en-15-al (1) together with four known diterpenoids kirenol (2), ent-2-oxo-15,16,19-trihydroxypimar-8(14)-ene (3), darutigenol (4) and darutoside (5) were isolated from the ethanol extract of Siegesbeckia pubescens. The planar structures and relative configurations of these compounds were elucidated by comprehensive spectroscopic analysis.