The floating photovoltaic membrane prototype developed by Ocean Sun was selected as a reference object,and a 1∶40 scale laboratory model was designed and produced to further explore the impact of inflow conditions on...The floating photovoltaic membrane prototype developed by Ocean Sun was selected as a reference object,and a 1∶40 scale laboratory model was designed and produced to further explore the impact of inflow conditions on the hydrodynamic properties of the membrane structure.By conducting free attenuation tests,results showed that the inflow has only a slight effect on the natural frequencies of the heave,pitch,and surge of the membrane structure.This finding shows that the dynamic properties of the membrane structure remain essentially stable under different inflow conditions.The results of further regular and irregular wave hydrodynamic experiments show that,compared with the control group,the response of the membrane structure under inflow conditions in terms of heave,pitch,surge,and heave acceleration motions is relatively gentle,whereas the response of the membrane structure to the mooring force is strong.Especially when the waves are irregular,the inflow conditions have a more significant impact on the membrane structure,which may lead to more complex response changes in the structure.Therefore,in the actual engineering design process,the impact of inflow conditions on the behavior of the membrane structure must be fully considered,and appropriate engineering measures must be taken to ensure the safety and stability of the structure.展开更多
Honeycomb-like films of basic zinc carbonate were successfully prepared on FTO(SnO_(2):F)conductive glass using bovine serum albumin(BSA)as a template at room temperature.After low-temperature annealing,a high-specifi...Honeycomb-like films of basic zinc carbonate were successfully prepared on FTO(SnO_(2):F)conductive glass using bovine serum albumin(BSA)as a template at room temperature.After low-temperature annealing,a high-specific-surface-area porous ZnO film with excellent electron mobility was obtained.The surface morphology,crystallization performance,and photoluminescence characteristics of basic zinc carbonate thin films and annealed ZnO thin film were analyzed by scanning electron microscopy(SEM),transmission electron microscopy(TEM),X-ray diffraction(XRD),photoluminescence spectroscopy(PL)and UV-Visible spectroscopy(UV-vis).By comparing with those samples prepared without any protein,it was determined that the complexation between BSA molecules and Zn^(2+)ions was the primary factor in the synthesis of porous films of basic zinc carbonate.The experimental results showed that the ZnO thin film samples prepared with this method had high specific surface area and broadband luminescence characteristics in the near ultraviolet range.展开更多
Restraining the aggregation and polysulfide dissolution of edge-enriched metal sulfides is of significance for their applications as anode materials of lithium-ion batteries(LIBs)with high capacity and long cycle-life...Restraining the aggregation and polysulfide dissolution of edge-enriched metal sulfides is of significance for their applications as anode materials of lithium-ion batteries(LIBs)with high capacity and long cycle-life.In this work,we have reported the incorporation of MoS2 nanocrystals into amorphous carbon on the surface of reduced graphene oxide(rGO)by balancing the decomposition rates of phenolic resin(PF)-impregnated ammonium thiomolybdate(ATM),which subsequently forms the MoS2@C/rGO film through redispersion and vacuum filtration.Such structural design effectively avoids the aggregation of MoS2 nanocrystals and Li2S loss,and meanwhile ion enrichment in amorphous carbon and diffusion reinforcement can greatly accelerate the electrochemical reaction kinetics.When applied as the selfstanding anode,the MoS2@C/rGO film possesses high reversible capacities of 1164 mA h g^-1 at the current density of 0.2 A g^-1 and 810 mA h g^-1 at 6.4 A g^-1.It also exhibits quite a high capacity retention after 1000 cycles at 3.2 A g^-1.This work develops the formation theory of incorporation structures and promotes their applications in energy storage devices.展开更多
基金The National Natural Science Foundation of China(No.52171274).
文摘The floating photovoltaic membrane prototype developed by Ocean Sun was selected as a reference object,and a 1∶40 scale laboratory model was designed and produced to further explore the impact of inflow conditions on the hydrodynamic properties of the membrane structure.By conducting free attenuation tests,results showed that the inflow has only a slight effect on the natural frequencies of the heave,pitch,and surge of the membrane structure.This finding shows that the dynamic properties of the membrane structure remain essentially stable under different inflow conditions.The results of further regular and irregular wave hydrodynamic experiments show that,compared with the control group,the response of the membrane structure under inflow conditions in terms of heave,pitch,surge,and heave acceleration motions is relatively gentle,whereas the response of the membrane structure to the mooring force is strong.Especially when the waves are irregular,the inflow conditions have a more significant impact on the membrane structure,which may lead to more complex response changes in the structure.Therefore,in the actual engineering design process,the impact of inflow conditions on the behavior of the membrane structure must be fully considered,and appropriate engineering measures must be taken to ensure the safety and stability of the structure.
文摘Honeycomb-like films of basic zinc carbonate were successfully prepared on FTO(SnO_(2):F)conductive glass using bovine serum albumin(BSA)as a template at room temperature.After low-temperature annealing,a high-specific-surface-area porous ZnO film with excellent electron mobility was obtained.The surface morphology,crystallization performance,and photoluminescence characteristics of basic zinc carbonate thin films and annealed ZnO thin film were analyzed by scanning electron microscopy(SEM),transmission electron microscopy(TEM),X-ray diffraction(XRD),photoluminescence spectroscopy(PL)and UV-Visible spectroscopy(UV-vis).By comparing with those samples prepared without any protein,it was determined that the complexation between BSA molecules and Zn^(2+)ions was the primary factor in the synthesis of porous films of basic zinc carbonate.The experimental results showed that the ZnO thin film samples prepared with this method had high specific surface area and broadband luminescence characteristics in the near ultraviolet range.
基金supported by the National Natural Science Foundation of China(21975074 and 21838003)the Basic Research Program of Shanghai(17JC1402300)+1 种基金Shanghai Scientific and Technological Innovation Project(18JC1410500)the Fundamental Research Funds for the Central Universities(222201718002)。
文摘Restraining the aggregation and polysulfide dissolution of edge-enriched metal sulfides is of significance for their applications as anode materials of lithium-ion batteries(LIBs)with high capacity and long cycle-life.In this work,we have reported the incorporation of MoS2 nanocrystals into amorphous carbon on the surface of reduced graphene oxide(rGO)by balancing the decomposition rates of phenolic resin(PF)-impregnated ammonium thiomolybdate(ATM),which subsequently forms the MoS2@C/rGO film through redispersion and vacuum filtration.Such structural design effectively avoids the aggregation of MoS2 nanocrystals and Li2S loss,and meanwhile ion enrichment in amorphous carbon and diffusion reinforcement can greatly accelerate the electrochemical reaction kinetics.When applied as the selfstanding anode,the MoS2@C/rGO film possesses high reversible capacities of 1164 mA h g^-1 at the current density of 0.2 A g^-1 and 810 mA h g^-1 at 6.4 A g^-1.It also exhibits quite a high capacity retention after 1000 cycles at 3.2 A g^-1.This work develops the formation theory of incorporation structures and promotes their applications in energy storage devices.